Effect of pressure and temperature upon tin alkoxide-promoted ring-opening polymerisation of epsilon-caprolactone in supercritical carbon dioxide

Stassin, Fabrice; Jérôme, Robert

doi:10.1039/b209170d

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Article (Scientific journals)

Effect of pressure and temperature upon tin alkoxide-promoted ring-opening polymerisation of epsilon-caprolactone in supercritical carbon dioxide

Stassin, Fabrice; Jérôme, Robert

2003 • In Chemical Communications, (2), p. 232-233

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/10964

DOI
10.1039/b209170d

PubMed
12585406

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Keywords :

ring-opening polymerization (ROP); lactone; green technology; supercritical carbon dioxide

Abstract :

[en] Ring-opening polymerisation of epsilon-caprolactone in supercritical carbon dioxide is slowed down by a carbonation reaction, resulting in a positive volume of activation and a higher energy of activation as compared to polymerisation in a regular hydrocarbon solvent.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Stassin, Fabrice; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Effect of pressure and temperature upon tin alkoxide-promoted ring-opening polymerisation of epsilon-caprolactone in supercritical carbon dioxide

Publication date :

2003

Journal title :

Chemical Communications

ISSN :

1359-7345

eISSN :

1364-548X

Publisher :

Royal Society of Chemistry, Cambridge, United Kingdom

Issue :

Pages :

232-233

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.rsc.org/ej/CC/2003/b209170d.pdf

Funders :

The European Community in the frame of the ‘Superpol’ Brite program
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique
The Walloon Region in the frame of the TECMAVER program

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since 11 April 2009

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Bibliography

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