[en] A versatile approach to the preparation of hyperbranched polymers, in which an inimer is used to assemble a charge transfer complex (CTC) with conventional vinyl monomers, is reported. A novel hyperbranched fluoro-polymer (see Figure) has been successfully synthesized through the copolymerization of chlorotrifluoroethylene (CTFE) and p-(chloromethyl)styrene (CMS) by atom transfer radical polymerization (ATRP).
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Wang, Wenxin; University of Nottingham > School of Chemistry
Yan, Deyue; Shanghai Jiao Tong University > School of Chemistry and Chemical Technology
Bratton, Daniel; University of Nottingham > School of Chemistry
Howdle, Steven M; University of Nottingham > School of Chemistry
Wang, Qiang; University of Nottingham > School of Chemistry
Lecomte, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Charge transfer complex inimer: A facile route to dendritic materials
BELSPO - Service Public Fédéral de Programmation Politique scientifique [BE] NSCF - National Natural Science Foundation of China [CN] W. L. Gore and Associates, Inc