Thermo-reversible reactions for the preparation of smart materials: recyclable covalently-crosslinked shape memory polymers

Defize, Thomas; Riva, Raphaël; Thomassin, Jean-Michel; Jérôme, Christine; Alexandre, Michaël

doi:10.1002/masy.201100036

Article (Scientific journals)

Thermo-reversible reactions for the preparation of smart materials: recyclable covalently-crosslinked shape memory polymers

Defize, Thomas; Riva, Raphaël; Thomassin, Jean-Michel et al.

2011 • In Macromolecular Symposia, 309/310 (1), p. 154-161

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/106042

DOI
10.1002/masy.201100036

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Keywords :

Diels Alder reaction; network; shape-memory; stimuli-responsive network; polymer functionalization

Abstract :

[en] [4+2] thermoreversible Diels-Alder cycloaddition has been used to crosslink star-shaped poly(ε-caprolactone) in order to produce networks based on strong carbon-carbon covalent bondings. Depending on the nature of the Diels-Alder reactants, these bonds can be thermoreversibly broken, allowing re-processing of the polymer matrix.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Defize, Thomas ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Riva, Raphaël ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Thomassin, Jean-Michel ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Alexandre, Michaël ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Thermo-reversible reactions for the preparation of smart materials: recyclable covalently-crosslinked shape memory polymers

Publication date :

December 2011

Journal title :

Macromolecular Symposia

ISSN :

1022-1360

eISSN :

1521-3900

Publisher :

Wiley, Germany

Volume :

309/310

Issue :

Pages :

154-161

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://onlinelibrary.wiley.com/doi/10.1002/masy.201100036/pdf

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique
The Walloon Region in the frame of the IMPEIOSE project

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since 23 December 2011

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