Water-soluble complexes formed by poly(2-vinylpyridinium)-block-poly(ethylene oxide) and poly(sodium methacrylate)-block-poly(ethylene oxide) copolymers

Gohy, Jean-François; Varshney, Sunil K; Jérôme, Robert

doi:10.1021/ma0020483

Article (Scientific journals)

Water-soluble complexes formed by poly(2-vinylpyridinium)-block-poly(ethylene oxide) and poly(sodium methacrylate)-block-poly(ethylene oxide) copolymers

Gohy, Jean-François; Varshney, Sunil K; Jérôme, Robert

2001 • In Macromolecules, 34 (10), p. 3361-3366

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/9705

DOI
10.1021/ma0020483

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Keywords :

self-assembly in solution; micelle; stimuli responsive micelle

Abstract :

[en] Formation of interpolyelectrolyte complexes (IPEC) by mixing protonated poly(2-vinylpyridine)-block-poly(ethylene oxide) (P2VP-b-PEO) with neutralized poly(methacrylic acid)-block-poly(ethylene oxide) (PMAA-b-PEO) has been investigated in water. It was observed that (i) IPEC are formed in a limited pH range, which is controlled by the degree of ionization of the PMAA and P2VP blocks; (ii) IPEC self-assemble to form the core of monodisperse spherical micelles surrounded by a corona of PEO blocks; (iii) IPEC are salt-sensitive, falling apart above a critical salt concentration; (iv) IPEC are not observed at high pH, but micelles are formed by the P2VP-b-PEO copolymers, which contain an uncharged P2VP core surrounded by a PEO corona; (v) IPEC are not observed at low pH, but the PMAA-b-PEO diblocks aggregate into micelles, the core of which is formed by a hydrogen-bonded complex between PMAA and PEO; and (vi) these PMAA-b-PEO micelles, which are temperature-sensitive, show a complete reorganization of the micellar core above a critical temperature.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Gohy, Jean-François; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Varshney, Sunil K; Polymer Source, Dorval, Canada

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Water-soluble complexes formed by poly(2-vinylpyridinium)-block-poly(ethylene oxide) and poly(sodium methacrylate)-block-poly(ethylene oxide) copolymers

Publication date :

08 May 2001

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - Washington

Volume :

Issue :

Pages :

3361-3366

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma0020483

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
The Fondation Européenne de la Science (ESF) in the frame of the SUPERNET program

Available on ORBi :

since 25 March 2009

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