auto ignition control; HCCI engine application; Influence of fuel composition; numerical and experimental validation; reduced mechanism kinetics
Abstract :
[en] A certain possible approach for the control of HCCI chemistry is to use kinetic chemistry mechanisms. This opens a field of interest that lead to the composition of a validated reduced PRF chemistry mechanism. For this purpose a skeletal chemical reaction mechanism for n-heptane and for iso-octane are constructed from a detailed n-heptane and iso-octane mechanism of the Chalmers University of Technology. Subsequently these two mechanisms are forged into one reduced chemical reaction mechanism for mixtures of n-heptane and isooctane (39 species and 47 reactions). This mechanism is numerically validated against the Chalmers mechanisms, respecting the HCCI application range. The reduced mechanism is also successfully numerically validated against another more detailed mechanism provided by LLNL. Engine experiments are performed validating this mixture mechanism with respect to the fuel composition containing n-heptane and iso-octane. The influence of the compression ratio and the equivalence ratio is also studied and used to validate the reduced PRF mechanism.
Disciplines :
Chemical engineering Physics Energy Engineering, computing & technology: Multidisciplinary, general & others
Banerjee, I. and Ierapetritou, M.G. (2003) Development of an adaptive chemistry model considering micromixing effects. Chem. Eng. Sci., 58, 4537-4555.
Battin-Leclerc, F., Glaude, P.A., Warth, V., Fournet, R., Scacchi, G., and Come, G.M. (2000) Computer tools for modelling the chemical phenomena related to combustion. Chem. Eng. Sci., 55, 2883-2893.
Bikas, G. and Peters, N. (2001) Brief communication: Kinetic modelling of n-decane combustion and autoignition. Combust. Flame, 126, 1456-1475.
Curran, H.J., Gaffuri, P., Pitz, W.J., and Westbrook, C.K. (1998) A comprehensive modeling study of n-heptane oxidation. Combust. Flame, 114, 149-177.
Curran, H.J., Gaffuri, P., Pitz, W.J., and Westbrook, C.K. (2002) A comprehensive modeling study of iso-octane oxidation. Combust. Flame, 129, 253-280.
Dagaut, P., Reuillon, M., and Cathonnet, M. (1994) High pressure oxidation of liquid fuels from low to high temperatures. 2. Mixtures of n-heptane and iso-octane. Combust. Sci. Technol., 95, 233-260.
Glassman, I. (1996) Combustion, Academic Press, San Diego, USA, p. 84.
Glaude, P.A., Warth, V., Fournet, R., Battin-Leclerc, F., Scacchi, G., and Come, G.M. (1998) Modeling of the oxidation of n-octane and n-decane using an automatic generation of mechanisms. Inc. Int. J. Chem. Kinet., 30, 949-959.
Griffiths, J.F., MacNamara, J.P., Sheppard, C.G.W., Turton, D.A., and Whitaker, B.J. (2002) The relationship of knock during controlled autoignition to temperature inhomogeneities and fuel reactivity, Fuel, 81, 2219-2225.
Huang, Y., Sung, C.J., and Eng, J.A. (2004) Dilution limits of n-butane/air mixtures under conditions relevant to HCCI combustion. Combust. Flame, 136, 457-466.
Lovas, T., Nilsson, D., and Mauss, F. (2000) Automatic reduction procedure for chemical mechanisms applied to premixed methane/air flames. Proc. Combust. Inst., 28, 1809-1815.
Lu, T., Ju, Y., and Law, C.K. (2001) Complex CSP for chemistry reduction and analysis. Combust. Flame, 126, 1445-1455.
Machrafi, H., Lombaert, K., Cavadias, S., Guibert, P., and Amouroux, J. (2005) Reduced chemical reaction mechanisms: Experimental and HCCI modelling investigations of autoignition processes of iso-octane in internal combustion engines. Fuel, 84(18), 2330-2340.
Machrafi, H., Lombaert, K., Cavadias, S., and Guibert, P. (2005) Reduced Chemical Reaction Mechanisms: Experimental and HCCI Modelling Investigations of Autoignition Processes of n-Heptane in Internal Combustion Engines, 7th International Conference on Engines for Automobiles, Capri, Italy. SAE 2005-24-035.
Ogink, R. and Golovitchev, V. (2001) Generalised Skeletal Reaction Mechanism For Aliphatic Hydrocarbons (From Methane To Iso-octane) For CFD Engine Modelling. First Biennial Meeting of The Scandinavian-Nordic Section of the Combustion Institute, Göteborg, Sweden, 151-156.
Ranzi, E., Faravelli, T., Gaffuri, P., and Sogaro, A. (1995) Low-temperature combustion: Automatic generation of primary oxidation reactions and lumping procedures. Combust. Flame, 102, 179-192.
Ranzi, E., Gaffuri, P., Faravelli, T., and Dagaut, P. (1995) A wide-range modeling study of n-heptane oxidation, Combust. Flame, 103, 91-106.
Simon, Y., Scacchi, G., and Baronnet, F. (1996) Etude des réactions d'oxydation du n-heptane et de l'isooctane. Can. J. Chem., 74, 1391-1402.
Soyhan, H.S., Mauss, F., and Sorusbay, C. (2002) Chemical kinetic modeling of combustion in internal combustion engines using reduced chemistry, Combust. Sci. and Technol., 174(11-12), 73-91.
Tanaka, S., Ayala, F., and Keck, J.C. (2003) A reduced chemical kinetic model for HCCI combustion of primary reference fuels in a rapid compression machine. Combust. Flame, 133, 467-481.
Tanaka, S., Ayala, F., Keck, J.C., and Heywood, J.B. (2003) Two-stage ignition in HCCI combustion and HCCI control by fuels and additives. Combust. Flame, 132, 219-239.