The He(I), Threshold photoelectron and Constant Ion State spectroscopy of Vinylchloride (C2H3Cl).

Locht, Robert; Leyh, Bernard; Hottmann, K.; Baumgärtel, H.

doi:10.1016/S0301-0104(97)00128-6

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The He(I), Threshold photoelectron and Constant Ion State spectroscopy of Vinylchloride (C2H3Cl).

Locht, Robert; Leyh, Bernard; Hottmann, K. et al.

1997 • In Chemical Physics, 220, p. 217-232

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/915

DOI
10.1016/S0301-0104(97)00128-6

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Keywords :

He(I)-photoelectron; Threshold photoelectron; CIS spectrum; Synchrotron radiation; C2H3Cl

Abstract :

[en] Using synchrotron radiation the threshold photoelectron (TPES) spectrum and constant ion state (CIS) spectroscopy of C2H3Cl are reported. For comparison, the He(I) photoelectron spectrum has also been measured and reexamined. The threshold photoelectron spectrum has been measured between 9.0 and 25.0 eV and the photon energy range of 9.9-12.0 eV has been investigated in detail. Many features have been identified and tentatively assigned with the help of the photoabsorption spectroscopic results. These data were compared with the well-resolved He(I) photoelectron spectrum. The fine structure observed in the two first ionic states is assigned to progressions belonging partially to previously unobserved vibration normal modes. State-selected CIS spectra have been recorded for the first vibronic states between 10.0 and 11.67 eV. They exhibit fine structure assigned to autoionization of Rydberg states.

Research Center/Unit :

Laboratoire de Dynamique Moléculaire

Disciplines :

Chemistry

Author, co-author :

Locht, Robert ; Université de Liège - ULiège > Département de Chimie (Faculté des sciences) > Laboratoire de Dynamique Moléculaire (Sciences)

Leyh, Bernard ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de dynamique moléculaire

Hottmann, K.

Baumgärtel, H.; Freie Universität Berlin > Institut für Physikalische Chemie

Language :

English

Title :

The He(I), Threshold photoelectron and Constant Ion State spectroscopy of Vinylchloride (C2H3Cl).

Alternative titles :

[fr] Les spectres photoélectronique à He(I)-, de seuil et à état ionique constant du Chlorure de Vinyle (C2H3Cl).

Publication date :

1997

Journal title :

Chemical Physics

ISSN :

0301-0104

Publisher :

Elsevier Science, Amsterdam, Netherlands

Volume :

220

Pages :

217-232

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science/journal/03010104

Funders :

FRFC, BMFT, EU Contract n° chge-CT93-0027 in the EU-HCM Programme.

Commentary :

- PDF-version of Editor's Postprint available on request - Version-pdf du tiré-à-part disponible sur demande

Available on ORBi :

since 12 November 2008

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Bibliography

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