[en] The desorption behaviour of the diblock polyampholyte PMAA-b-PDMAEMA, poly(methacrylic acid)-block-poly ((dimethylamino)ethyl methacrylate), preadsorbed on silicon substrates was investigated under the influence of several desorption agents. The investigated polyampholyte is known to adsorb in regular structures directly from aqueous solutions onto silicon substrates. While the adsorption process is mainly determined by electrostatic interactions, two kinds of desorption mechanism should be assumed. The first mechanism is based on changed electrostatic conditions caused for instance by a strong change in pH of the aqueous solution. The other mechanism is observed after treatment with hydrophobic organic solvent, which leads to the desorption of hydrophobic adsorbed polyampholyte chains, while the electrostatically attached ones will not be influenced. To complete the desorption experiments with organic solvents also adsorption experiments from analogous polyampholytic solutions in the same organic solvents were performed. The amount of polymer at the substrate surface after adsorption or desorption experiments was determined using ellipsometry. Atomic force microscopy (AFM) was used to investigate the surface topography of dried samples after the desorption process.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Mahltig, Boris; Gesellschaft zur Förderung von Medizin-, Bio- und Umwelttechnologien, Dresden, Germany
Gohy, Jean-François; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Pfuetze, G.; Institut für Polymerforschung, Dresden, Germany
Stamm, Manfred; Institut für Polymerforschung, Dresden, Germany
Language :
English
Title :
Desorption behaviour of regular adsorbed polyampholytic layers
The DFG priority program “Polyelectrolyte” (grant IIC10-322 1009) BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique ESF - European Science Foundation
Commentary :
The original publication is available at http://www.springerlink.com/content/r22011l1604j2736/fulltext.pdf. The authors acknowledge Journal of Polymer Research (Kluwer Academic Press) for allowing them to archive this paper.
E. F. Murphy, J. R. Lu, J. Brewer, J. Russell and J. Penfold, Langmuir, 15, 1313 (1999).
A. V. Dobrynin, M. Rubinstein and J.-F. Joanny, Macromolecules, 30, 4332 (1997).
R. R. Netz and J.-F. Joanny, Macromolecules, 31, 5123 (1998).
N. L. Fillipova, Langmuir, 14, 1162 (1998).
N. G. Hoogeveen, M. A. Cohen Stuart and G. J. Fleer, J. Colloid Interface Sci., 182, 133 (1996).
N. G. Hoogeveen, M. A. Cohen Stuart and G. J. Fleer, J. Colloid Interface Sci., 182, 146 (1996).
E. Pefferkorn, J. Colloid Interface Sci., 261, 197 (1999).
T. Hugel, M. Gorsholz, H. Clausen-Schaumann, A. Pfau, H. Gaub and M. Seitz, Macromolecules, 34, 1039 (2001).
S. E. Kudaibergenov, Adv. Polym. Sci., 144, 115 (1999).
K. A. Vaynberg, N. J. Wagner and R. Sharma, Biomacromolecules, 1, 466 (2000).
A. Böker, A. H. E. Müller and G. Krausch, Macromolecules, 34, 7477 (2001).
S. B. Moldakarimov, E. Y. Kramarenko, A. R. Khokhlov and S. E. Kudaibergenov, Macromol. Theory Simul., 10, 780 (2001).
Y. Kamiyama and J. Israelachvilli, Macromolecules, 25, 5081 (1992).
J. Blaakmeer, M. A. Cohen Stuart and G. J. Fleer, J. Colloid Interface Sci., 140, 314 (1990).
F. Le Berre, M. Malmsten and E. Blomberg, Langmuir, 17, 69 (2001).
T. Kato, M. Kawaguchi, A. Takahashi, T. Onabe and H. Tanaka, Langmuir, 15, 4302 (1999).
S. Neyret, L. Ouali, F. Candau and E. Pefferkorn, J. Colloid Interface Sci., 176, 86 (1995).
M. A. Cohen Stuart, G. J. Fleer, J. Lyklema, W. Norde and J. M. H. M. Scheutjens, Adv. Colloid Interface Sci., 34, 477 (1991).
A. V. Dobrynin, S. P. Obukhov and M. Rubinstein, Macromolecules, 32, 5689 (1999).
Y. Kantor, M. Kardar and H. Li, Phys. Rev. B, 49, 1383 (1994).
M. Tanaka, A. Yu. Grosberg and T. Tanaka, Langmuir, 15, 4052 (1999).
M. O. Khan, T. Akesson and B. Jönsson, Macromolecules, 34, 4216 (2001).
E. B. Zhulina, A. V. Dobrynin and M. Rubinstein, J. Phys. Chem. B, 105, 8917 (2001).
A. V. Dobrynin, E. B. Zhulina and M. Rubinstein, Macromolecules, 34, 627 (2001).
P. G. Higgs and J.-F. Joanny, J. Chem. Phys., 94, 1543 (1991).
O. J. Rojas, R. D. Neuman and P. M. Claesson, J. Colloid Interface Sci., 237, 104 (2001).
O. J. Rojas, M. Ernstsson, R. D. Neuman and P. M. Claesson, Langmuir, 18, 1604 (2002).
D. F. Siqueira and M. Stamm, Colloid Polym. Sci., 274, 588 (1996).
J. F. Douglas, H. E. Johnson and S. Granick, Science, 262, 2010 (1993).
M. Santore and Z. Fu, Macromolecules, 30, 8516 (1997).
R. A. L. Jones and W. R. Richards, Polymers at Surfaces and Interfaces. Cambridge University Press, Cambridge, 1999.
B. Mahltig, P. Müller-Buschbaum, M. Wolkenhauer, O. Wunnicke, S. Wiegand, J.-F. Gohy, R. Jérôme and M. Stamm, J. Colloid Interface Sci., 242, 36 (2001).
B. Mahltig, C. Werner, M. Müller, R. Jérôme and M. Stamm, J. Biomater. Sci. Polymer Edn., 12, 995 (2001).
B. Mahltig, J.-F. Gohy, R. Jérôme and M. Stamm, J. Polym. Sci. B, 39, 709 (2001).
S. Creutz, P. Teyssié and R. Jérôme, Macromolecules, 30, 6 (1997).
S. Creutz, J. van Stam, S. Antoun, F. C. De Schryer and R. Jérôme, Macromolecules, 30, 4078 (1997).
S. Antoun, P. Teyssié and R. Jérôme, Macromolecules, 30, 1556 (1997).
B. Mahltig, J.-F. Gohy, R. Jérôme, C. Bellmann and M. Stamm, Colloid Polym. Sci., 278, 502 (2000).
B. Mahltig, R. Jérôme and M. Stamm, Phys. Chem. Chem. Phys., 3, 4371 (2001).
H. Walter, C. Harrats, P. Müller-Buschbaum, R. Jérôme and M. Stamm, Langmuir, 15, 1260 (1999).
M. Harke, R. Teppner, O. Schulz, H. Motschmann and H. Orendi, Rev. Sci. Instrum., 68, 3130 (1997).
E. P. C. Mes, W. T. Kok, H. Poppe and R. Tijssen, J. Polym. Sci. B, 37, 593 (1999).
M. A. V. Axelos, D. Tchoubar and J. Y. Bottero, Langmuir, 5, 1186 (1989).
N. Dan and M. Tirrel, Macromolecules, 26, 4310 (1993).
C. Amiel, M. Sikka, J. W. Schneider, Y.-H. Tsao, M. Tirrel and J. W. Mays, Macromolecules, 28, 3125 (1995).
