[en] Polymer modification of carbon nanotubes is accomplished using a grafting-to approach. Radicals formed by the thermolysis of poly(2-vinylpyridine) terminated with a radical-stabilizing nitroxide can react with the surface of nanotubes, resulting in grafting densities up to 12 wt.-%. The modified nanotubes, which are easily dispersed in water, can immobilize metal nanoclusters on their surfaces.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Lou, Xudong; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Pagnoulle, Christophe; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Bocharova, Vera; Institut für Polymerforschung, Dresden, Germany
Kiriy, Anton; Institut für Polymerforschung, Dresden, Germany
Stamm, Manfred; Institut für Polymerforschung, Dresden, Germany
Language :
English
Title :
Surface modification of multiwalled carbon nanotubes by poly(2-vinylpyridine): Dispersion, selective deposition, and decoration of the nanotubes
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique The "Région Wallonne" in the frame of the Nanotechnologies ENABLE program DFG - Deutsche Forschungsgemeinschaft
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