Dissociative photoionization; Collision activated dissociation; Kinetic energy release; Theoretical calculations; 1,1- and 1,2-C2H2F2
Abstract :
[en] The collision activated dissociation and dissociative photoionization of 1,1- and 1,2-C2H2F2 in the HF-loss channel are investigated. The measured KER ditributions are interpreted by the opening of two competitive reaction channels leading to two C2HF+ isomers. This hypothesis is checked by ab initio calculations.
Research Center/Unit :
Laboratoire de Dynamique Moléculaire
Disciplines :
Chemistry
Author, co-author :
Leyh, Bernard ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de dynamique moléculaire
Lorquet, Andrée ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de dynamique moléculaire
Lorquet, Jean-Claude ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)
Locht, Robert ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)
Language :
English
Title :
Dissociation of Difluoroetylene Cations: an ion-neutral complex along the fluoroethylidene+ + HF reaction path.
Publication date :
2000
Event name :
15th International Mass Spectrometry Conference
Event organizer :
Spanish Society of Mass Spectrometry
Event place :
Barcelona, Spain
Event date :
27 August-1 September 2000
Audience :
International
Main work title :
15th International Mass Spectrometry Conference: Book of Abstracts
Author, co-author :
Gelpi, E.
Collection name :
Volume 15.
Pages :
247
Funders :
ARC, FRFC
Commentary :
- PDF-version of Editor's Postprint available on request
- Version-pdf du tiré-à-part disponible sur demande
