[en] In order to assess the geothermometric potential of the Na-2(Mn2-2x Fe1+2x )(PO4)(3) system (x = 0-1), which represents the compositions of natural weakly oxidized alluaudites, we performed hydrothermal experiments between 400 and 800 degrees C, at 1 kbar, under an oxygen fugacity (f(O-2)) controlled by the Ni-NiO (NNO), Fe2O3-Fe3O4 (HM), Cu2O-CuO (CT), and Fe-Fe3O4 (MI) buffers. When f(O-2) is controlled by NNO, single-phase alluaudites crystallize at 400 and 500 degrees C, whereas the association alluaudite + maricite appears between 500 and 700 degrees C. The limit between these two fields corresponds to the maximum temperature that can be reached by alluaudites in granitic pegmatites, because maricite has never been observed in these geological environments. Because alluaudites are very sensitive to variations of oxygen fugacity, the field of hagendorfite, Na2MnFe2+Fe3+(PO4)(3), has been positioned in the f(O-2)-T diagram, and provides a tool that can be used to estimate the oxygen fugacity conditions that prevailed in granitic pegmatites during the crystallization of this phosphate.
Disciplines :
Earth sciences & physical geography
Author, co-author :
Hatert, Frédéric ; Université de Liège - ULiège > Département de géologie > Minéralogie et cristallochimie
Fransolet, André-Mathieu ; Université de Liège - ULiège > Département de géologie > Minéralogie et cristallochimie
Maresch, Walter W.
Language :
English
Title :
The stability of primary alluaudites in granitic pegmatites: an experimental investigation of the Na-2(Mn2-2x Fe1+2x )(PO4)(3) system
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Bibliography
Antenucci D (1992) Synthèse et cristallochimie de composés à structure alluaudite. Incidences dans les processus d'altération des phosphates Fe-Mn des pegmatites granitiques. PhD thesis, University of Liège, 259 p
Araki T, Moore PB (1981) Fillowite, Na 2 Ca(Mn,Fe) 2+ 7 (PO 4 ) 6 : Its crystal structure. Am Mineral 66:827-842
Auernhammer M, Effenberger H, Hentschel G, Reinecke T, Tillmanns E (1993) Nickenichite, a new arsenate from the Eifel, Germany. Mineral Petrol 48:153-166
Baldwin JR, Von Knorring O (1983) Compositional range of Mn-garnet in zoned granitic pegmatites. Can Mineral 21:683-688
Boury P (1981) Comportement du fer et du manganèse dans les associations de phosphates pegmatitiques. Master thesis, University of Liegrave;ge, 118 p
Bridson JH, Quinlan SE, Tremaine PR (1998) Synthesis and crystal structure of marićite and sodium iron(III) hydroxyphosphate. Chem Mater 10:763-768
Brunet F, Chopin C, Seifert F (1998) Phase relations in the MgO-P 2 O 5 -H 2 O system and the stability of phosphoellenbergerite: Petrological implications. Contrib Mineral Petrol 131:54-70
Burnham CW (1991) LCLSQ version 8.4, least-squares refinement of crystallographic lattice parameters. Dept Earth Planetary Sciences, Harvard University, 24 p
Černyacute; P (1991) Rare-element granitic pegmatites. Part I: Anatomy and internal evolution of pegmatite deposits. Geosci Can 18(2):49-67
Černyacute; P, Meintzer RE, Anderson AJ (1985) Extreme fractionation in rare-element granitic pegmatites: Selected examples of data and mechanisms. Can Mineral 23:381-421
Černúte; P, Ercit TS, Vanstone PT (1996) Petrology and mineralization of the Tanco rare-element pegmatite, Southeastern Manitoba. Field trip guidebook A4, Geological Association of Canada/ Mineralogical Association of Canada Annual Meeting, Winnipeg, Manitoba, May 27-29, 1996, 63 p
Engel G (1976) Untersuchungen zur Kristallchemie verschiedener Phosphate NaM II PO 4 und verwandter Verbindungen. N Jb Mineral Abh 127(2):197-211
Eugster HP (1957) Heterogeneous reactions involving oxidation and reduction at high pressures and temperatures. J Chem Phys 26:1760-1761
Fontan F (1978) Etude minéralogique et essais expérimentaux sur des phosphates de fer et de manganèse des pegmatites des Jebilet (Maroc) et des Pyrénées (France). PhD thesis, Université Paul-Sabatier, Toulouse, 250 p
Fontan F, Huvelin P, Orliac M, Permingeat F (1976) La ferrisicklérite des pegmatites de Sidi-Bou-Othmane (Jebilet, Maroc) et le groupe des minéraux à structure de triphylite. Bull Soc française Minéral Cristall 99:274-286
Fransolet A-M (1975) Etude minéralogique et pétrologique des phosphates de pegmatites granitiques. PhD thesis, University of Liège, 333 p
Fransolet A-M (1977) Le problème génétique des alluaudites. Bull Soc franccedil;aise Minéral Cristall 100:348-352
Fransolet A-M, Abraham K, Speetjens J-M (1985) Evolution génétique et signification des associations de phosphates de la pegmatite d'Angarf-Sud, plaine de Tazenakht, Anti-Atlas, Maroc. Bull Minéral 108:551-574
Fransolet A-M, Keller P, Fontan F (1986) The phosphate mineral associations of the Tsaobismund pegmatite, Namibia. Contrib Mineral Petrol 92:502-517
Fransolet A-M, Antenucci D, Fontan F, Keller P (1994) New relevant data on the crystal chemistry, and on the genetical problem of alluaudites and wyllieites. In: Abstracts of the 16th IMA general meeting, Pisa, pp 125-126
Fransolet A-M, Keller P, Fontan F (1997) The alluaudite group minerals: their crystallochemical flexibility and their modes of formation in the granite pegmatites. In: Abstracts of the meeting "phosphates: biogenic to exotic", London
Fransolet A-M, Fontan F, Keller P, Antenucci D (1998) La série johnsomervilleite-fillowite dans les associations de phosphates de pegmatites granitiques de l'Afrique centrale. Can Mineral 36:355-366
Fransolet A-M, Hatert F, Fontan F (2004) Petrographic evidence for primary hagendorfite in an unusual assemblage of phosphate minerals, Kibingo granitic pegmatite, Rwanda. Can Mineral 42:697-704
Ginzbourg AI (1960) Specific geochemical features of the pegmatitic process. In: International Geological Congress, report of the 21st session, Norden, Part 17, pp 111-121
Hatert F (2002) Cristallochimie et synthèse hydrothermale d'alluaudites dans le système Na-Mn-Fe-P-O: Contribution au problème de la genèse de ces phosphates dans les pegmatites granitiques. PhD thesis, University of Liège, 247 p
Hatert F (2004a) The crystal chemistry of lithium in the alluaudite structure: A study of the (Na 1-x Li x ) 1.5 Mn 1.5 Fe 3+ (PO 4 ) 3 solid solution (x = 0 to 1). Mineral Petrol 81:205-217
Hatert F (2004b) Etude cristallochimique et synthèse hydrothermale des alluaudites: Contribution nouvelle au problème geacute;nétique des phosphates de fer et de manganèse dans les pegmatites granitiques et, partant, à celui de l'évolution de ces gisements. Mém Acad royale Sci Belgique, Cl Sci, Coll in-8, 3ème seacute;rie XXI: 96 p
Hatert F, Keller P, Lissner F, Antenucci D, Fransolet A-M (2000a) First experimental evidence of alluaudite-like phosphates with high Li-content: The (Na 1-x Li x )MnFe 2 (PO 4 ) 3 series (x = 0 to 1). Eur J Mineral 12:847-857
Hatert F, Fransolet A-M, Grandjean F, Long GJ (2000b) Solid state syntheses and crystal chemistry of phosphates in the Na 2 O-MnO-Fe 2 O 3 -P 2 O 5 system: preliminary results. J Conf Abstr 5:46
Hatert F, Antenucci D, Fransolet A-M, Liègeois-Duyckaerts M (2002) The crystal chemistry of lithium in the alluaudite structure: A study of the (N 1-x Li x )CdIn 2 (PO 4 ) 3 solid solution (x = 0 to 1). J Solid State Chem 163:194-201
Hatert F, Hermann RP, Long GJ, Fransolet A-M, Grandjean F (2003) An X-ray Rietveld, infrared, and Mössbauer spectral study of the NaMn(Fe 1-x In x ) 2 (PO 4 ) 3 alluaudite-like solid solution. Am Mineral 88:211-222
Hatert F, Long GJ, Hautot D, Fransolet A-M, Delwiche J, Hubin-Franskin MJ, Grandjean F (2004) A structural, magnetic, and Mössbauer spectral study of several Na-Mn-Fe-bearing alluaudites. Phys Chem Miner 31:487-506
Hatert F, Rebbouh L, Hermann RP, Fransolet A-M, Long GJ, Grandjean F (2005) Crystal chemistry of the hydrothermally synthesized Na 2 (Mn 1-x Fe 2+ x ) 2 Fe 3+ (PO 4 ) 3 alluaudite-type solid solution. Am Mineral 90:653-662
Héreng P (1989) Contribution à l'étude minéralogique de phosphates de fer et de manganèse de la pegmatite de Buranga, Rwanda. Master thesis, University of Liège, 101 p
Hermann RP, Hatert F, Fransolet A-M, Long GJ, Grandjean F (2002) Mössbauer spectral evidence for next-nearest neighbor interactions within the alluaudite structure of Na 1-x LixMnFe 2 (PO 4 ) 3 . Solid State Sci 4:507-513
Huvelin P, Orliac M, Permingeat F (1972) Ferri-alluaudite calcifère de Sidi-bou-Othmane (Jebilet, Maroc). Notes Serv géol Maroc 32(241):35-49
Johnson CL, Lauretta DS, Buseck P (2000) A high-resolution transmission electron microscopy study of fine-grained phosphates in metal from the Bishunpur LL3.1 ordinary chondrite. In: 63rd Annual Meteoritical Society Meeting, Chicago, Illinois, p 5303
Keller P, Von Knorring O (1989) Pegmatites at the Okatjimukuju farm, Karibib, Namibia. Part I: Phosphate mineral associations of the Clementine II pegmatite. Eur J Mineral 1:567-593
Keller P, Fransolet A-M, Fontan F (1994) Triphylite-lithiophilite and triplite-zwieselite in granitic pegmatites: Their textures and genetic relationships. N Jb Mineral Abh 168(2):127-145
Keller P, Hatert F, Lissner F, Schleid T, Fransolet A-M (2006) Hydrothermal synthesis and crystal structure of Na(Na,Mn) 7 Mn 22 (PO 4 ) 180 0.5H 2 O, a new compound of fillowite structure type. Eur J Mineral (in press)
Khorari S (1997) Cristallochimie des arséniates de structure alluaudite. PhD thesis, University of Liège
Lahti SI (1981) On the granitic pegmatites of the Eräjärvi area in Orivesi, southern Finland. Geol Surv Finland Bull 314:82
Lauretta DS, Buseck PR (2000) Chondrule formation and volatile recondensation recorded in an opaque assemblage from the Bishunpur chondrite. Lunar and Planetary Science XXXI, Houston, Texas, p 1136
Le Page Y, Donnay G (1977) The crystal structure of the new mineral marićite, NaFePO 4 . Can Mineral 15:518-521
London D (1986) Magmatic-hydrothermal transition in the Tanco rare-element pegmatite: Evidence from fluid inclusions and phase-equilibrium experiments. Am Mineral 71:376-395
London D, Wolf MB, Morgan GB, Gallego Garrido M (1999) Experimental silicate-phosphate equilibria in peraluminous granitic magmas, with a case study of the Alburquerque batholith at Tres Arroyos, Badajoz, Spain. J Petrol 40:215-240
London D, Morgan GB, Wolf MB (2001) Amblygonite-montebrasite solid solutions as monitors of fluorine in evolved granitic and pegmatitic melts. Am Mineral 86:225-233
Mason B (1941) Minerals of the Varuträsk pegmatite. XXIII. Some iron-manganese phosphate minerals and their alteration products, with special reference to material from Varuträsk. Geol Fören Stockholm Förh 63:117-175
Moore PB (1971) Crystal chemistry of the alluaudite structure type: contribution to the paragenesis of pegmatite phosphate giant crystals. Am Mineral 56:1955-1975
Moore PB (1972) Natrophilite, NaMnPO 4 , has ordered cations. Am Mineral 57:1333-1344
Moore PB, Ito J (1979) Alluaudites, wyllieites, arrojadites: Crystal chemistry and nomenclature. Mineral Mag 43:227-235
Morgan GB, London D (1987) Alteration of amphibolic wallrocks around the Tanco rare-element pegmatite, Bernic Lake, Manitoba. Am Mineral 72:1097-1121
Moring J, Kostiner E (1986) The crystal structure of NaMnPO 4 . J Solid State Chem 61:379-383
Norton FJ (1955) Dissociation pressures of iron and copper oxides. General Electric Research Laboratory Report, 55-R1-1248
O'Neill HSC (1988) Systems Fe-O and Cu-O: Thermodynamic data for the equilibria Fe-"FeO", Fe-Fe 3 O 4 , "FeO"-Fe 3 O 4 ,,Fe 3 O 4 , -Fe 2 O 3 , Cu-Cu 2 O, and Cu 2 O-CuO from emf measurements. Am Mineral 73:470-486
O'Neill HSC, Pownceby MI (1993) Thermodynamic data from redox reactions at high temperatures. I. An experimental and theoretical assessment of the electrochemical method using stabilized zirconia electrolytes, with revised values for the Fe-"FeO", Co-CoO, Ni-NiO and Cu-Cu 2 O oxygen buffers, and new data for the W-WO 2 buffer. Contrib Mineral Petrol 114:296-314
Quensel P (1937) Minerals of the Varuträsk Pegmatite. I. The lithium-manganese phosphates. Geol Fören Stockholm Förh 59(1):77-96
Quensel P (1940) Minerals of the Varuträsk Pegmatite. XVII. Further comments on the minerals varulite and alluaudite. Geol Fören Stockholm Förh 62(3):297-302
Quensel P (1957) The paragenesis of the Varuträsk pegmatite, including a review of its mineral assemblage. Arkiv für Mineralogi och Geologi 2(2):9-125
Redhammer GJ, Tippelt G, Bernroider M, Lottermoser W, Amthauer G, Roth G (2005) Hagendorfite (Na,Ca)MnFe2 (PO 2 ) 3 from type locality Hagendorf (Bavaria, Germany): Crystal structure determination and 57 Fe Mössbauer spectroscopy. Eur J Mineral 17:915-932
Robinson GW, Velthuizen JV, Ansell HG, Sturman BD (1992) Mineralogy of the Rapid Creek and Big Fish River area, Yukon Territory. Mineral Rec 23(4):1-47
Roda E, Fontan F, Pesquera A, Velasco F (1996) The phosphate mineral association of the granitic pegmatites of the Fregeneda area (Salamanca, Spain). Mineral Mag 60:767-778
Roda Robles E, Fontan F, Pesquera Pérez A, Keller P (1998) The Fe-Mn phosphate associations from the Pinilla de Fermoselle pegmatite, Zamora, Spain: Occurrence of kryzhanovskite and natrodufrénite. Eur J Mineral 10:155-167
Roda E, Pesquera A, Gil-Crespo PP, Torres-Ruiz J, Fontan F (2005) Origin and internal evolution of the Li-F-Be-B-P-bearing Pinilla de Fermoselle pegmatite (Central Iberian Zone, Zamora, Spain). Am Mineral 90:1887-1899
Solodovnikov SF, Klevtsov PV, Solodovnikova ZA, Glinskaya LA, Klevtsova RF (1998) Binary molybdates K 4 M 2+ (MoO 4 ) 3 (M 2+ = Mg, Mn, Co) and crystal structure of K 2 Mn(MoO 3 ) 3 . J Struct Chem 39(2):230-237
Stefanidis T, Nord AG (1984) Structural studies of thortveitite-like dimanganese diphosphate, Mn 2 P 2 O 7 Acta Crystallogr C40:1995-1999
Sturman BD, Mandarino JA, Corlett MI (1977) Marićite, a sodium iron phosphate from the Big Fish River area, Yukon Territory, Canada. Can Mineral 15:396-398
Tsyrenova GD, Solodovnikov SF, Zolotova ES, Tsybikova BA, Bazarova ZG (2000) Phase formation in the K 2 O(K 2 CO 3 ) -CdO-MoO 3 system. Russ J Inorg Chem 45(1):103-108
Tuttle OF (1949) Two pressure vessels for silicate-water studies. Geol Soc Am Bull 60:1727-1729
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