2003 • In Anton, J.; Cederquist, H.; Larsson, M.et al. (Eds.) 23rd International Conference on the Photonic, Electronic and Atomic Collisions: Book of Abstracts.
Ergodicity; Kinetic Energy Release Distribution; Phase Space sampling; Maximum Entropy; Ergodicity Index
Abstract :
[en] The experimental KER and the statistical distributions are compared by the Maximum Entropy Method. An Ergodicity Index F(E) is defined to measure the phase space sampling efficiency. This is applied to the KERD of C4H4+ cation produced by the C5H5N+ -> HCN+C4H4+ fragmentation path. In this particular case the F(E) is found to decrease steadily with increasing internal energy.
Research center :
Laboratoire de dynamique Moléculaire
Disciplines :
Chemistry
Author, co-author :
Gridelet, E.
Locht, Robert ; Université de Liège - ULiège > Chimie (Faculté des sciences) > Laboratoire de Dynamique Moléculaire (Sciences)
Lorquet, Andrée ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de dynamique moléculaire
Lorquet, Jean-Claude ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)
Leyh, Bernard ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de dynamique moléculaire
Language :
English
Title :
How ergodic is the Fragmentation of the Pyridine Cation ? A Maximum Entropy Ananlysis
Publication date :
2003
Event name :
23rd International Conference on Photonic, Electronic and Atomic Collisions
Event organizer :
Université de Stockholm
Event place :
Stockholm, Sweden
Event date :
23-29 July 2003
Audience :
International
Main work title :
23rd International Conference on the Photonic, Electronic and Atomic Collisions: Book of Abstracts.
Author, co-author :
Anton, J.
Cederquist, H.
Larsson, M.
Lindroth, E.
Mannervik, S.
Schmidt, H.
Schuch, R.
Pages :
Th011
Peer reviewed :
Peer reviewed
Funders :
ARC
Commentary :
- PDF-version of Editor's Postprint available on request
- Version-pdf du tiré-à-part disponible sur demande
