Nitrate; Groundwater; Modelling; Chalk; Environmental tracers; European Water Frazmework Directive
Résumé :
[en] Regional degradation of groundwater resources by nitrate has become one of the main challenges for water managers worldwide. Regulations have been defined to reverse observed nitrate trends in groundwater bodies, such as the Water Framework Directive and the Groundwater Daughter Directive in the European Union. In such a context, one of the main challenges remains to develop efficient approaches for groundwater quality assessment at regional scale, including quantitative numerical modelling, as a decision support for groundwater management. A new approach combining the use of environmental tracers and the innovative ‘Hybrid Finite Element Mixing Cell’ (HFEMC) modelling technique is developed to study and forecast the groundwater quality at the regional scale, with an application to a regional chalk aquifer in the Geer basin in Belgium. Tritium data and nitrate time series are used to produce a conceptual model for regional groundwater flow and contaminant transport in the combined unsaturated and saturated zones of the chalk aquifer. This shows that the spatial distribution of the contamination in the Geer basin is essentially linked to the hydrodynamic conditions prevailing in the basin, more precisely to groundwater age and mixing and not to the spatial patterns of land use or local hydrodispersive processes. A three-dimensional regional scale groundwater flow and solute transport model is developed. It is able to reproduce the spatial patterns of tritium and nitrate and the observed nitrate trends in the chalk aquifer and it is used to predict the evolution of nitrate concentrations in the basin. The modelling application shows that the global inertia of groundwater quality is strong in the basin and trend reversal is not expected to occur before the 2015 deadline fixed by the European Water Framework Directive. The expected time required for trend reversal ranges between 5 and more than 50 years, depending on the location in the basin and the expected reduction in nitrate application. To reach a good chemical status, nitrate concentrations in the infiltrating water should be reduced as soon as possible below 50mg/l; however, even in that case, more than 50 years is needed to fully reverse upward trends.
Centre/Unité de recherche :
Aquapôle - ULiège
Disciplines :
Géologie, ingénierie du pétrole & des mines
Auteur, co-auteur :
Orban, Philippe ; Université de Liège - ULiège > Département Argenco : Secteur GEO3 > Hydrogéologie & Géologie de l'environnement
Brouyère, Serge ; Université de Liège - ULiège > Département Argenco : Secteur GEO3 > Hydrogéologie & Géologie de l'environnement
Batlle Aguilar, Jordi ; Université de Liège - ULiège > Département Argenco : Secteur GEO3 > Hydrogéologie & Géologie de l'environnement
Couturier, Julie ; Université de Liège - ULiège > Département Argenco : Secteur GEO3 > Hydrogéologie & Géologie de l'environnement
Goderniaux, Pascal ; Université de Liège - ULiège > Département Argenco : Secteur GEO3 > Hydrogéologie & Géologie de l'environnement
Leroy, Mathieu ; Université de Liège - ULiège > Département Argenco : Secteur GEO3 > Hydrogéologie & Géologie de l'environnement
Maloszewski, Piotr
Dassargues, Alain ; Université de Liège - ULiège > Département Argenco : Secteur GEO3 > Hydrogéologie & Géologie de l'environnement
Langue du document :
Anglais
Titre :
Regional transport modelling for nitrate trend assessment and forecasting in a chalk aquifer
Date de publication/diffusion :
2010
Titre du périodique :
Journal of Contaminant Hydrology
ISSN :
0169-7722
Maison d'édition :
Elsevier Science, Amsterdam, Pays-Bas
Volume/Tome :
118
Pagination :
79-93
Peer reviewed :
Peer reviewed vérifié par ORBi
Intitulé du projet de recherche :
FP6 Project AquaTerra (Project nb. 55428)
Organisme subsidiant :
DG RDT - Commission Européenne. Direction Générale de la Recherche et de l'Innovation
AERM, 2005. Méthodes et procédures pour l'état des lieux des districts Rhin et Meuse - Sambre, Document de référence, Version finale approuvée par le comité de bassin du 4 février 2005 et approuvée par le préfet coordonnateur de bassin. Etat des lieux des districts Rhin et Meuse - partie française, AERM.
M.N. Almasri, and J.J. Kaluarachchi Modeling nitrate contamination of groundwater in agricultural watersheds Journal of Hydrology 343 2007 211 229
I.E. Amin, and M.E. Campana A general lumped parameter model for the interpretation of tracer data and transit time calculation in hydrologic systems Journal of Hydrology 179 1996 1 21
E.R. Anderman, M.C. Hill, and E.P. Poeter Two-dimensional advective transport in ground-water flow parameter estimation Ground Water 34 6 1996 1001 1009
K. Bajracharya, and A. Barry Note on common mixing cell models Journal of Hydrology 153 1994 189 214
M.E. Barrett, and R.J. Charbeneau A Parsimonious Model for Simulation of Flow and Transport in a Karst Aquifer 1996 Center for Research in Water Resources, Bureau of Engineering Research, The University of Texas at Austin Austin
R. Barthel, J. Jagelke, J. Götzinger, T. Gaiser, and A. Printz Aspects of choosing appropriate concepts for modelling groundwater resources in regional integrated water resources management - examples from the Neckar (Germany) and Ouémé catchment (Benin) Physics and Chemistry of the Earth 33 1-2 2008 92 114
J. Batlle-Aguilar, P. Orban, A. Dassargues, and S. Brouyère Identification of groundwater quality trends in a chalk aquifer threatened by intensive agriculture in Belgium Hydrogeology Journal 15 8 2007 1615 1627
P. Biver Etude phénoménologique et numérique de la propagation des polluants miscibles dans un milieu à porosité multiple (Phenomenological and Numerical Study of Miscible Contaminant Propagation in a Multi-Porosity Medium) 1993 University of Liège Liège (Belgium) 389 pp
H.P. Broers The spatial distribution of groundwater age for different geohydrological situations in the Netherlands: implications for groundwater quality monitoring at the regional scale Journal of Hydrology 299 2004 84 106
H.P. Broers, and B. van der Grift Regional monitoring of temporal changes in groundwater quality Journal of Hydrology 296 2004 192 220
Brouyère, S., 2001. Etude et modélisation du transport et du piégeage des solutés en milieu souterrain variablement saturé (Study and modelling of transport and retardation of solutes in variably saturated media). PhD Thesis, University of Liège, Liège, Belgium, 640 pp.
S. Brouyère Modelling the migration of contaminants through variably saturated dual-porosity, dual-permeability chalk Journal of Contaminant Hydrology 82 2006 195 219
S. Brouyère, G. Carabin, and A. Dassargues Climate change impacts on groundwater resources: modelled deficits in a chalky aquifer, Geer basin, Belgium Hydrogeology Journal 12 2004 123 134
S. Brouyère, A. Dassargues, and V. Hallet Migration of contaminants through the unsaturated zone overlying the Hesbaye chalky aquifer in Belgium: a field investigation Journal of Contaminant Hydrology 72 1-4 2004 135 164
S. Brouyère, P. Orban, S. Wildemeersch, J. Couturier, N. Gardin, and A. Dassargues The hybrid finite element mixing cell method: a new flexible method for modelling mine water problems Mine Water and the Environment 28 2009 102 114
M.E. Campana, N. Sadler, N.L. Ingraham, and R.L. Jacobson A deuterium-calibrated compartmental model of transient flow in a regional aquifer system Tracer Hydrology 1997 389 396
L.W. Canter Nitrates in Groundwater 1997 CRC Press USA
G. Carabin, and A. Dassargues Modeling groundwater with ocean and river interaction Water Resources Research 35 8 1999 2347 2358
E.F. Cassiraga, D. Fernandez-Garcia, and J.J. Gomez-Hernandez Performance assessment of solute transport upscaling methods in the context of nuclear waste disposal International Journal of Rock Mechanics and Mining Sciences 42 2005 756 764
M.A. Celia, E.T. Bouloutas, and R.L. Zarba A general mass-conservative numerical solution for the unsaturated flow equation Water Resources Research 26 7 1990 1483 1496
J.S. Christiansen, M. Thorsen, T. Clausen, S. Hansen, and J.C. Refsgaard Modelling of macropore flow and transport processes at catchment scale Journal of Hydrology 299 2004 136 158
A.L. Collins, and D.F. McGonigle Monitoring and modelling diffuse pollution from agriculture for policy support: UK and European experience Environmental Science & Policy 11 2 2008 97 101
G. Dagan Upscaling of dispersion coefficients in transport through heterogeneous formations Computational Methods in Water Resources 12 1994 431 439
A. Dassargues, and A. Monjoie The chalk in Belgium R.A. Downing, M. Price, G.P. Jones, The Hydrogeology of the Chalk of the North-West Europe 1993 Oxford University Press Oxford, UK 153 269 Chapter 8
S. Dautrebande, and C. Sohier Projet de recherche PIRENE, Rapport final 2004 University of Gembloux
S. Dautrebande, A. Dewez, V. Hallet, J. Guiot, F. Rouxhet, and A. Monjoie Programme Action Hesbaye. Final report of the EC-Life project 1996
DGRNE, 2005. District Hydrographique International de la Meuse. Tome I : État des lieux en Région wallonne.Analyse des pressions anthropiques sur les eaux souterraines, Ministère de la Région wallonne, Direction générale des Ressources naturelles et de l'Environnement.
C.J. Duffy, and L.W. Gelhar A frequency domain analysis of groundwater quality fluctuations: interpretation of field data Water Resources Research 22 7 1986 1115 1128
C.J. Duffy, and D.-H. Lee Base flow response from non-point source contamination: spatial variability in source, structure, and initial condition Water Resources Research 28 3 1992 905 914
B.A. Fretwell, W.G. Burgess, J.A. Barker, and N.L. Jefferies Redistribution of contaminants by a fluctuting water table in a micro-porous, double-porosity aquifer: field observations and model simulations Journal of Contaminant Hydrology 78 2005 27 52
K.K. Gardner, and R.M. Vogel Predicting ground water nitrate concentration from land use Ground Water 43 3 2005 343 352
Grath, J., Scheidleder, A., Uhlig, S., Weber, K., Kralik, M., Keimel, T. and Gruber, D., 2001. The EU Water Framework Directive: Statistical aspects of the identification of ground water pollution trends, and aggregation of monitoring results. Final report., Austrian Federal Ministry of Agriculture and Forestry, Environment and Water Management (Ref.: 41.046/01-IV1/00 and GZ 16 2500/2-I/6/00), European Comission (Grant Agreement Ref.: Subv 99/130794), in kind contributions by project partners., Vienna.
K.B. Hallberg, and D.R. Keeney Nitrate W.M. Alley, Regional Ground-Water quality 1993 Van Nostrand Reinhold New York 297 322
Hallet, V., 1998. Etude de la contamination de la nappe aquifère de Hesbaye par les nitrates: hydrogéologie, hydrochimie et modélisation mathématique des écoulements et du transport en milieu saturé (Contamination of the Hesbaye aquifer by nitrates: hydrogeology, hydrochemistry and mathematical modeling). PhD Thesis, University of Liège, Liège (Belgium), 361 pp.
V. Hallet, and A. Dassargues Effective porosity values used in calibrated transport simulations in a fissured and slightly karstified chalk aquifer Groundwater quality 1998 : Remediation and protection, Tübingen 1998
G.A. Harrington, G.R. Walker, A.J. Love, and A., N.K. A compartmental mixing-cell approach for the quantitative assessment of groundwater dynamics in the Otway Basin, South Australia Journal of Hydrology 214 1999 49 63
T. Harter, H. Davis, M.C. Mathews, and R.D. Meyer Shallow ground water quality on dairy farms with irrigated forage crops Journal of Contaminant Hydrology 55 2002 287 315
H.J. Henriksen, L. Troldborg, P. Nyegaard, T.O. Sonnenborg, J.C. Refsgaard, and B. Madsen Methodology for construction, calibration and validation of a national hydrologic model for Denmark Journal of Hydrology 280 2003 52 71
Hérivaux, C., Orban, P., Batlle-Aguilar, J., Brouyère, S. and Goderniaux, P., 2008. Socio-economic analysis integrating soil-water system modelling for the Geer catchment (Meuse, Walloon region) - diffuse nitrate pollution in groundwater. Deliverable I3.8, AquaTerra (Integrated Project FP6 no. 505428).
M.C. Hill Methods and guidelines for effective model calibration Water Resources Investigations Report 98-4005 1998 US Geological Survey Denver
M.C. Hill, and C.R. Tiedeman Effective groundwater model calibration With Analysis of data, sensitivities, predictions and uncertainty 2007 John Wiley and Sons New Jersey 455 pp.
P.F. Hudak Regional trends in nitrate content of Texas groundwater Journal of Hydrology 228 2000 37 47
B.M. Jackson, C.A. Browne, A.P. Butler, D. Peach, A.J. Wade, and H.S. Wheater Nitrate transport in Chalk catchments: monitoring, modelling and policy implications Environmental Science & Policy 11 2 2008 125 135
H. Johnsson, M. Larsson, K. Martensson, and M. Hoffmann SOILNDB: a decision support tool for assessing nitrogen leaching losses from arable land Environmental Modelling & Software 17 6 2002 505 517
W.A. Jury Simulation of solute transport using a transfer function model Water Resources Research 18 2 1982 363 368
D.-C. Koh, L.N. Plummer, D.K. Solomon, E. Busenberg, Y.-J. Kim, and H.-W. Chang Application of environmental tracers to mixing, evolution, and nitrate contamination of ground water in Jeju Island, Korea Journal of Hydrology 327 2006 258 275
S.F. Korom Natural denitrification in the saturated zone: a review Water Resources Research 28 6 1992 1657 1668
E. Ledoux, E. Gomez, J.-M. Monget, C. Viavattene, P. Viennot, A. Ducharne, M. Benoit, C. Mignolet, C. Schott, and B. Mary Agriculture and groundwater nitrate contamination in the Seine basin. The STICS-MODCOU modelling chain Science of the Total Environment 375 2007 33 47
K. Loague, and R.H. Abrams DBCP contaminated groundwater: hot spots and nonpoint sources Journal of Environmental Quality 28 2 1999 429 446
K. Loague, R.H. Abrams, S.N. Davis, A. Nguyen, and I.T. Stewart A case study simulation of DBCP groundwater contamination in Fresno County, California 2. Transport in the saturated subsurface Journal of Hydrology 29 1998 137 163 (Pubitemid 28045717)
P. Maloszewski, and A. Zuber Determining the turnover time of groundwater systems with the aid of environmental tracers. 1. Models and their applicability Journal of Hydrology 57 1982 207 231
P. Maloszewski, and A. Zuber Lumped parameter models for the interpretation of environmental tracer data Manual on mathematical models in isotope hydrology 1996 IAEA-TECDOC 910, IAEA Vienna
A. Mariotti Dénitrification in situ dans les eaux souterraines, processus naturels ou provoqués : une revue Hydrogéologie 3 1994 43 68
M. Mengis, S.L. Schiff, M. Harris, M.C. English, R. Aravena, R.J. Elgood, and A. MacLean Multiple geochemical and isotopic approaches for assessing ground water NO3 - elimination in a riparian zone Ground Water 37 3 1999 448 457
R.J. Mitchell, R. Scott Babcock, S. Gelinas, L. Nanus, and D.E. Stasney Nitrate distributions and source identification in the Abbotsford-Sumas aquifer, Northwester Washington state Journal of Environmental Quality 32 2003 789 800
M.A.A. Mohamed, H. Terao, R. Suzuki, I.S. Babiker, K. Ohta, K. Kaori, and K. Kato Natural denitrification in the Kakamigahara ground water basin, Gifu prefecture, central Japan The Science of the Total Environment 307 2003 191 201
Monjoie, A., 1967. Observations nouvelles sur la nappe aquifère de la craie en Hesbaye (Belgique). Mémoires de l'Association Internationale des Hydrogéologues (IAH), Istanboul.
Orban, P., 2009. Solute transport modelling at the groundwater body scale: Nitrate trends assessment in the Geer basin (Belgium). PhD Thesis, University of Liège, Faculty of Applied Sciences, Liège, 219 pp.
Orban, P., Batlle-Aguilar, J., Goderniaux, P., Brouyère, S., Broers, H.P., Visser, A., Heerdink, R., Van der Grift, B., Surdyk, N., Dubus, I.G. and Amaoui, N., 2008. Report which describes the physically deterministic determination and extrapolation of time trends at selected test locations in Dutch part of the Meuse Basin, the Brévilles catchment and the Geer catchment., Deliverable T2.10. AquaTerra - Integrated Project of the 6 th EU RTD Framework Program. Project N°505428, pp. 47.
O. Oren, Y. Yechieli, J.K. Böhlke, and A. Dody Contamination of groundwater under cultivated fields in a arid environment, central Arava Valley, Israel Journal of Hydrology 290 2004 312 328
Poeter, E.P., Hill, M.C., Banta, E.R., Mehl, S. and Christensen, S., 2005. UCODE-2005 and Six Other Computer Codes for Universal Sensitivity Analysis, Calibration, and Uncertainty Evaluation: U.S. Geological Survey Techniques and Methods 6-A11, 283 pp.
J.C. Refsgaard, M. Thorsen, J.B. Jensen, S. Kleeschulte, and S. Hansen Large scale modelling of groundwater contamination from nitrate leaching Journal of Hydrology 221 1999 117 140
P. Renard, and G. de Marsily Calculating equivalent permeability: a review Advances in Water Resources 20 5-6 1997 253 278
A. Ritter, R. Munoz-Carpena, D.D. Bosch, B. Schaffer, and T.L. Potter Agricultural land use and hydrology affect variability of shallow groundwater nitrate concentration in South Florida Hydrological Processes 21 18 2007 2464 2473
R.W. Ritzi, S. Sorooshian, and V.K. Gupta On the estimation of parameters for frequency domain models Water Resources Research 27 5 1991 873 882
E. Rozos, and D. Koutsoyiannis A multicell karstic aquifer model with alternative flow equations Journal of Hydrology 325 2006 340 355
J. Sandor, I. Kiss, O. Farkas, and I. Ember Association between gastric cancer mortality and nitrate content of drinking water: ecological study on small area inequalities European Journal of Epidemiology 17 5 2001 443 447
M. Schwientek, F. Einsiedl, W. Stichler, A. Stögbauer, H. Strauss, and P. Maloszewski Evidence for denitrification regulated by pyrite oxidation in a heterogeneous porous groundwater system Chemical Geology 255 1-2 2008 60 67
T.H. Skaggs, Z.J. Kabala, and W.A. Jury Deconvolution of a nonparametric transfer function for solute transport in soils Journal of Hydrology 207 1998 170 178
M. Sophocleous, J.K. Koelliker, R.S. Govindaraju, T. Birdie, S.R. Ramireddygari, and S.P. Perkins Integrated numerical modeling for basin-wide water management: the case of the Rattlesnake Creek basin in south-central Kansas Journal of Hydrology 214 1999 179 196
I.T. Stewart, and K. Loague A type transfer function approach for regional-scale pesticide leaching assessments Journal of Environmental Quality 28 2 1999 378 387
R. Therrien, and E.A. Sudicky Three-dimensional analysis of variably-saturated flow and solute transport in discretely-fractured porous media Journal of Contaminant Hydrology 23 1-2 1996 1 44
P.J. Thorburn, J.S. Biggs, K.L. Weier, and B.A. Keating Nitrate in ground waters of intensive agricultural areas in coastal Northeastern Australia Agriculture, Ecosystems and Environment 94 2003 49 58
M.P. Unterweger, B.M. Courset, F.J. Schima, and W.B. Mann Preparation and calibration of the 1978 National Bureau of Standarts tritiated water standarts Journal of Applied Radiation and Isotopes 31 1980 611 614
A. Visser, I. Dubus, H.P. Broers, S. Brouyere, M. Korcz, P. Orban, P. Goderniaux, J. Batlle-Aguilar, N. Surdyk, N. Amraoui, H. Job, J.L. Pinault, and M. Bierkens Comparison of methods for the detection and extrapolation of trends in groundwater quality Journal of Environmental Monitoring 11 2009 2030 2043
WHO Guidelines for Drinking Water Quality 3rd 2004 World Health Organization Geneva
M.-J. Yi, and K.-K. Lee Transfer function-noise modelling of irregularly observed groundwater heads using precipitation data Journal of Hydrology 288 2004 272 287