Article (Scientific journals)
Synthesis of tadpole-shaped copolyesters based on living macrocyclic poly(epsilon-caprolactone)
Li, H. Y.; Jérôme, Robert; Lecomte, Philippe
2006In Polymer, 47 (26), p. 8406-8413
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Keywords :
lactone; ring-opening polymerization (ROP); macrocycle
Abstract :
[en] Synthesis of an asymmetric tadpole-shaped aliphatic copolyester consisting of a poly(epsilon-caprolactone) ring and two poly(L-lactide) tails was reported for the first time. First, a high molecular weight cyclic PCL macroinitiator (Mn = 31,000) was prepared by intramolecular photocross-linking of "living" chains. Polymerization of L-lactide was resumed by the tin dialkoxide containing macrocycles, thus making the targeted tadpole-shaped copolyester available. A preliminary investigation of the crystallization of these copolyesters was carried out by differential scanning calorimetry and polarized optical microscopy.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Li, H. Y.;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Lecomte, Philippe  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Synthesis of tadpole-shaped copolyesters based on living macrocyclic poly(epsilon-caprolactone)
Publication date :
08 December 2006
Journal title :
Polymer
ISSN :
0032-3861
eISSN :
1873-2291
Publisher :
Elsevier Sci Ltd, Oxford, United Kingdom
Volume :
47
Issue :
26
Pages :
8406-8413
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique
Commentary :
The authors acknowledge Polymer (Elsevier) for allowing them to archive this paper.
Available on ORBi :
since 25 February 2009

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