Autoionization in Diatomic Molecules: an example of Electrostatic Autoionization in CO.

Raseev, G.; Leyh, Bernard; Lefebvre-Brion, H.

doi:10.1007/BF01426236

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Autoionization in Diatomic Molecules: an example of Electrostatic Autoionization in CO.

Raseev, G.; Leyh, Bernard; Lefebvre-Brion, H.

1986 • In Zeitschrift für Physik. D, Atoms, Molecules, and Clusters, 2, p. 319-326

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https://hdl.handle.net/2268/6511

DOI
10.1007/BF01426236

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Keywords :

electronic autoionization; rotational autoionization; spin-orbit autoionization; vibrational autoionization; multichannel quantum defect (MQDT)

Abstract :

[en] A review is presented of the different types of autoionization which have been studied theoretically in diatomic molecules: electronic (or electrostatic), rotational, spin-orbit and vibrational autoionizations. An example involving a large number of vibrational channels is treated. It concerns the electrostatic autoionization in the 730-708 Angstöm wavelength region which appears in the CO photoionization spectrum. The structure observed at 721 Angstrôm is explained by the enhancement in intensity of numerous levels of Rydberg series converging to excited levels of the A 2Pi state caused by two autoionized Rydberg levels with a B 2Sigma+ core.

Research Center/Unit :

Laboratoire de Dynamique Moléculaire

Disciplines :

Chemistry

Author, co-author :

Raseev, G.

Leyh, Bernard ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de dynamique moléculaire

Lefebvre-Brion, H.

Language :

English

Title :

Autoionization in Diatomic Molecules: an example of Electrostatic Autoionization in CO.

Alternative titles :

[fr] L'autoionisation dans les molécules biatomiques: un exemple d'autoionisation électrostatique dans CO.

Publication date :

1986

Journal title :

Zeitschrift für Physik. D, Atoms, Molecules, and Clusters

ISSN :

0178-7683

eISSN :

1431-5866

Publisher :

Springer Verlag, Berlin, Germany

Volume :

Pages :

319-326

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

NATO - North Atlantic Treaty Organization
FRFC - Fonds de la Recherche Fondamentale Collective
F.R.S.-FNRS - Fonds de la Recherche Scientifique

Funding text :

NATO (Contract n° 096.82), ARC, FRFC and FNRS

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