Autoionization in Diatomic Molecules: an example of Electrostatic Autoionization in CO.

Raseev, G.; Leyh, Bernard; Lefebvre-Brion, H.

doi:10.1007/BF01426236

Download

Article (Scientific journals)

Autoionization in Diatomic Molecules: an example of Electrostatic Autoionization in CO.

Raseev, G.; Leyh, Bernard; Lefebvre-Brion, H.

1986 • In Zeitschrift für Physik. D, Atoms, Molecules, and Clusters, 2, p. 319-326

Peer Reviewed verified by ORBi

Permalink
https://hdl.handle.net/2268/6511

DOI
10.1007/BF01426236

Files (1)Send to Details Statistics Bibliography Similar publications

Files

Full Text

Leyh_1986_Zeits-Physk-D_319.pdf

Author postprint (612.74 kB)

Download

All documents in ORBi are protected by a user license.

Send to

RIS BibTex APA Chicago Permalink X Linkedin

Details

Keywords :

electronic autoionization; rotational autoionization; spin-orbit autoionization; vibrational autoionization; multichannel quantum defect (MQDT)

Abstract :

[en] A review is presented of the different types of autoionization which have been studied theoretically in diatomic molecules: electronic (or electrostatic), rotational, spin-orbit and vibrational autoionizations. An example involving a large number of vibrational channels is treated. It concerns the electrostatic autoionization in the 730-708 Angstöm wavelength region which appears in the CO photoionization spectrum. The structure observed at 721 Angstrôm is explained by the enhancement in intensity of numerous levels of Rydberg series converging to excited levels of the A 2Pi state caused by two autoionized Rydberg levels with a B 2Sigma+ core.

Research center :

Laboratoire de Dynamique Moléculaire

Disciplines :

Chemistry

Author, co-author :

Raseev, G.

Leyh, Bernard ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de dynamique moléculaire

Lefebvre-Brion, H.

Language :

English

Title :

Autoionization in Diatomic Molecules: an example of Electrostatic Autoionization in CO.

Alternative titles :

[fr] L'autoionisation dans les molécules biatomiques: un exemple d'autoionisation électrostatique dans CO.

Publication date :

1986

Journal title :

Zeitschrift für Physik. D, Atoms, Molecules, and Clusters

ISSN :

0178-7683

eISSN :

1431-5866

Publisher :

Springer Verlag, Berlin, Germany

Volume :

Pages :

319-326

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

NATO (Contract n° 096.82), ARC, FRFC and FNRS

Available on ORBi :

since 18 February 2009

Statistics

Number of views

59 (1 by ULiège)

Number of downloads

198 (0 by ULiège)

More statistics

Scopus citations^®

Scopus citations^®
without self-citations

OpenCitations

Bibliography

Dehmer J.L., Dill D., Parr A.C. Photophysics and photochemistry in the vacuum ultra-violet , S. et al., McGlynn, D. Reidel Publishing Company, Dordrecht, Boston, London; 1985, 341.
Dehmer J.L., Parr A.C., Southworth S.H. Handbook on Synchrotron Radiation, G.V., Marr, North Holland, Amsterdam; 1986.
Greene, Jungen Adv. At. Mol. Phys. 1985, 21:51.
Nenner I., Beswick J.A. Handbook on synchrotron radiation, G.V., Marr, North Holland, Amsterdam; 1986.
.
Southworth S.H., Parr A.C., Hardis J.E., Dehmer J.L. Phys. Rev. 1986, 33 A:1020.
Holland D.M.P., Parr A.C., Ederer D.L., West J.B., Dehmer J.L. Int. J. Mass Spect. 1983, 52:195.
Fano U. Phys. Rev. 1961, 124:1866.
Bardsley J.N. J. Phys. 1968, 1 B:349.
Lefebvre-Brion H., Field R.W. Perturbations in the spectra of diatomic molecules, Academic Press, Orlando, Florida; 1986.
Morin P., Nenner I., Adam M.Y., Hubin-Franskin M.J., Delwiche J., Lefebvre-Brion H., Giusti-Suzor A. Chem. Phys. Lett. 1982, 92:609.
Herzberg G., Jungen J. Mol Spectrosc. 1972, 41:425.
Lefebvre-Brion H., Giusti-Suzor A., Raseev G. J. Chem. Phys. 1985, 83:1557.
Berry R.S., Nielsen S.E. Phys. Rev. 1970, 1 A:383.
Jungen, Atabek O. J. Chem. Phys. 1977, 66:5584.
.
Duzy C., Berry R.S. J. Chem. Phys. 1976, 64:2431.
Collins L.A., Schneider B.I. Phys. Rev. 1984, 29 A:1695.
Hazi A.U., Derkits C., Bardsley J.N. Phys. Rev. 1983, 27 A:1751.
Takagi H., Nakamura H. Phys. Rev. 1983, 27 A:691.
Tennyson J., Noble C.J. J. Phys. 1985, 18 B:155.
Raseev G. J. Phys. 1985, 18 B:423.
Levine Z.H., Soven P. Phys. Rev. 1984, 29 A:625.
Mies F.M. Phys. Rev. 1968, 175:164.
Seaton M.J. Proc. Phys. Soc. London 1966, 88:801.
Fano U. Phys. Rev. 1970, 2 A:353.
Raoult M., Jungen J. Chem. Phys. 1981, 74:3388.
Raoult M., Le Rouzo H., Raseev G., Lefebvre-Brion H. J. Phys. 1983, 16 B:4601.
.
Huffmann R.E., Larrabee J.C., Tanaka Y. (1964) Absorption Coefficients of Carbon Monoxide in the 1006–600-Å Wavelength Region. The Journal of Chemical Physics 40:2261.
Berkowitz J. Photoabsorption, photoionization and photoelectron spectroscopy , Academic Press, New York; 1979, 228.
Ogawa M., Ogawa S. J. Mol. Spectrosc. 1972, 41:393.
Leyh B., Raseev G., Hubin-Franskin M.J., Delwiche J., Lefebvre-Brion H., Nenner I., Roy P., Collin J.E. Photophysics and photochemistry above 6 eV , Elsevier Science Publishers, Amsterdam; 1985, 33.
Giusti-Suzor A., Lefebvre-Brion H. Phys. Rev. 1984, 30 A:3057.
Jungen, Dill D. J. Chem. Phys. 1980, 73:3338.
Raseev G. Comput. Phys. Commun 1980, 20:275.
Carlson T.A., Gérard P., Krause M.O., Vor Wald G., Taylor J.W., Grimm F.A. J. Chem. Phys. 1986, 84:4755.