Superhydrophobic aluminum surfaces by deposition of micelles of fluorinated block copolymers

[en] Superhydrophobic surfaces are generated by chemisorption on aluminum substrates of fluorinated block copolymers synthesized by reversible addition−fragmentation chain transfer in supercritical carbon dioxide. In an appropriate solvent, those block copolymers can form micelles with a fluorinated corona, which are grafted on the aluminum substrate thanks to the presence of carboxylic acid groups in the corona. Water contact angle and drop impact analysis were used to characterize the wettability of the films at the macroscale, and atomic force microscopy measurements provided morphological information at the micro- and nanoscale. The simple solvent casting of the polymer solution on a hydroxylated aluminum surface results in a coating with multiscale roughness, which is fully superhydrophobic over areas up to 4 cm2.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Desbief, Simon; University of Mons (UMons) > Centre d’Innovation et de Recherche en Matériaux (CIRMAP) > Service de Chimie des Matériaux Nouveaux et Laboratoire Interfaces et Fluides Complexes (InFlux)

Grignard, Bruno ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Rioboo, Romain; University of Mons (UMons) > Laboratoire de Physique des Surfaces et des Interfaces (LPSI)

Vaillant, Alexandre; University of Mons (UMons) > Laboratoire de Physique des Surfaces et des Interfaces (LPSI)

Seveno, David; University of Mons (UMons) > Laboratoire de Physique des Surfaces et des Interfaces (LPSI)

Voué, Michel; University of Mons (UMons) > Laboratoire de Physique des Surfaces et des Interfaces (LPSI)

De Coninck, Joel; University of Mons (UMons) > Laboratoire de Physique des Surfaces et des Interfaces (LPSI)

Jonas, Alain M.; Université catholique de Louvain (UCL) > Institute of Condensed Matter and Nanosciences

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Damman, Pascal; University of Mons (UMons) > Centre d’Innovation et de Recherche en Matériaux (CIRMAP) > Laboratoire Interfaces et Fluides Complexes (InFlux)

Lazzaroni, Roberto; Univesity of Mons (UMons) > Centre d’Innovation et de Recherche en Matériaux (CIRMAP) > Service de Chimie des Marériaux Nouveaux

Language :

English

Title :

Superhydrophobic aluminum surfaces by deposition of micelles of fluorinated block copolymers

Publication date :

02 February 2010

Journal title :

Langmuir

ISSN :

0743-7463

eISSN :

1520-5827

Publisher :

American Chemical Society, Washington, United States - District of Columbia

Volume :

Issue :

Pages :

2057-2067

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/la902565y

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
The "Région Wallonne" in the frame of the "CORRONET" program

Available on ORBi :

since 27 June 2010

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