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Article (Scientific journals)
Cobalt-mediated radical polymerization of vinyl acetate in miniemulsion: Very fast formation of stable poly(vinyl acetate) latexes at low temperature
Detrembleur, Christophe; Debuigne, Antoine; Bryaskova, Rayna et al.
2006 • In Macromolecular Rapid Communications, 27 (1), p. 37-41
Peer Reviewed verified by ORBi
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https://hdl.handle.net/2268/6247
DOI
10.1002/marc.200500645
 

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Keywords :
radical polymerization; cobalt-mediated radical polymerization (CMRP); vinyl acetate
Abstract :
[en] Poly(vinyl acetate) macroinitiators end-capped by a Co(acac)(2) complex (PVAc-Co(acac)(2)), prepared in bulk by cobalt-mediated radical polymerization (CMRP), are used for the controlled radical polymerization of vinyl acetate in miniemulsion to give high-molecular-weight polymers and high monomer conversion. Stable poly(vinyl acetate) latexes with solid contents ranging from 25 to 30 wt.-% are prepared within unusually short reaction times (similar to 1 h) at low temperatures (0-30 degrees C).
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry
Author, co-author :
Detrembleur, Christophe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Debuigne, Antoine  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Bryaskova, Rayna ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Charleux, Bernadette;  Université Pierre et Marie Curie > Laboratoire de Chimie des Polymères
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Cobalt-mediated radical polymerization of vinyl acetate in miniemulsion: Very fast formation of stable poly(vinyl acetate) latexes at low temperature
Publication date :
03 January 2006
Journal title :
Macromolecular Rapid Communications
ISSN :
1022-1336
eISSN :
1521-3927
Publisher :
Wiley-V C H Verlag Gmbh, Weinheim, Germany
Volume :
27
Issue :
1
Pages :
37-41
Peer reviewed :
Peer Reviewed verified by ORBi
Additional URL :
http://www3.interscience.wiley.com/cgi-bin/fulltext/112217675/PDFSTART
Funders :
Solvay sa
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique
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