Cobalt-mediated radical polymerization of vinyl acetate in miniemulsion: Very fast formation of stable poly(vinyl acetate) latexes at low temperature

Detrembleur, Christophe; Debuigne, Antoine; Bryaskova, Rayna; Charleux, Bernadette; Jérôme, Robert

doi:10.1002/marc.200500645

Article (Scientific journals)

Cobalt-mediated radical polymerization of vinyl acetate in miniemulsion: Very fast formation of stable poly(vinyl acetate) latexes at low temperature

Detrembleur, Christophe; Debuigne, Antoine; Bryaskova, Rayna et al.

2006 • In Macromolecular Rapid Communications, 27 (1), p. 37-41

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/6247

DOI
10.1002/marc.200500645

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Keywords :

radical polymerization; cobalt-mediated radical polymerization (CMRP); vinyl acetate

Abstract :

[en] Poly(vinyl acetate) macroinitiators end-capped by a Co(acac)(2) complex (PVAc-Co(acac)(2)), prepared in bulk by cobalt-mediated radical polymerization (CMRP), are used for the controlled radical polymerization of vinyl acetate in miniemulsion to give high-molecular-weight polymers and high monomer conversion. Stable poly(vinyl acetate) latexes with solid contents ranging from 25 to 30 wt.-% are prepared within unusually short reaction times (similar to 1 h) at low temperatures (0-30 degrees C).

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry

Author, co-author :

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Bryaskova, Rayna ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Charleux, Bernadette; Université Pierre et Marie Curie > Laboratoire de Chimie des Polymères

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Cobalt-mediated radical polymerization of vinyl acetate in miniemulsion: Very fast formation of stable poly(vinyl acetate) latexes at low temperature

Publication date :

03 January 2006

Journal title :

Macromolecular Rapid Communications

ISSN :

1022-1336

eISSN :

1521-3927

Publisher :

Wiley-V C H Verlag Gmbh, Weinheim, Germany

Volume :

Issue :

Pages :

37-41

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www3.interscience.wiley.com/cgi-bin/fulltext/112217675/PDFSTART

Funders :

Solvay sa
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique

Available on ORBi :

since 16 February 2009

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