Synthesis of novel well-defined poly(vinyl acetate)-b-poly(acrylonitrile) and derivatized water-soluble poly(vinyl alcohol)-b-poly(acrylic acid) block copolymers by cobalt-mediated radical polymerization

Debuigne, Antoine; Warnant, Jérôme; Jérôme, Robert; Voets, Ilja; de Keizer, Arie; Cohen Stuart, Martien A; Detrembleur, Christophe

doi:10.1021/ma702341v

Article (Scientific journals)

Synthesis of novel well-defined poly(vinyl acetate)-b-poly(acrylonitrile) and derivatized water-soluble poly(vinyl alcohol)-b-poly(acrylic acid) block copolymers by cobalt-mediated radical polymerization

Debuigne, Antoine; Warnant, Jérôme; Jérôme, Robert et al.

2008 • In Macromolecules, 41 (7), p. 2353-2360

Peer Reviewed verified by ORBi

Permalink
https://hdl.handle.net/2268/5584

DOI
10.1021/ma702341v

Files (1)Send to Details Statistics Bibliography Similar publications

Files

Full Text

Debuigne A 2008 Macromolecules 2353.pdf

Publisher postprint (190.3 kB)

Request a copy

All documents in ORBi are protected by a user license.

Send to

RIS BibTex APA Chicago Permalink X Linkedin

Details

Keywords :

radical polymerization; cobalt-mediated radical polymerization (CMRP); block copolymer

Abstract :

[en] Poly(vinyl acetate)−Co(acac)2 macroinitiators, prepared by cobalt-mediated radical polymerization of vinyl acetate (VAc), were used to synthesize well-defined poly(vinyl acetate)-b-poly(acrylonitrile) (PVAc-b-PAN) block copolymers. Different solvents and temperatures were tested for the polymerization of the acrylonitrile segment by cobalt-mediated radical polymerization (CMRP), and copolymers with low polydispersity were obtained provided that dimethylformamide was used as solvent at 0 °C. The mechanism of control was assumed to change from a degenerative chain transfer mechanism for the VAc polymerization to a reversible-termination process for the AN polymerization. The hydrolysis of the ester groups of the PVAc block and the nitrile groups of the PAN sequence of the copolymer by potassium hydroxide in an ethanol/water mixture provided the double hydrophilic and pH-responsive poly(vinyl alcohol)-b-poly(acrylic acid) block copolymer. Finally, the pH responsiveness of these copolymers was demonstrated by DLS pH titration with formation of aggregates at pH < 3.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Warnant, Jérôme; Université de Liège - ULiège > Depmartment of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Voets, Ilja; University of Wageningen, The Netherlands > Laboratory of Physical Chemistry and Colloid Science

de Keizer, Arie; University of Wageningen, The Netherlands > Laboratory of Physical Chemistry and Colloid Science

Cohen Stuart, Martien A; University of Wageningen, The Netherlands > Laboratory of Physical Chemistry and Colloid Science

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Publication date :

08 April 2008

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

American Chemical Society, Washington, United States - Washington

Volume :

Issue :

Pages :

2353-2360

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma702341v

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique

Available on ORBi :

since 04 February 2009

Statistics

Number of views

109 (8 by ULiège)

Number of downloads

0 (0 by ULiège)

More statistics

Scopus citations^®

Scopus citations^®
without self-citations

OpenCitations

OpenAlex citations

See more details

publications

supporting

mentioning

contrasting

Smart Citations

Citing PublicationsSupportingMentioningContrasting

View Citations

See how this article has been cited at scite.ai

scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.

Bibliography

Braunecker, W. A.; Matyjaszewski, K. Prog. Polym. Sci. 2007, 32, 93-146.
Hawker, C. J.; Bosman, A. W.; Harth, E. Chem. Rev. 2001, 101, 3661-3688.
Georges, M. K.; Veregin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Macromolecules 1993, 26, 2987-2988.
Kamigaito, M.; Ando, T.; Sawamoto, M. Chem. Rev. 2001, 101, 3689-3745.
Matyjaszewski, K.; Xia, J. Chem. Rev. 2001, 101, 2921-2990.
Tsarevsky, N. V.; Matyjaszewski, K. Chem. Rev. 2007, 101, 2270-2299.
Moad, G.; Rizzardo, E.; Thang, S. H. Aust. J. Chem. 2005, 58, 379-410.
Moad, G.; Chiefari, J.; Chong, Y. K.; Krstina, J.; Mayadunne, R. T. A.; Postma, A.; Rizzardo, E.; Thang, S. H. Polym. Int. 2000, 49, 993-1001.
Chiefari, J.; Chong, Y. K.; Ercole, F.; Krstina, J.; Jeffery, J.; Le, T. P. T.; Mayadunne, R. T. A.; Meijs, G. F.; Moad, C. L.; Moad, G.; Rizzardo, E.; Thang, S. H. Macromolecules 1998, 31, 5559-5562.
Lai, J. T.; Filla, D.; Shea, R. Macromolecules 2002, 35, 6754-6756.
Perrier, S.; Takolpuckdee, P.; Mars, C. A. Macromolecules 2005, 38, 2033-2036.
Charmot, D.; Corpart, P.; Adam, H.; Zard, S. Z.; Biadatti, T.; Bouhadir, G. Macromol. Symp. 2000, 150, 23-32.
Taton, D.; Wilczewska, A.-Z.; Destarac, M. Macromol. Rapid Commun. 2001, 22, 1497-1503.
Destarac, M.; Bzducha, W.; Taton, D.; Gauthier-Gillaizeau, I.; Zard, S. Z. Macromol. Rapid Commun. 2002, 23, 1049-1054.
Stenzel, M. H.; Cummins, L.; Roberts, G. E.; Davis, T. P.; Vana, P.; Barner-Kowollik, C. Macromol. Chem. Phys. 2003, 204, 1160-1168.
Wayland, B. B.; Poszmik, G.; Mukerjee, S. L.; Fryd, M. J. Am. Chem. Soc. 1994, 116, 7943-7944.
Wayland, B. B.; Basickes, L.; Mukerjee, S.; Wei, M.; Fryd, M. Macromolecules 1997, 30, 8109-8112.
Lu, Z.; Fryd, M.; Wayland, B. B. Macromolecules 2004, 37, 2686-2687.
Wayland, B. B.; Peng, C-H.; Fu, X.; Lu, Z.; Fryd, M. Macromolecules 2006, 39, 8219-8222.
Debuigne, A.; Caille, J.-R.; Jerome, R. Angew. Chem., Int. Ed. 2005, 44, 1101-1104.
Debuigne, A.; Caille, J.-R.; Detrembleur, C.; Jerome, R. Angew. Chem., Int. Ed. 2005, 44, 3439-3442.
Bryaskova, R.; Detrembleur, C.; Debuigne, A.; Jerome, R. Macromolecules 2006, 39, 8263-8268.
Kaneyoshi, H.; Matyjaszewski, K. Macromolecules 2005, 38, 8163-8169.
Maria, S.; Kaneyoshi, H.; Matyjaszewski, K.; Poli, R. Chem.-Eur. J. 2007, 13, 2480-2492.
Debuigne, A.; Caille, J.-R.; Jerome, R. Macromolecules 2005, 38, 5452-5458.
Detrembleur, C.; Debuigne, A.; Bryaskova, R.; Charleux, B.; Jerome, R. Macromol. Rapid Commun. 2006, 27, 37-41.
Detrembleur, C.; Stoilova, O.; Bryaskova, R.; Debuigne, A.; Mouithys-Mickalad, A.; Jerome, R. Macromol. Rapid Commun. 2006, 27, 498-504.
Debuigne, A.; Caille, J.-R.; Willet, N.; Jerome, R. Macromolecules 200538, 9488-9496.
Bryaskova, R.; Willet, N.; Debuigne, A.; Jerome, R.; Detrembleur, C. J. Polym. Sci., Part A: Polym. Chem. 2006, 45, 81-89.
Bryaskova, R.; Willet, N.; Degee, P.; Dubois, P.; Jerome, R.; Detrembleur, C. J. Polym. Sci., Part A: Polym. Chem. 2007, 45, 2532-2542.
Debuigne, A.; Willet, N.; Jérôme, R.; Detrembleur, C. Macromolecules 2007, 40, 7111-7118.
Benoit, D.; Chaplinski, V.; Braslau, R.; Hawker, C. J. J. Am. Chem. Soc. 1999, 121, 3904-3920.
Tang, C.; Kowalewski, T.; Matyjaszewski, K. Macromolecules 2003, 36, 1465-1473.
Kaim, A. J. Polym. Sci., Part A: Polym. Chem. 2006, 45, 232-241.
Matyjaszewski, K.; Jo, S. M.; Paik, H.-j.; Gaynor, S. G. Macromolecules 1997, 30, 6398-6400.
Matyjaszewski, K.; Jo, S. M.; Paik, H.-j.; Shipp, D. A. Macromolecules 1999, 32, 6431-6438.
Barboiu, B.; Percec, V. Macromolecules 2001, 34, 8626-8636.
Tang, C.; Kowalewski, T.; Matyjaszewski, K. Macromolecules 2003, 36, 8587-8589.
An, Q.; Qian, J.; Yu, L.; Luo, Y.; Liu, X. J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 1973-1977.
Liu, X.-H.; Li, Y.-G.; Lin, Y.; Li, Y.-S. J. Polym. Sci., Part A: Polym. Chem. 2007, 45, 1272-1281.
Liu, X.-H.; Zhang, G.-B.; Lu, X.-F.; Liu, J.-Y.; Pan, D.; Li, Y.-S. J. Polym. Sci., Part A: Polym. Chem. 2005, 44, 490-498.
Jo, S. M.; Gaynor, S. G.; Matyjaszewski, K. Polym. Prepr. 1996, 37, 272-273.
Bajaj, P.; Roopanwal, A. K. J. Macromol. Sci., Rev. Macromol. Chem. Phys 1997, C37, 97-147.
Kowalewski, T.; Tsarevsky, N. V.; Matyjaszewski, K. J. Am. Chem. Soc. 2002, 124, 10632-10633.
Tang, C.; Tracz, A.; Kruk, M.; Zhang, R.; Smilgies Detlef, M.; Matyjaszewski, K.; Kowalewski, T. J. Am. Chem. Soc. 2005, 127, 6918-6919.
Kowalewski, T.; McCullough, R. D.; Matyjaszewski, K. Eur. Phys. J. E 2003, 10, 5-16.
Kruk, M.; Dufour, B.; Celer, E. B.; Kowalewski, T.; Jaroniec, M.; Matyjaszewski, K. Chem. Mater. 2006, 18, 1417-1424.
Tang, C.; Qi, K.; Wooley, K. L.; Matyjaszewski, K.; Kowalewski, T. Angew. Chem., Int. Ed. 2004, 43, 2783-2787.
Aqil, A.; Detrembleur, C.; Gilbert, B.; Jerome, R.; Jerome, C. Chem. Mater. 2007, 19, 2150-2154.
Zhang, L.; Eisenberg, A. Science 1995, 268, 1728-1731.
Zhang, L.; Eisenberg, A. J. Am. Chem. Soc. 1996, 118, 3168-3181.
Bernaerts, K. V.; Willet, N.; Van Camp, W.; Jerome, R.; Du Prez, F. E. Macromolecules 2006, 39, 3760-3769.
Philippova, O. E.; Hourdet, D.; Audebert, R.; Khokhlov, A. R. Macromolecules 1997, 30, 8278-8285.
Soppimath, K. S.; Aminabhavi, T. M.; Dave, A. M.; Kumbar, S. G.; Rudzinski, W. E. Drug Dev. Ind. Pharm. 2002, 28, 957-974.
Pradhan, R. K.; Misra, P. K.; Tripathy, S. S. Macromol. Rep. 1994, A37, 279-286.
Encyclopedia of Polymer Science and Engineering; John Wiley and Sons: New York, 1989.
Kaneyoshi, H.; Matyjaszewski, K. Macromolecules 2006, 39, 2757-2763.
Debuigne, A.; Detrembleur, C.; Bryaskova, R.; Caille, J.-R.; Jérôme, R. ACS Symp. Ser. 2006, 944, 372-386.
Molyneux, P. Water-Soluble Synthetic Polymers: Properties and Behavior; CRC Press: Boca Raton, FL, 1982; Vols. I and II.
Khutoryanskiy, V. V.; Mun, G. A.; Nurkeeva, Z. S.; Dubolazov, A. V. Polym. Int. 2004, 53, 1382-1387.
Cohen Stuart, M. A.; Hofs, B.; Voets, I. K.; de Keizer, A. Curr. Opin. Colloid Interface Sci. 2005, 10, 30-36.

Similar publications

Sorry the service is unavailable at the moment. Please try again later.

Name	Provider / Domaine	Expiration	Description
JSESSIONID	Oracle Corporation www.uliege.be	Session	General purpose platform session cookie, used by sites written in JSP. Usually used to maintain an anonymous user session by the server.
CookieScriptConsent	CookieScript .uliege.be	1 year	This cookie is used by Cookie-Script.com service to remember visitor cookie consent preferences. It is necessary for Cookie-Script.com cookie banner to work properly.

Name	Provider / Domaine	Expiration	Description
_pk_id	InnoCraft Ltd .uliege.be	1 year	Used to store a few details about the user such as the unique visitor ID
_pk_ses	InnoCraft Ltd .uliege.be	30 minutes	Short lived cookies used to temporarily store data for the visit
_pk_ref	InnoCraft Ltd .uliege.be	6 months	Used to store the attribution information, the referrer initially used to visit the website