Reference : Copper bromide complexed by fluorinated macroligands: towards microspheres by ATRP of...
Scientific journals : Article
Engineering, computing & technology : Materials science & engineering
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/4869
Copper bromide complexed by fluorinated macroligands: towards microspheres by ATRP of vinyl monomers in scCO2
English
Grignard, Bruno [Université de Liège - ULiège > > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Christine mailto [Université de Liège - ULiège > > Center for Education and Research on Macromolecules (CERM) > >]
Calberg, Cédric mailto [Université de Liège - ULiège > > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [Université de Liège - ULiège > > Center for Education and Research on Macromolecules (CERM) > > >]
Wang, Wenxing [University of Nottingham, School of Chemistry, UK > > > >]
Howdle, Steven M [University of Nottingham, School of Chemistry, UK > > > >]
Detrembleur, Christophe mailto [Université de Liège - ULiège > > Center for Education and Research on Macromolecules (CERM) > > >]
2008
Chemical Communications
Royal Society of Chemistry
3
314-316
Yes (verified by ORBi)
International
1359-7345
Cambridge
[en] green technology ; supercritical carbon dioxide
[en] We report the successful synthesis of poly(methyl methacrylate) (PMMA) by atom transfer radical polymerization using a catalyst ligated to a polymeric ligand having a dual role, i.e., the complexation of the copper salt and the stabilization of the growing PMMA particles; at the end of the polymerization, the catalyst is removed by supercritical fluid extraction leading to PMMA microspheres with low residual catalyst content.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Région wallonne in the frame of the ‘‘Surfaces auto-nettoyantes et anticorrosion (CORRONET)’’ project ; Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS
Researchers
http://hdl.handle.net/2268/4869
10.1039/b716208a
http://www.rsc.org/ej/CC/2008/b716208a.pdf
http://www.rsc.org/suppdata/CC/b7/b716208a/b716208a.pdf

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