Cathodic electrografting of acrylics: From fundamentals to functional coatings

Gabriel, Sabine; Jérôme, Robert; Jérôme, Christine

doi:10.1016/j.progpolymsci.2009.11.003

Reference : Cathodic electrografting of acrylics: From fundamentals to functional coatings


	Document type :	Scientific journals : Article
	Discipline(s) :	Physical, chemical, mathematical & earth Sciences : Chemistry Engineering, computing & technology : Materials science & engineering
	To cite this reference:	http://hdl.handle.net/2268/4487

Title :	Cathodic electrografting of acrylics: From fundamentals to functional coatings
Language :	English
Author, co-author :	Gabriel, Sabine [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Robert [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Christine [Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Publication date :	2010
Journal title :	Progress in Polymer Science
Publisher :	Elsevier Science
Volume :	35
Pages :	113-140
Peer reviewed :	Yes (verified by ORBi)
Audience :	International
ISSN :	0079-6700
Keywords :	[en] eletropolymerization ; electrografting ; review
Abstract :	[en] Promoting permanent adhesion between so dissimilar materials as polymers and metals is a very challenging target and a severe brake to the implementation of many potential applications. However, synthetic polymers can now be chemisorbed onto a variety of conducting surfaces by cathodic electrografting of acrylic monomers. The first part of this review will focus on the fundamental aspects of this emerging technology, thus from the historical discovery to experimental and theoretical developments, with the purpose to better comprehend the electrografting phenomenon. Once firmly established, this concept has been exploited in order to make polymeric coatings with specific functionality chemisorbed onto more diversified substrates in more convenient liquid media. This remarkable progress that largely relies on advanced controlled polymerization processes will be the topic of the second part of the review, with a special emphasis on the more recent development of smart coatings, particularly stimuli responsive coatings very well-suited to nanotechnologies.
Research centres :	Center for Education and Research on Macromolecules (CERM)
Funders :	Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/4487
DOI :	10.1016/j.progpolymsci.2009.11.003
Other URL :	http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TX2-4XRCRM4-1-2F&_cdi=5578&_user=532038&_orig=browse&_coverDate=02%2F28%2F2010&_sk=999649998&view=c&wchp=dGLzVtb-zSkzk&md5=f8cbb4f17b78b77b5436fcef8e88f963&ie=/sdarticle.pdf
	http://www.elsevier.com/wps/find/journaldescription.cws_home/418/description#description
Mentions required by the publisher for OA :	The authors acknowledge Progress in Polymer Science (Elsevier) for allowing them to archive this paper.

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