Article (Scientific journals)
Effect of the Solvent Polarity on the Living Ligated Anionic Polymerization of tert-Butyl Methacrylate and Copolymerization with Methyl Methacrylate
Zune, Catherine; Archambeau, C.; Dubois, Philippe et al.
2001In Journal of Polymer Science. Part A, Polymer Chemistry, 39 (10), p. 1774-1785
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Keywords :
anionic polymerization
Abstract :
[en] An anionic polymerization of t-butyl methacrylate and a copolymerization with methyl methacrylate were initiated with an organolithium ligated with 10 equiv of LiCl. As a rule, the complexation of the active species by LiCl masked the effect that the polarity of the solvent might have on the molecular structure of the chains.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Zune, Catherine;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Archambeau, C.;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Dubois, Philippe ;  Université de Liège - ULiège > Centre d'études et de rech. sur les macromolécules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Effect of the Solvent Polarity on the Living Ligated Anionic Polymerization of tert-Butyl Methacrylate and Copolymerization with Methyl Methacrylate
Publication date :
15 May 2001
Journal title :
Journal of Polymer Science. Part A, Polymer Chemistry
ISSN :
0887-624X
eISSN :
1099-0518
Publisher :
John Wiley & Sons, Hoboken, United States - New Jersey
Volume :
39
Issue :
10
Pages :
1774-1785
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
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