[en] An anionic polymerization of t-butyl methacrylate and a copolymerization with methyl methacrylate were initiated with an organolithium ligated with 10 equiv of LiCl. As a rule, the complexation of the active species by LiCl masked the effect that the polarity of the solvent might have on the molecular structure of the chains.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Zune, Catherine; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Archambeau, C.; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Dubois, Philippe ; Université de Liège - ULiège > Centre d'études et de rech. sur les macromolécules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Effect of the Solvent Polarity on the Living Ligated Anionic Polymerization of tert-Butyl Methacrylate and Copolymerization with Methyl Methacrylate
Publication date :
15 May 2001
Journal title :
Journal of Polymer Science. Part A, Polymer Chemistry
ISSN :
0887-624X
eISSN :
1099-0518
Publisher :
John Wiley & Sons, Hoboken, United States - New Jersey
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