Controlled radical polymerization of methyl methacrylate initiated by an alkyl halide in the presence of the Wilkinson catalyst

Moineau, Georges; Granel, Claude; Dubois, Philippe; Jérôme, Robert; Teyssié, Philippe

doi:10.1021/ma971123f

Article (Scientific journals)

Controlled radical polymerization of methyl methacrylate initiated by an alkyl halide in the presence of the Wilkinson catalyst

Moineau, Georges; Granel, Claude; Dubois, Philippe et al.

1998 • In Macromolecules, 31 (2), p. 542-544

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/4355

DOI
10.1021/ma971123f

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Keywords :

radical polymerization; atom transfer radical polymerization (ATRP)

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Moineau, Georges; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Granel, Claude; Université de Liège - ULiège > Department of Chemistrty > Center for Education and Research on Macromolecules (CERM)

Dubois, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Controlled radical polymerization of methyl methacrylate initiated by an alkyl halide in the presence of the Wilkinson catalyst

Publication date :

27 January 1998

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - Washington

Volume :

Issue :

Pages :

542-544

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma971123f

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique
Elf Atochem

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since 19 January 2009

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Bibliography

Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721.
(b) Ando, T.; Kato, M.; Kamigaito, M.; Sawamoto, M. Macromolecules 1996, 29, 1070.
Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614.
(b) Wang, J. S.; Matyjaszewski, K. Macromolecules 1995, 28, 7901.
Grimaud, T.; Matyjaszewski, K. Macromolecules 1997, 30, 2216.
Kameda, N.; Itagaki, N. Bull. Chem. Soc. Jpn. 1973, 46, 2597.
(b) Kameda, N.; Ishii, E. Makromol. Chem. 1983, 184, 1901.
(c) Kameda, N.; Ishii, E. Nippon Kagaku Kaishi 1983, 8, 1196.
(d) Kameda, N.; Hattori, M. Kobunshi Ronbunshu 1984, 41 (11), 679.
(e) Kameda, N.; Hattori, M. Kobunshi Ronbunshu 1985, 42 (8), 485.
Percec, V.; Barboiu, B.; Neumann, A.; Ronda, J. C.; Zhao, M. Macromolecules 1996, 29, 3665.
Hutchinson, R. A.; Aronson, M. T.; Richards, J. R. Macromolecules 1993, 26, 6410.
Osborn, J. A.; Wilkinson, G. Inorg. Synth. 1990, 28, 77.
Haddleton et al. have shown that these two criteria are not enough to confirm a radical pathway: Haddleton, D. M.; Crossman, M. C.; Hunt, K. H.; Topping, C.; Waterson, C.; Suddaby, K. G. Macromolecules 1997, 30, 3992.
Conditions: T = 50 °C; reaction time, 18 h; solvent, THF, [MMA]0 = 5.55 mol·L-1, [HEMA]0 = 0.5 mol·L-1, [RhCl-(PPh3)3]0 = 18.4 × 10-3 mol·L-1, [PPh3]0 = 13 × 10-2 mol·L-1, [2,2′-dichloroacetophenone]0 = 36.8 × 10-3 mol·L-1. Conversion, 85%. The percentage of HEMA determined by 1H NMR, 9.6%.
Moineau, G.; Dubois, P.; Teyssié, P.; Jérôme, R.; Senninger, T. French Patent, Pending, 1996.