Controlled nitroxide-mediated radical polymerization of styrene, styrene/acrylonitrile mixtures, and dienes using a nitrone

Detrembleur, Christophe; Sciannamea, Valérie; Koulic, Christian; Claes, Michaël; Hoebeke, Maryse; Jérôme, Robert

doi:10.1021/ma0201835

Article (Scientific journals)

Controlled nitroxide-mediated radical polymerization of styrene, styrene/acrylonitrile mixtures, and dienes using a nitrone

Detrembleur, Christophe; Sciannamea, Valérie; Koulic, Christian et al.

2002 • In Macromolecules, 35 (19), p. 7214-7223

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/4125

DOI
10.1021/ma0201835

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Keywords :

radical polymerization; nitroxide-mediated polymerization (NMP)

Abstract :

[en] Radical polymerization of styrene and copolymerization of styrene and acrylonitrile (60/40) are controlled when conducted in the presence of N-tert-butyl-alpha-isopropylnitrone, which is easily synthesized from cheap reagents. However, for the control to be effective, the nitrone has to be prereacted with the radical initiator. Nitroxides are then formed "in situ", such that this nitrone system is an attractive alternative for the classical nitroxide-mediated polymerization (NMP), which may require a multistep synthesis of nitroxides or alkoxyamines. The choice of the radical initiator is important because it dictates the structure of the nitroxide and thus its capacity to control the radical polymerization. Well-defined poly(styrene)-b-poly(styrene-co-acrylonitrile), poly(styrene)-b-poly(n-butyl acrylate), and poly(styrene)-b-poly(isoprene) copolymers have been successfully synthesized by this process.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Sciannamea, Valérie; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Koulic, Christian; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Claes, Michaël

Hoebeke, Maryse ; Université de Liège - ULiège > Department of Physics > Centre of Oxygen R&D

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Controlled nitroxide-mediated radical polymerization of styrene, styrene/acrylonitrile mixtures, and dienes using a nitrone

Publication date :

10 September 2002

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - Washington

Volume :

Issue :

Pages :

7214-7223

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma0201835

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique

Available on ORBi :

since 13 January 2009

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