Amphiphilic poly(vinyl acetate)-b-poly(N-vinylpyrrolidone) and novel double hydrophilic poly(vinyl alcohol)-b-poly(N-vinylpyrrolidone) block copolymers prepared by cobalt-mediated radical polymerization

Debuigne, Antoine; Willet, Nicolas; Jérôme, Robert; Detrembleur, Christophe

doi:10.1021/ma0712908

Article (Scientific journals)

Amphiphilic poly(vinyl acetate)-b-poly(N-vinylpyrrolidone) and novel double hydrophilic poly(vinyl alcohol)-b-poly(N-vinylpyrrolidone) block copolymers prepared by cobalt-mediated radical polymerization

Debuigne, Antoine; Willet, Nicolas; Jérôme, Robert et al.

2007 • In Macromolecules, 40 (20), p. 7111-7118

Peer Reviewed verified by ORBi

Permalink
https://hdl.handle.net/2268/4093

DOI
10.1021/ma0712908

Files (1)Send to Details Statistics Bibliography Similar publications

Files

Full Text

Debuigne A 2007 Macromolecules 7111.pdf

Publisher postprint (245.4 kB)

Request a copy

All documents in ORBi are protected by a user license.

Send to

RIS BibTex APA Chicago Permalink X Linkedin

Details

Keywords :

radical polymerization; cobalt-mediated radical polymerization (CMRP)

Abstract :

[en] Well-defined amphiphilic block copolymers of poly(vinyl acetate) (PVAc) and poly(N-vinylpyrrolidone) (PNVP) were synthesized by cobalt-mediated radical polymerization (CMRP). The NVP polymerization initiated by poly(vinyl acetate) end-capped by the cobalt(II)acetylacetonate complex met the criteria of controlled polymerization, i.e., first-order kinetic in NVP, increase of the molar mass with the NVP conversion, and narrow molar mass distribution. Therefore, the length of the two blocks can be tuned by the [VAc]/[Co(acac)(2)] and the [NVP]/[PVAc] ratios for the synthesis of the macroinitiator and the polymerization of the second monomer, respectively. These amphiphilic PVAc-b-PNVP block copolymers were easily converted into the double hydrophilic PVOH-b-PNVP counterparts by selective methanolysis of the PVAc block. These two types of copolymers were prone to self-association into micelles in appropriate solvents.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Willet, Nicolas ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Publication date :

02 October 2007

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - Washington

Volume :

Issue :

Pages :

7111-7118

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma0712908

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique

Available on ORBi :

since 13 January 2009

Statistics

Number of views

116 (7 by ULiège)

Number of downloads

0 (0 by ULiège)

More statistics

Scopus citations^®

113

Scopus citations^®
without self-citations

OpenCitations

111

OpenAlex citations

118

Bibliography

(a) Georges, M. K.; Veregin, R. P. N.; Kazmaier, P. M.; Hamer, G. K. Macromolecules 1993, 26, 2987-2988.
(b) Hawker, C. J.; Bosman, A. W.; Harth, E. Chem. Rev. 2001, 101, 3661-3688.
(a) Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614-5615.
(b) Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721-1723.
(c) Kamigaito, M.; Ando, T.; Sawamoto, M. Chem. Rev. 2001, 101, 3689-3745.
(d) Matyjaszewski, K.; Xia, J. Chem. Rev. 2001, 101, 2921-2990.
(a) Moad, G.; Chiefari, J.; Chong, Y. K.; Krstina, J.; Mayadunne, R. T. A.; Postma, A.; Rizzardo, E.; Thang, S. H. Polym. Int. 2000, 49, 993-1001.
(b) Moad, G.; Rizzardo, E.; Thang, S. H. Aust. J. Chem. 2005, 58, 379-410.
(a) Finch, C. A. Polyvinyl alcohol: Properties and Applications; John Wiley and Sons: New York, 1973.
(b) Chiellini, E.; Corti, A.; D'Antone, S.; Solaro, R. Prog. Polym. Sci. 2003, 28 (6), 963-1014.
(a) Kirsh, Y. E. Water Soluble Poly-N-Vinylamides, Synthesis and physicochemical Properties; John Wiley and Sons: New York, 1998.
(b) Saraz, I.; Forsling, W. Polymer 2000, 4831-4839.
(c) Encyclopedia of Polymer Science and Engineering; John Wiley and Sons: New York, 1989; Vol. 17.
lovu, M. C.; Matyjaszewski, K. Macromolecules 2003, 36, 9346.
(a) Rizzardo, E.; Chiefari, J.; Mayadunne, R. T. A.; Moad, G.; Thang, S. H. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1999, 40 (2), 342-343.
(b) Rizzardo, E.; Chiefari, J.; Mayadunne, R. T. A.; Moad, G.; Thang, S. H. ACS Symp. Ser. 2000, 768, 278-296.
(c) Rizzardo, E.; Chiefari, J.; Mayadunne, R.; Moad, G.; Thang, S. Macromol. Symp. 2001, 174, 209-212.
(d) Destarac, M.; Charmot, D.; Zard, S.; Gauthier-Gilaizeau, I. (Rhodia) WO0142312, 2001.
(e) Destarac, M.; Buzducha, W.; Taton, D.; Gauthier-Gillaizeau, S.; Zard, S. Z. Macromol. Rapid Commun. 2002, 23, 1049-1054.
(f) Stenzel, M. H.; Cummins, L.; Roberts, G. E.; Davis, T. P.; Vana, P.; Barner-Kowollik, C. Macromol. Chem. Phys. 2003, 204, 1160-1168.
(g) Stenzel, M. H.; Davis, T. P.; Barner-Kowollik, C. Chem. Commun. 2004, 1546-1547.
(h) Simms, R. W.; Davis, T. P.; Cunningham, M. F. Macromol. Rapid Commun. 2005, 26, 592-596.
(i) Theis, A.; Davis, T. P.; Stenzel, M. H.; Barner-Kowollik, C. Polymer 2006, 47, 999-1010.
Kwak, Y.; Goto, A.; Fukuda, T.; Kobayashi, Y.; Yamago, S. Macromolecules 2006, 39, 4671.
Wayland, B. B.; Fu, X.; Peng, C.-H.; Lu, Z.; Fryd, M. A. C. S. Symposium Series 2006, 944, 358-371.
(a) Debuigne, A.; Caille, J.-R.; Jerome, R. Angew. Chem., Int. Ed. 2005, 44, 1101-1104.
(b) Debuigne, A.; Caille, J.-R.; Jerome, R. Macromolecules 2005, 38, 5452-5458.
(c) Kaneyoshi, H.; Matyjaszewski, K. Macromolecules 2005, 38, 8163-8169.
(d) Bryaskova, R.; Detrembleur, C.; Debuigne, A.; Jerome, R. Macromolecules 2006, 39, 8263-8268.
(e) Sciannamea, V.; Debuigne, A.; Piette, Y.; Jerome, R.; Detrembleur, C. Chem. Commun. 2006, 4180-4182.
(a) Debuigne, A.; Caille, J.-R.; Detrembleur, C.; Jerome, R. Angew. Chem., Int. Ed. 2005, 44, 3439-3442.
(b) Detrembleur, C.; Debuigne, A.; Bryaskova, R.; Charleux, B.; Jérôme, R. Macromol. Rapid Commun. 2006, 27, 37-41.
(a) Debuigne, A.; Caille, J.-R.; Willet, N.; Jerome, R. Macromolecules 2005, 38, 9488-9496.
(b) Bryaskova, R.; Willet, N.; Debuigne, A.; Jerome, R.; Detrembleur, C. J. Polym. Sci., Part A: Polym. Chem. 2007, 45 (1), 81-89.
Detrembleur, C.; Stoilova, O.; Bryaskova, R.; Debuigne, A.; Mouithys-Mickalad, A.; Jerome, R. Macromol. Rapid Commun. 2006, 27, 498-504.
(a) Wan, D.; Satoh, K.; Kamigaito, M.; Okamoto, Y. Macromolecules 2005, 38, 10397-10405.
(b) Postma, A.; Davis, T. P.; Li, G.; Moad, G.; O'Shea, M. S. Macromolecules 2006, 39, 5307-5318.
(c) Pound, G.; McLeary, J. B.; McKenzie, J. M.; Lange, R. F. M.; Klumperman, B. Macromolecules 2006, 39, 7796-7797.
(d) Klumperman, B.; McLeary, J. B.; van den Dungen, E. T. A.; Pound, G. Macromol. Symp. 2007, 248, 141-149.
(e) Nguyen, T.-L. U.; Eagles, K.; Davis, T. P.; Barner-Kowollik, C.; Stenzel, M. H. J. Polym. Sci., Polym. Chem. Part A 2006, 44, 4372-4383.
(a) Devasia, R.; Bindu, R. L.; Borsali, R.; Mougin, N.; Gnanou, Y. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 2005, 46 (2), 195-196.
(b) Devasia, R.; Bindu, R. L.; Borsali, R.; Mougin, N.; Gnanou, Y. Macromol. Symp. 2005, 229, 8-17.
(a) Bilalis, P.; Pitsikalis, M.; Hadjichristidis, N. J. Polym. Sci., Polym. Chem. Part A 2005, 44, 659-665.
(a) Yamago, S.; Ray, B.; Iida, K.; Yoshida, J.; Tada, T.; Yoshizawa, K.; Kwak, Y.; Goto, A.; Fukuda, T. J. Am. Chem. Soc. 2004, 126, 13908-13909.
(b) Ray, B.; Masashi, K.; Shigeru, Y. Macromolecules 2006, 39, 5259-5265.
(a) Yamago, S.; Kayahara, E.; Kotani, M.; Ray, B.; Kwak, Y.; Goto, A.; Fukuda, T. Angew. Chem., Int. Edt. 2007, 46, 1304-1306.
Kaneyoshi, H.; Matyjaszewski, K. Macromolecules 2006, 39, 2757-2763.
Maria, S.; Kaneyoshi, H.; Matyjaszewski, K.; Poli, R. Chem.-Eur. J. 2007, 13, 2480-2492.
Mc Allister, R.; Weber, J. H. J. Organomet. Chem. 1974, 77, 91-105.
Wolf, F.; Lohs, K.; Boehm, S. Makromol. Chem. 1970, 134, 241-251.
Evidence of the integrity of PNVP upon treatment by potassium hydroxide at room temperature in methanol is provided as Supporting Information.
Chung, T. W.; Cho, K. Y.; Lee, H.-C.; Nah, J. W.; Yeo, J. H.; Akaike, T.; Cho, C. S. Polymer 2004, 45, 1591-1597.
Torchilin, V. P.; Levchenko, T. S.; Whiteman, K. R.; Yaroslavov, A. A.; Tsatsakis, A. M.; Rizos, A. K.; Michailova, E. V.; Shtilman, M. I. Biomaterials 2001, 22, 3035-3044.
(a) Cameron, N. S.; Corbierre, M. K.; Eisenberg, A. Can. J. Chem. 1999, 77, 1311-1326.
(b) Zhang, L.; Shen, H.; Eisenberg, A. Macromolecules 1997, 30, 1001-1011.
(c) Zhang, L.; Eisenberg, A. Polym. Adv. Technol. 1998, 9, 677-699.
(d) Zhang, L.; Eisenberg, A. Macromolecules 1999, 32, 2239-2249.