Amphiphilic poly(vinyl acetate)-b-poly(N-vinylpyrrolidone) and novel double hydrophilic poly(vinyl alcohol)-b-poly(N-vinylpyrrolidone) block copolymers prepared by cobalt-mediated radical polymerization

Debuigne, Antoine; Willet, Nicolas; Jérôme, Robert; Detrembleur, Christophe

doi:10.1021/ma0712908

Article (Scientific journals)

Amphiphilic poly(vinyl acetate)-b-poly(N-vinylpyrrolidone) and novel double hydrophilic poly(vinyl alcohol)-b-poly(N-vinylpyrrolidone) block copolymers prepared by cobalt-mediated radical polymerization

Debuigne, Antoine; Willet, Nicolas; Jérôme, Robert et al.

2007 • In Macromolecules, 40 (20), p. 7111-7118

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/4093

DOI
10.1021/ma0712908

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Keywords :

radical polymerization; cobalt-mediated radical polymerization (CMRP)

Abstract :

[en] Well-defined amphiphilic block copolymers of poly(vinyl acetate) (PVAc) and poly(N-vinylpyrrolidone) (PNVP) were synthesized by cobalt-mediated radical polymerization (CMRP). The NVP polymerization initiated by poly(vinyl acetate) end-capped by the cobalt(II)acetylacetonate complex met the criteria of controlled polymerization, i.e., first-order kinetic in NVP, increase of the molar mass with the NVP conversion, and narrow molar mass distribution. Therefore, the length of the two blocks can be tuned by the [VAc]/[Co(acac)(2)] and the [NVP]/[PVAc] ratios for the synthesis of the macroinitiator and the polymerization of the second monomer, respectively. These amphiphilic PVAc-b-PNVP block copolymers were easily converted into the double hydrophilic PVOH-b-PNVP counterparts by selective methanolysis of the PVAc block. These two types of copolymers were prone to self-association into micelles in appropriate solvents.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Willet, Nicolas ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Publication date :

02 October 2007

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - Washington

Volume :

Issue :

Pages :

7111-7118

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma0712908

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique

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