Synthesis of poly(vinyl acetate) and poly(vinyl alcohol) containing block copolymers by combination of cobalt-mediated radical polymerization and ATRP

Debuigne, Antoine; Caille, Jean-Raphaël; Willet, Nicolas; Jérôme, Robert

doi:10.1021/ma051246x

Article (Scientific journals)

Synthesis of poly(vinyl acetate) and poly(vinyl alcohol) containing block copolymers by combination of cobalt-mediated radical polymerization and ATRP

Debuigne, Antoine; Caille, Jean-Raphaël; Willet, Nicolas et al.

2005 • In Macromolecules, 38 (23), p. 9488-9496

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https://hdl.handle.net/2268/4067

DOI
10.1021/ma051246x

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Keywords :

radical polymerization; cobalt-mediated radical polymerization (CMRP); block copolymers

Abstract :

[en] Poly(vinyl acetate) (PVAc) chains of a low polydispersity (Mw/Mn similar to 1.1-1.2) have been prepared by cobalt-mediated radical polymerization of vinyl acetate (VAc). They have been end-capped by an activated bromide by addition of an alpha-bromoester or an alpha-bromoketone containing nitroxide and converted into effective macroinitiators for the atom transfer radical polymerization of styrene (Sty), ethyl acrylate, and methyl methacrylate. Because each block is formed by a controlled process, well-defined PVAc containing diblock copolymers are easily prepared. The PVAc-b-PS copolymers synthesized from alpha-bromoketone end-capped PVAc can be converted into well-defined poly(vinyl alcohol)-b-polystyrene amphiphiles by methanolysis of the poly(vinyl acetate) block. Self-association of an amphiphilic poly(vinyl alcohol)(3500)-b-polystyrene(16 600) in a (4/1) water/tetrahydrofuran mixture results in the formation of vesicles as observed by transmission electron microscopy.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Caille, Jean-Raphaël; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Willet, Nicolas ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Synthesis of poly(vinyl acetate) and poly(vinyl alcohol) containing block copolymers by combination of cobalt-mediated radical polymerization and ATRP

Publication date :

15 November 2005

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - Washington

Volume :

Issue :

Pages :

9488-9496

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma051246x

Funders :

Solvay sa
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique

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