La spectroscopie des complexes de transfert de charge peut contribuer à l'interprétation du premier potentiel d'ionisation du donneur (éthylenimine, oxyde d'éthylene, sulfure d'éthylene)
[en] The relationships between the ionization energy (IE) of a donor compound and the position of the UV photoabsorption band of the complex of this donor with iodine as an acceptor are carefully analyzed. Their specificity with respect to (i) the adiabatic and vertical IE and (ii) the nature of the ionized orbital (n or pi) is examined. This analysis allowed us to attempt to determine the nature of the molecular orbital (MO) involved in the ionization process of ethylenimine, ethylene oxide and ethylene sulfide. Very likely the first IE corresponds to the ionization of the non-bonding (n) orbital located on the N and O atoms. Owing to the closeness of the "n" and "pi" IE for sulfides, in the case of ethylene sulfide no conclusion could be drawn.
Research Center/Unit :
Laboratoire des Etats Ionisés.
Disciplines :
Chemistry
Author, co-author :
Locht, Robert ; Université de Liège - ULiège > Department of Chemistry (Faculté des sciences) > Laboratoire de Dynamique Moléculaire (Sciences)
Language :
French
Title :
La spectroscopie des complexes de transfert de charge peut contribuer à l'interprétation du premier potentiel d'ionisation du donneur (éthylenimine, oxyde d'éthylene, sulfure d'éthylene)
Alternative titles :
[en] The spectroscopy of charge transfer complexes can contribute to the interpretation of the first ionization potential of the donor (ethylenimine, ethylene oxide and ethylene sulfide)
Defense date :
23 April 1971
Number of pages :
44
Institution :
ULiège - Université de Liège
Degree :
PhD
Promotor :
D'Or, L.
Momigny, J.
Funders :
FRFC - Fonds de la Recherche Fondamentale Collective
Commentary :
Thèse Annexe (secondary thesis)
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