[en] A pump-probe experiment that can examine a pure charge migration on a time scale short compared to the onset of nuclear motion is discussed. The mass spectrometric studies of Schlag et al. suggest that short peptide terminated by an aromatic amino acid are particularly suitable test compounds. The pump pulse needs to ionize the molecule on a time scale short compared to the period of the electronic motion, typically sub-fs. However, ionization occurs preferentially when the electrical field of the light is maximal so that the duration of the pulse envelope can be somewhat longer. Detection by photoelectron spectrometry of the peptide cation, to produce a dication, is shown to be able to probe the electronic rearrangement.
Disciplines :
Chemistry
Author, co-author :
Remacle, Françoise ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de chimie physique théorique
Levine, Raphaël David
Language :
English
Title :
Probing ultrafast purely electronic charge migration in small peptides
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Bibliography
R. Weinkauf, P. Schanen, A. Metsala, E.W. Schlag, M. Burgle, and H. Kesslet, J. Phys. Chem. 100(47) (1996) 18567.
R. Weinkauf, P. Schanen, D. Yang, S. Sonkara, and E. W. Schlag, J. Phys. Chem. 99(28) (1995) 11255.
R. Weinkauf, E. W. Schlag, T. J. Martinez, and R. D. Levine, J. Phys. Chem. A 101(42) (1997) 7702.
L. Y. Baranov and E. W. Schlag, Z. Naturforsch. Sect, a-a, J. Phys. Sci. 54(6)-(7) (1999) 387.
S. Y. Sheu, D. Y. Yang, H. L. Selzle, and E. W. Schlag, European Phys. J. D 20(2) (2002) 557.
S. Y. Sheu and E. W. Schlag, International J. Mass Spectrometry 219(1) (2002) 73.
S. Y. Sheu, E. W. Schlag, D. Y. Yang, and H. L. Selzle, J. Phys. Chem. A 105(26) (2001) 6353.
E. W. Schlag, S. Y. Sheu, D. Y. Yang, H. L. Selzle, and S. H. Lin, J. Phys. Chem. B 104(32) (2000) 7790.
E. W. Schlag, S. Y. Sheu, D. Y. Yang, H. L. Selzle, and S. H. Lin, Proc. Nat. Academy Sci. USA 97(2) (2000) 1068.
L. Lehr, T. Horneff, R. Weinkauf, and E. W. Schlag, J. Phys. Chem. A 109(36) (2005) 8074.
E.W.Schlag, H. L. Selzle, P. Schanen, R. Weinkauf, and R. D. Levine, J. Phys. Chem. A 110(27) (2006) 8497.
Y. J. Hu, B. Hadas, M. Davidovitz, B. Balta, and C. Lifshitz, J. Phys. Chem. A 107(34) (2003) 6507.
M. S. Thompson, W. D. Cui, and J. P. Reilly, Angew. Chem.-Int. Ed. 43(36) (2004) 4791.
F. Remacle, R. D. Levine, and M. A. Ratner, Chem. Phys. Lett. 285(1)-(2) (1998) 25.
F. Remacle and R. D. Levine, Proc. Nat. Academy Sci. USA 103(18) (2006) 6793.
F. Remacle and R. D. Levine, J. Chem. Phys. 104(3) (1996) 1399.
F. Remacle and R. D. Levine, J. Chem. Phys. 107(9) (1997) 3382.
F. Remacle and R. D. Levine, J. Chem. Phys. 107(9) (1997) 3392.
H. L. Selzle, E. W. Schlag, F. Remacle, and R. D. Levine, Collection Czechoslovak Chem. Commun. 63(7) (1998) 1143.
A. Held and E. W. Schlag, Accounts Chem. Res. 31(7) (1998) 467.
K. Muller-Dethlefs and E. W. Schlag, Angew. Chem.-Int. Ed. 37(10) (1998) 1346.
O. Gessner, A. M. D. Lee, J. P. Shaffer, H. Reisler, S. V. Levchenko, A. I. Krylov, J. G. Underwood, H. Shi, A. L. L. East, D. M. Wardlaw, E. T. Chrysostom, C. C. Hayden, and A. Stolow, Science 311(5758) (2006) 219.
A. Stolow, A. E. Bragg, and D. M. Neumark, Chem. Reviews 104(3) (2004) 1719.
A. Stolow, Annu. Rev. Phys. Chem. 54 (2003) 89.
G. L. Yudin, S. Chelkowski, J. Itatani, A. D. Bandrauk, P. B. Corkum, Phys. Rev. A 72(4) (2005).
M. Drescher, M. Hentschel, R. Kienberger, M. Uiberacker, V. Yakovlev, A. Scrinizi, T. Westerwalbesloh, U. Kleineberg, U. Heinzmann, and F. Krausz, Nature 419(6909) (2002) 803.
M. Hentschel, R. Kienberger, C. Spielmann, G. A. Reider, N. Milosevic, T. Brabec, P. Corkum, U. Heinzmann, M. Drescher, and F. Krausz, Nature 414(6863) (2001) 509.
M. F. Kling, C. Siedschlag, A. J. Verhoef, J. I. Khan, M. Schultze, T. Uphues, Y. Ni, M. Uiberacker, M. Drescher, F. Krausz, M. J. J. Vrakking, Science 312(5771) (2006) 246.
R. Kienberger, M. Uiberacker, E. Goulielmakis, A. Baltuska, M. Drescher, and F. Krausz, J. Modern Optics 52(2)-(3) (2005) 261.
F. Krausz and M. Ivanov, Rev. Mod. Phys. (2006) submitted.
H. Niikura, D. M. Villeneuve, and P. B. Corkum, Phys. Rev. A 73(1) (2006) 021402.
G. L. Yudin, A. D. Bandrauk, and P. B. Corkum, Phys. Rev. Lett. 96(5) (2006) 063002.
H. Niikura, F. Legare, R. Hasbani, M. Y. Ivanov, D. M. Villeneuve, and P. B. Corkum, Nature 421(6925) (2003) 826.
C. Siedschlag, H. G. Muller, and M. J. J. Vrakking, Laser Phys. 15(5) (2005) 916.
N. Dudovich, O. Smirnova, J. Levesque, Y. Mairesse, M. Y. Ivanov, D. M. Villeneuve, and P. B. Corkum, Nature Phys. 2(11) (2006) 781.
F. Remacle and R. D. Levine, Int. J. Quantum Chem. 67(1) (1998) 85.
M. Desouter-Lecomte, D. Dehareng, B. Leyh-Nihant, M. T. Praet, A. J. Lorquet, and J. C. Lorquet, J. Phys. Chem. 89(1) (1985) 214.
D. R. Yarkony, Rev. Modern Phys. 68(3) (1996) 985.
G. A. Worth and L. S. Cederbaum, Ann. Rev. Phys. Chem. 55 (2004) 127.
Y. Haas, M. Kiessinger, and S. Zilberg, Conical Intersections in Photochemistry, Spectroscopy, and Chemical Dynamics. Special Issue Edn., Elsevier, Amsterdam (2000), Vol. 259.
W. Domcke, D. R. Yarkony, and H. Koppel, Conical Intersections; Electronic Structure, Dynamics and Spectroscopy. World Scientific, Singapore (2004), Vol. 15.
R. D. Levine, Molecular Reaction Dynamics. University Press, Cambridge (2005).
F. Remacle and R. D. Levine, J. Chem. Phys. 125(13) (2006) 133321.
F. Remacle, R. D. Levine, E. W. Schlag, and R. Weinkauf, J. Phys. Chem. A 103(49) (1999) 10149.
F. Remacle and R. D. Levine, J. Chem. Phys. 110(11) (1999) 5089.
L. S. Cederbaum and J. Zobeley, Chem. Phys. Lett. 307(3)-(4) (1999) 205.
A. I. Kuleff, J. Breidbach, and L. S. Cederbaum, J. Chem. Phys. 123(3) (2005) 044111.
H. Hennig, J. Breidbach, and L. S. Cederbaum, J. Chem. Phys. 122(13) (2005).
H. Hennig, J. Breidbach, and L. S. Cederbaum, J. Phys. Chem. A 109(2) (2005) 409.
M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgomery, T. Vreven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hase gawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Kiene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G. A. Voth, P. Salvador, J. J. Dannenberg, V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, O. Parkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford, J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, and J. A. Pople, Gaussian 03, Revision B.04 (2003).
J. A. Pople and R. K. Nesbet, J. Chem. Phys. 22 (1954) 571.
F. Remade and R. D. Levine, Faraday Discussions 131 (2006) 45.
F. Remade and R. D. Levine, J. Phys. Chem. C 111 (2007) 2301.
J. E. Braun and H. J. Neusser, Mass Spectrom. Rev. 21(1) (2002) 16.
H. J. Neusser and K. Siglow, Chem. Rev. 100(11) (2000) 3921.
K. Seki and H. Inokuchi, Chem. Phys. Lett. 65(1) (1979) 158.
E. J. Heller, Accounts Chem. Res. 14(12) (1981) 368.
R. L. Sundberg and E. J. Heller, Chem. Phys. Lett. 93 (1982) 586.
R. Manne, Chem. Phys. Lett. 104(3) (1984) 378.
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