Aqueous medium quenching; Coordination polymer; Mn(II); Sensing of Pd2+; pH-dependenent LOD value; Aqueous media; Coordination Polymers; Coordination-polymers; Detection value; Limit of detection; Ph-dependenent limit of detection value; X- ray diffractions; Catalysis; Chemistry (all); Organic Chemistry
Abstract :
[en] Herein, we report the synthesis of a Mn(II)-based coordination polymer (CP); and its structure, phase consistency and thermal stability have been established by single-crystal X-ray diffraction (SCXRD), powder X-ray diffraction (PXRD) and thermalgravimetric analysis (TGA) respectively. This is the first example of paramgnetic Mn(II)-based CP that acts as pH-dependent emitting material [λem=525 nm (pH=2.0-4.0) and 450 nm (pH=5.0-12.0)]. Its emission is quenched by Pd2+ in aqueous medium in presence of other thirteen cations with reasonably low pH-dependent limits of detection (LODs) [21.178 ppb (pH=3), 15.005 ppb (pH=7.0) and 59.940 ppb (pH=10.0)] as described by well-established mechanism. Therefore, urgency of such stable sensor remains high in regard to the environmental pollution.
Disciplines :
Chemistry
Author, co-author :
Shit, Manik ; Department of Chemistry, Jadavpur University, Jadavpur, Kolkata, 700 032, India
Mahapatra, Manas ; Université de Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM) ; Department of Chemistry, Jadavpur University, Jadavpur, Kolkata, 700 032, India
Sepay, Nayim; Department of Chemistry, Lady Brabourne College, Kolkata, 700017, India
Sinha, Chittaranjan; Department of Chemistry, Jadavpur University, Jadavpur, Kolkata, 700 032, India
Dutta, Basudeb ; Institute for Integrated Cell-Material Sciences, Kyoto University, Kyoto, 606-8501, Japan ; Department of Chemistry, Aliah University, New Town, Kolkata, 700160, India
Hedayetullah Mir, Mohammad ; Department of Chemistry, Aliah University, New Town, Kolkata, 700160, India
Language :
English
Title :
Highly Efficient Detection of Pd2+ in Aqueous Medium by an Elusive Mn(II) Coordination Polymer.
Publication date :
10 December 2024
Journal title :
Chemistry
ISSN :
0947-6539
eISSN :
1521-3765
Publisher :
John Wiley and Sons Inc, Germany
Volume :
30
Issue :
69
Pages :
e202402425
Peer reviewed :
Peer Reviewed verified by ORBi
Funding text :
The authors are thankfull to Jadavpur University, India for infrastucture. H.\u2005M. thanks SERB, India (Grant No. CRG/2022/001842, dated 19/12/2022) for funding.
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