Assessment of Multiple Trace Metal Fluxes in a Semi-Arid Watershed Containing Mine Tailing, Using a Multiple Tool Approach (Zaida Mine, Upper Moulouya Watershed, Morocco)
GIS; remote sensing; RUSLE model; sediment contamination; soil erosion; trace metals flux; Oceanography; Water Science and Technology; Waste Management and Disposal; Earth-Surface Processes
Abstract :
[en] Few studies have quantified the complex flux of trace metals from mine tailings to rivers through water erosion, especially in the semi-arid region of North Morocco (Zaida mine) where soil erosion is a severe issue. This study applies (i) methods to understand and estimate the complex flux of trace metals from mine tailings to rivers, using the RUSLE model combined with the concentration of trace metals in the soil and additionally (ii) pollution indices and statistical analyses to assess the sediment contamination by Cd, Cu, Pb, and Zn. Our study revealed that the basin has a low erosion rate, with an average of 9.1 t/ha/yr. Moreover, the soil contamination is particularly high at the north of the mine tailings, as prevailing winds disperse particles across the basin. The assessment of the sediments indicated that Pb is the main contaminant, with concentrations exceeding 200 mg/kg specifically downstream of the tailings. This study also identified high a concentration of trace elements 14 km away from the tailings alongside the Moulouya river, due to the specific hydrological transport patterns in the area. This research contributes to a better understanding of the transport and fate of the trace metals in mining areas. It proposes a replicable method that can be applied in other regions to assess the contamination flows and thereby assist water resource management.
Disciplines :
Environmental sciences & ecology
Author, co-author :
Mimouni, Yassine ; Université de Liège - ULiège > Freshwater and OCeanic science Unit of reSearch (FOCUS) ; Laboratory for Agricultural Productions Improvement, Biotechnology and Environment, Department of Biology, Faculty of Sciences, University Mohammed First, Oujda, Morocco
Chafi, Abdelhafid; Laboratory for Agricultural Productions Improvement, Biotechnology and Environment, Department of Biology, Faculty of Sciences, University Mohammed First, Oujda, Morocco
Bouabdli, Abdelhak ; Laboratory of Geosciences, Department of Geology, Faculty of Science, Ibn Tofail University, Kenitra, Morocco
Baghdad, Bouamar; Casablanca School of Architecture and Landscape—Honoris United Universities, Casablanca, Morocco
Deliège, Jean-François ; Université de Liège - ULiège > Département de Biologie, Ecologie et Evolution > Aquapôle
Language :
English
Title :
Assessment of Multiple Trace Metal Fluxes in a Semi-Arid Watershed Containing Mine Tailing, Using a Multiple Tool Approach (Zaida Mine, Upper Moulouya Watershed, Morocco)
Publication date :
17 July 2024
Journal title :
Hydrology
eISSN :
2306-5338
Publisher :
Multidisciplinary Digital Publishing Institute (MDPI)
Alewell C. Borrelli P. Meusburger K. Panagos P. Using the USLE: Chances, Challenges and Limitations of Soil Erosion Modelling Int. Soil Water Conserv. Res. 2019 7 203 225 10.1016/j.iswcr.2019.05.004
Napoli M. Cecchi S. Orlandini S. Mugnai G. Zanchi C.A. Simulation of Field-Measured Soil Loss in Mediterranean Hilly Areas (Chianti, Italy) with RUSLE Catena 2016 145 246 256 10.1016/j.catena.2016.06.018
Aouichaty N. Bouslihim Y. Hilali S. Zouhri A. Koulali Y. Estimation of Water Erosion in Abandoned Quarries Sites Using the Combination of RUSLE Model and Geostatistical Method Sci. Afr. 2022 16 e01153 10.1016/j.sciaf.2022.e01153
Moustakim M. Benmansour M. Nouira A. Benkdad A. Damnati B. Caesium-137 Re-Sampling Approach and Excess Lead-210 Sediment Dating to Assess the Impacts of Climate Change and Agricultural Practices on Soil Erosion and Sedimentation in Northwest Morocco Environ. Earth Sci. 2022 81 278 10.1007/s12665-022-10409-6
Gourfi A. Daoudi L. Rhoujjati A. Benkaddour A. Fagel N. Use of Bathymetry and Clay Mineralogy of Reservoir Sediment to Reconstruct the Recent Changes in Sediment Yields from a Mountain Catchment in the Western High Atlas Region, Morocco Catena 2020 191 104560 10.1016/j.catena.2020.104560
Briak H. Mrabet R. Moussadek R. Aboumaria K. Use of a Calibrated SWAT Model to Evaluate the Effects of Agricultural BMPs on Sediments of the Kalaya River Basin (North of Morocco) Int. Soil Water Conserv. Res. 2019 7 176 183 10.1016/j.iswcr.2019.02.002
El Jazouli A. Barakat A. Ghafiri A. El Moutaki S. Ettaqy A. Khellouk R. Soil Erosion Modeled with USLE, GIS, and Remote Sensing: A Case Study of Ikkour Watershed in Middle Atlas (Morocco) Geosci. Lett. 2017 4 25 10.1186/s40562-017-0091-6
Echogdali F.Z. Boutaleb S. Taia S. Ouchchen M. Id-Belqas M. Kpan R.B. Abioui M. Aswathi J. Sajinkumar K.S. Assessment of Soil Erosion Risk in a Semi-Arid Climate Watershed Using SWAT Model: Case of Tata Basin, South-East of Morocco Appl. Water Sci. 2022 12 137 10.1007/s13201-022-01664-w
Ahmad W.S. Jamal S. Taqi M. El-Hamid H.T.A. Norboo J. Estimation of Soil Erosion and Sediment Yield Concentrations in Dudhganga Watershed of Kashmir Valley Using RUSLE & SDR Model Environ. Dev. Sustain. 2022 26 215 238 10.1007/s10668-022-02705-9
Mahoney D. Blandford B. Fox J. Coupling the Probability of Connectivity and RUSLE Reveals Pathways of Sediment Transport and Soil Loss Rates for Forest and Reclaimed Mine Landscapes J. Hydrol. 2021 594 125963 10.1016/j.jhydrol.2021.125963
Hao G.R. Li J.K. Li S. Li K.B. Zhang Z.H. Li H.E. Quantitative Assessment of Non-Point Source Pollution Load of PN/PP Based on RUSLE Model: A Case Study in Beiluo River Basin in China Environ. Sci. Pollut. Res. 2020 27 33975 33989 10.1007/s11356-020-09587-2 32557060
Fressard M. Cossart E. Chaize B. Pluri-Decennial Erosion Rates Using SUM/ISUM and Sediment Traps Survey in the Mercurey Vineyards (Burgundy, France) Geomorphology 2022 403 108181 10.1016/j.geomorph.2022.108181
Wu Q. Wang M. A Framework for Risk Assessment on Soil Erosion by Water Using an Integrated and Systematic Approach J. Hydrol. 2007 337 11 21 10.1016/j.jhydrol.2007.01.022
Shi W. Wang J. Li X. Xu Q. Jiang X. Multi-Fractal Characteristics of Reconstructed Landform and Its Relationship with Soil Erosion at a Large Opencast Coal-Mine in the Loess Area of China Geomorphology 2021 390 107859 10.1016/j.geomorph.2021.107859
Tansel B. Rafiuddin S. Heavy Metal Content in Relation to Particle Size and Organic Content of Surficial Sediments in Miami River and Transport Potential Int. J. Sediment Res. 2016 31 324 329 10.1016/j.ijsrc.2016.05.004
Ma Y. Qin Y. Zheng B. Zhang L. Zhao Y. Seasonal Variation of Enrichment, Accumulation and Sources of Heavy Metals in Suspended Particulate Matter and Surface Sediments in the Daliao River and Daliao River Estuary, Northeast China Environ. Earth Sci. 2015 73 5107 5117 10.1007/s12665-015-4325-7
Elouadihi N. Laghlimi M. Moussadek R. Laghrour M. Bouabdli A. Baghdad B. Phytoremediation Study of Mining Soils: Case of the Mibladen and Zaida Mine (High Moulouya, Morocco) J. Exp. Biol. Agric. Sci. 2022 10 1391 1400 10.18006/2022.10(6).1391.1400
El Azhari A. Rhoujjati A. EL Hachimi M.L. Assessment of Heavy Metals and Arsenic Contamination in the Sediments of the Moulouya River and the Hassan II Dam Downstream of the Abandoned Mine Zeïda (High Moulouya, Morocco) J. Afr. Earth Sci. 2016 119 279 288 10.1016/j.jafrearsci.2016.04.011
Bouabdli A. Saidi N. M’Rabet S. Escarre J. Leblanc M. Heavy Metal Transport by the Moulouya River (Morocco) Rev. Sci. l’Eau 2005 18 199 213 10.7202/705556AR
Ech-Charef A. Dekayir A. Jordán G. Rouai M. Chabli A. Qarbous A. El Houfy F.Z. Soil Heavy Metal Contamination in the Vicinity of the Abandoned Zeïda Mine in the Upper Moulouya Basin, Morocco. Implications for Airborne Dust Pollution under Semi-Arid Climatic Conditions J. Afr. Earth Sci. 2023 198 104812 10.1016/j.jafrearsci.2022.104812
Hoepffner C. La Tectonique Hercynienne Dans l’Est Du Maroc PhD Thesis Universite Louis Pasteur Strasbourg, France 1987
Iavazzo P. Adamo P. Boni M. Hillier S. Zampella M. Mineralogy and Chemical Forms of Lead and Zinc in Abandoned Mine Wastes and Soils: An Example from Morocco J. Geochemical Explor. 2012 113 56 67 10.1016/j.gexplo.2011.06.001
Jébrak M. Marcoux É. Nasloubi M. Zaharaoui M. From Sandstone- to Carbonate-Hosted Strata Bound Deposits: An Isotope Study of Galena in the Upper-Moulouya District (Morocco) Miner. Depos. 1998 33 406 415 10.1007/s001260050158
Iavazzo P. Ducci D. Adamo P. Trifuoggi M. Migliozzi A. Boni M. Impact of Past Mining Activity on the Quality of Water and Soil in the High Moulouya Valley (Morocco) Water Air Soil Pollut. 2012 223 573 589 10.1007/s11270-011-0883-9
Hachimi M.L.E. Bouabdli A. Fekhaoui M. Les Rejets Miniers de Traitement: Caractérisation, Capacité Polluante et Impacts Environnementaux, Mine Zeïda, Mine Mibladen, Haute Moulouya (Maroc) Environ. Ingénierie Dev. 2013 N°63-mars 2013 23 42 10.4267/dechets-sciences-techniques.2567
Chahboune M. Chahlaoui A. Zaid A. Contribution to Comparative Study of the Physico-Chemical Quality of Waters of Moulouya and Ansegmir Rivers in Upstream of Hassan II Dam (Province of Midelt, Morocco) J. Biodivers. Environ. Sci. 2014 2014 278 288
Thomas G. Soil PH and Soil Acidity Methods of Soil Analysis Part 3: Chemical Methods Sparks D.L. Page A.L. Helmke P.A. Loeppert R.H. John Wiley and Sons Hoboken, NJ, USA Soil Science Society of America and American Society of Agronomy, USA 1996 475 489 978-0-891-18825-4
Smith J. Doran J. Measurement and Use of PH and Electrical Conductivity for Soil Quality Analysis Methods for Assessing Soil Quality Doran W. Jones A.J. Soil Science Society of America Special Publication Madison, WI, USA 1996 169 186
AFNOR NF P94-048 Sols Reconnaissance et Essais-Détermination de La Teneur En Carbonate—Méthode Du Calcimètre Association Française de Normalisation Paris, France 1996
Hoenig M. Spectrométrie d’absorption Atomique Électrothermique: Contribution a l’établissement d’une Méthodologie Rationnelle Pour La Détermination Des Éléments Traces Dans Les Milieux Naturels Ph.D. Thesis L’université des Sciences et Techniques de Lille Flandres Artois Lille, France 1990
Laghlimi M. Douaik A. Baghdad B. Hassan E.H. Rachid M. Meryem T. Spatial Distribution of Soil Heavy Metals in the Zaida Mine (Morocco) Based on Geostatistical Methods Int. J. Adv. Res. 2015 3 337 349
Renard K.G. Foster G. Weesies G. McCool D. Yoder D. Predicting Soil Erosion by Water: A Guide to Conservation Planning with the Revised Universal Soil Loss Equation (RUSLE) US Department of Agriculture, Agricultural Research Service Washington, DC, USA 1997
Panagos P. Ballabio C. Borrelli P. Meusburger K. Klik A. Rousseva S. Tadić M.P. Michaelides S. Hrabalíková M. Olsen P. et al. Rainfall Erosivity in Europe Sci. Total Environ. 2015 511 801 814 10.1016/j.scitotenv.2015.01.008 25622150
Arnoldus H.M.J. An Approximation of the Rainfall Factor in the Universal Soil Loss Equation An Approximation of the Rainfall Factor in the Universal Soil Loss Equation John Wiley and Sons Ltd. Chichester, UK 1980 127 132
Di Lena B. Curci G. Vergni L. Analysis of Rainfall Erosivity Trends 1980–2018 in a Complex Terrain Region (Abruzzo, Central Italy) from Rain Gauges and Gridded Datasets Atmosphere 2021 12 657 10.3390/atmos12060657
Kayet N. Pathak K. Chakrabarty A. Sahoo S. Evaluation of Soil Loss Estimation Using the RUSLE Model and SCS-CN Method in Hillslope Mining Areas Int. Soil Water Conserv. Res. 2018 6 31 42 10.1016/j.iswcr.2017.11.002
Desmet P.J.J. Govers G. A GIS Procedure for Automatically Calculating the USLE LS Factor on Topographically Complex Landscape Units J. Soil Water Conserv. 1996 51 427 433
Zhu M. He W. Zhang Q. Xiong Y. Tan S. He H. Spatial and Temporal Characteristics of Soil Conservation Service in the Area of the Upper and Middle of the Yellow River, China Heliyon 2019 5 e02985 10.1016/j.heliyon.2019.e02985
Sharpley A.N. Williams J.R. EPIC—Erosion/Productivity Impact Calculator: 1. Model Documentation U.S. Department of Agriculture Technical Bulletin No. 1768 Washington, DC, USA 1990 235p Available online: https://epicapex.tamu.edu/media/h2gkyznv/epicmodeldocumentation.pdf (accessed on 16 June 2024)
Neitsch S. Arnold J. Kiniry J. Williams J. Soil & Water Assessment Tool Theoretical Documentation Version 2009 Texas Water Resources Institute Technical Report College Station, TX, USA 2011 1 647 10.1016/j.scitotenv.2015.11.063
van der Knijff J. Jones R. Montanarella L. Soil Erosion Risk Assessment in Italy EPIC Redwood City, CA, USA 2000
Rendana M. Idris W.M.R. Rahim S.A. The Variation of Riverine Heavy Metal Flux Using RUSLE Model in the Ranau Sub-Basins, Malaysia. Adjacent to Ultrabasic Soil Water Air Soil Pollut. 2022 233 495 10.1007/s11270-022-05979-x
Bella Atangana M.S. Dam Ngoupayou J.R. Deliege J.F. Hydrogeochemistry and Mercury Contamination of Surface Water in the Lom Gold Basin (East Cameroon): Water Quality Index, Multivariate Statistical Analysis and Spatial Interpolation Water 2023 15 2502 10.3390/w15132502
USDA United States Department of Agriculture Soil Conservation Service National Engineering Handbook Section 3 USDA United States Department of Agriculture Soil Conservation Service Washington, DC, USA 1972
Zhang H. Luo Y. Makino T. Wu L. Nanzyo M. The Heavy Metal Partition in Size-Fractions of the Fine Particles in Agricultural Soils Contaminated by Waste Water and Smelter Dust J. Hazard. Mater. 2013 248–249 303 312 10.1016/j.jhazmat.2013.01.019 23416473
Menzel R.G. Enrichment Ratios For Water Quality Modeling CREAMS a Field Scale Model for Chemicals/Runoff, and Erosion from Agricultural Management Systems NATURAL Forgotten Books London, UK 1980 486 492 0364976101
Mueller G. Schwermetalle in Den Sedimenten Des Rheins—Veranderungen Seit 1971 Umsch. Wissensch. Techn. 1979 79 778 783
Förstner U. Müller G. Concentrations of Heavy Metals and Polycyclic Aromatic Hydrocarbons in River Sediments: Geochemical Background, Man’s Influence and Environmental Impact GeoJournal 1981 5 417 432 10.1007/BF02484715
Tomlinson D.L. Wilson J.G. Harris C.R. Jeffrey D.W. Problems in the Assessment of Heavy-Metal Levels in Estuaries and the Formation of a Pollution Index Helgoländer Meeresunters. 1980 33 566 575 10.1007/BF02414780
MacDonald D.D. Ingersoll C.G. Berger T.A. Development and Evaluation of Consensus-Based Sediment Quality Guidelines for Freshwater Ecosystems Arch. Environ. Contam. Toxicol. 2000 39 20 31 10.1007/s002440010075 10790498
Radziuk H. Switoniak M. Soil Erodibility Factor (K) in Soils under Varying Stages of Truncation Soil Sci. Annu. 2021 72 134621 10.37501/soilsa/134621
Mhaske S.N. Pathak K. Dash S.S. Nayak D.B. Assessment and Management of Soil Erosion in the Hilltop Mining Dominated Catchment Using GIS Integrated RUSLE Model J. Environ. Manag. 2021 294 112987 10.1016/j.jenvman.2021.112987
Royaume du Maroc, Ministère de l’Intérieur, Secrétariat Général, Division de l’Urbanisme et de l’Environnement Monographie de la Province de Midelt Administration de la Province de Midelt Midelt, Morocco 2020 45p
Zuazo V.H.D. Pleguezuelo C.R.R. Soil-Erosion and Runoff Prevention by Plant Covers. A Review Agron. Sustain. Dev. 2008 28 65 86 10.1051/agro:2007062
Aguilar F.J. Nemmaoui A. Aguilar M.A. Chourak M. Zarhloule Y. García Lorca A.M. A Quantitative Assessment of Forest Cover Change in the Moulouya River Watershed (Morocco) by the Integration of a Subpixel-Based and Object-Based Analysis of Landsat Data Forests 2016 7 23 10.3390/f7010023
Baize D. Teneurs totales en éléments traces métalliques dans les sols (France): Références et stratégies d’interprétation. Programme ASPITET INRA Paris, France 1997 2-7380-0747-3
Essien J.P. Inam E.D. Ikpe D.I. Udofia G.E. Benson N.U. Ecotoxicological Status and Risk Assessment of Heavy Metals in Municipal Solid Wastes Dumpsite Impacted Soil in Nigeria Environ. Nanotechnol. Monit. Manag. 2019 11 100215 10.1016/j.enmm.2019.100215
Grard A. Deliège J.F. Characterizing Trace Metal Contamination and Partitioning in the Rivers and Sediments of Western Europe Watersheds Hydrology 2023 10 51 10.3390/hydrology10020051
Zamani-Ahmadmahmoodi R. Esmaili-Sari A. Mohammadi J. Bakhtiari A.R. Savabieasfahani M. Spatial Distribution of Cadmium and Lead in the Sediments of the Western Anzali Wetlands on the Coast of the Caspian Sea (Iran) Mar. Pollut. Bull. 2013 74 464 470 10.1016/j.marpolbul.2013.06.009 23806672
Parra A. Oyarzún J. Maturana H. Kretschmer N. Meza F. Oyarzún R. Natural Factors and Mining Activity Bearings on the Water Quality of the Choapa Basin, North Central Chile: Insights on the Role of Mafic Volcanic Rocks in the Buffering of the Acid Drainage Process Environ. Monit. Assess. 2011 181 69 82 10.1007/s10661-010-1814-8 21170583
Ghorbel Ben Abid M. Contamination Métallique Issue Des Déchets de L’ancien Site Minier de Jebel Ressas: Modélisation Des Mécanismes de Transfert et Conception de Cartes d’aléa Post-Mine Dans Un Contexte Carbonaté et Sous Un Climat Semi-Aride Ph.D. Thesis Evaluation Du Risque Pour La Sa, Université Paul Sabatier—Toulouse III Toulouse, France 2012 Volume 8
Jiménez-Oyola S. Valverde-Armas P.E. Romero-Crespo P. Capa D. Valdivieso A. Coronel-León J. Guzmán-Martínez F. Chavez E. Heavy Metal(Loid)s Contamination in Water and Sediments in a Mining Area in Ecuador: A Comprehensive Assessment for Drinking Water Quality and Human Health Risk Environ. Geochem. Health 2023 45 4929 4949 10.1007/s10653-023-01546-3 36997826
Elvine Paternie E.D. Hakkou R. Ekengele Nga L. Bitom Oyono L.D. Ekoa Bessa A.Z. Oubaha S. Khalil A. Geochemistry and Geostatistics for the Assessment of Trace Elements Contamination in Soil and Stream Sediments in Abandoned Artisanal Small-Scale Gold Mining (Bétaré-Oya, Cameroon) Appl. Geochem. 2023 150 105592 10.1016/j.apgeochem.2023.105592
Song Y. Ji J. Mao C. Yang Z. Yuan X. Ayoko G.A. Frost R.L. Heavy Metal Contamination in Suspended Solids of Changjiang River—Environmental Implications Geoderma 2010 159 286 295 10.1016/j.geoderma.2010.07.020
Liu S. Yu F. Lang T. Ji Y. Fu Y. Zhang J. Ge C. Spatial Distribution of Heavy Metal Contaminants: The Effects of Water-Sediment Regulation in the Henan Section of the Yellow River Sci. Total Environ. 2023 892 164568 10.1016/j.scitotenv.2023.164568
Zerizghi T. Yang Y. Wang W. Zhou Y. Zhang J. Yi Y. Ecological Risk Assessment of Heavy Metal Concentrations in Sediment and Fish of a Shallow Lake: A Case Study of Baiyangdian Lake, North China Environ. Monit. Assess. 2020 192 154 10.1007/s10661-020-8078-8 32006115
Shapiro S.S. Wilk M.B. An Analysis of Variance Test for Normality (Complete Samples) Biometrika 1965 52 591 611 10.1093/biomet/52.3-4.591
Ahouach Y. Baali A. Boushaba A. Hakam O. Azennoud K. Lyazidi A. Benmessaoud S. Assouguem A. Kara M. Alsaigh M.A. et al. Impact of the Controlled Dump of Fez City (Morocco): Evaluation of Metallic Trace Elements Contamination in the Sediments Water 2023 15 1209 10.3390/w15061209
Madyouni H. Almanza V. Benabdallah S. Joaquim-Justo C. Romdhane M.S. Habaieb H. Deliege J.F. Assessment of Water Quality Variations and Trophic State of the Joumine Reservoir (Tunisia) by Multivariate Analysis Water 2023 15 3019 10.3390/w15173019
Sekabira K. Origa H.O. Basamba T.A. Mutumba G. Kakudidi E. Assessment of Heavy Metal Pollution in the Urban Stream Sediments and Its Tributaries Int. J. Environ. Sci. Technol. 2010 7 435 446 10.1007/BF03326153
Jiang H.H. Cai L.M. Hu G.C. Wen H.H. Luo J. Xu H.Q. Chen L.G. An Integrated Exploration on Health Risk Assessment Quantification of Potentially Hazardous Elements in Soils from the Perspective of Sources Ecotoxicol. Environ. Saf. 2021 208 111489 10.1016/j.ecoenv.2020.111489 33080423
Bouzekri S. El Hachimi M.L. Touach N. El Fadili H. El Mahi M. Lotfi E.M. The Study of Metal (As, Cd, Pb, Zn and Cu) Contamination in Superficial Stream Sediments around of Zaida Mine (High Moulouya-Morocco) J. Afr. Earth Sci. 2019 154 49 58 10.1016/j.jafrearsci.2019.03.014
Dai Z.H. Feng X. Zhang C. Shang L. Qiu G. Assessment of Mercury Erosion by Surface Water in Wanshan Mercury Mining Area Environ. Res. 2013 125 2 11 10.1016/j.envres.2013.03.014