[en] In this study, dimethylacrylamide (DMA) homopolymer and DMA/ethylene glycol dimethacrylate (DMA/EGDMA) copolymers are produced by an atmospheric pulsed plasma deposition technique. Such a mild deposition method is used to limit monomer fragmentations and favor cross-linked structures formed through the unsaturated carbon double bond polymerization. The kinetics of deposition, and the dependence of the chemical and physical properties of the films on the comonomer ratio are investigated by combining surface and volume-sensitive techniques. In addition, water-stable catechol-bearing terpolymer films are easily produced from a precursor mixture composed of dopamine methacrylamide dissolved in a 50 mol% DMA/EGDMA solution. Finally, it is demonstrated that the developed coatings can be exploited for efficient one-step bioconjugation reaction for potential biological applications.
Research Center/Unit :
CESAM - Complex and Entangled Systems from Atoms to Materials - ULiège CERM - Center for Education and Research on Macromolecules - ULiège
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Moreno-Couranjou, Maryline ; Luxembourg Institute of Science and Technology [LIST] - Department of Materials Research and Technology - Luxembourg
Guillot, Jérôme; Luxembourg Institute of Science and Technology [LIST] - Department of Materials Research and Technology - Luxembourg
Audinot, Jean-Nicolas; Department of Materials Research and Technology, Luxembourg Institute of Science and Technology (LIST), Belvaux, Luxembourg
Bour, Jérôme; Luxembourg Institute of Science and Technology [LIST] - Department of Materials Research and Technology - Luxembourg
Prouvé, Emilie; University of Bordeaux - Laboratoire de Chimie et Biologie des Membranes et Nano‐Objets - CNRS - Bordeaux INP - France
Durrieu, Marie-Christine; University of Bordeaux - Laboratoire de Chimie et Biologie des Membranes et Nano‐Objets - CNRS - Bordeaux INP - France
Choquet, Patrick; Luxembourg Institute of Science and Technology [LIST] - Department of Materials Research and Technology - Luxembourg
Detrembleur, Christophe ; University of Liège [ULiège] - Complex and Entangled Systems from Atoms to Materials [CESAM] Research Unit - Center for Education and Research on Macromolecules [CERM] - Belgium
Language :
English
Title :
Atmospheric pulsed plasma copolymerization of acrylic monomers: Kinetics, chemistry, and applications
Publication date :
July 2020
Journal title :
Plasma Processes and Polymers
ISSN :
1612-8850
eISSN :
1612-8869
Publisher :
Wiley-VCH Verlag
Volume :
17
Issue :
7
Peer reviewed :
Peer Reviewed verified by ORBi
Name of the research project :
FNR - Luxembourg National Research Fund [LU] in the frame of the BIOREAFILM project
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique FNR - Fonds National de la Recherche
Funding text :
The authors would like to thank P. Grysan and J.-L. Biagi from LIST for the assistance with AFM and SEM analysis and fruitful discussions. Christophe Detrembleur is FNRS Research Director and thanks the National Fund for Scientific Research (Belgium) for funding. This study was carried out in the framework of the BIOREAFILM project funded by the Luxembourgish agency Fonds National de la Recherche (C15/MS/10365992/BIOREAFILM/Moreno).
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