[en] The greenhouse enables to promotion of plant yield through creating an optimal environment. Efficient solar energy conversion and storage is a promising strategy to address the energy shortage issue of greenhouses in winter. This paper prepares form-stable composite phase change materials (PCMs) to store solar energy efficiently. Lightweight and porous balsa wood subjected to high-temperature carbonization is designed to simultaneously solve the liquid leakage, enhance the thermal conductivity, and improve the photothermal conversion and thermal energy storage of PCM. OP44E and SEBS are utilized as PCM and thickeners, followed by vacuum impregnation into the
carbonized balsa wood (CW). Results indicate that the carbon content of CW increases with the augment of carbonization temperature. Shaping effects of CW and SEBS endow-composite PCMs to have the highest adsorption rate of 92.7 wt.% with enthalpy
over 190 J/g. Composite PCMs reveal reliable thermal properties and thermal stability
below 100 °C. Composite PCMs have photothermal conversion larger than 88% under
xenon lamp radiation. The temperature of PCMs on the shallow layer is higher owing to
their photothermal conversion capacity. Greenhouse test indicates that
CW/OP44E/SEBS greenhouse gains a higher PCM temperature of 71.5 °C at 70 min,
compared to 40.3 °C in empty and OP44E/SEBS cases. CW/OP44E/SEBS
greenhouse maintaining indoor temperature over 20 °C lasts 15.3 min longer than
empty and OP44E/SEBS greenhouses. In addition, form-stable composite PCMs
feature excellent thermal stability, and photothermal conversion is capable of
maintaining the stable indoor temperature of a greenhouse, indicating potential in the field of agricultural building temperature regulation.
Research center :
Sustainable Building Design Lab
Disciplines :
Architecture
Author, co-author :
Zhang, Zhaoli
Zhang, Nan
Pan, Xiyu
Yuan, Yanping
Sultan, Muhammad
Attia, Shady ; Université de Liège - ULiège > Département ArGEnCo > Techniques de construction des bâtiments
Language :
English
Title :
Carbonated balsa based shape-stable phase change materials with photothermal conversion and application in a greenhouse
Badji, A., Benseddik, A., Bensaha, H., Boukhelifa, A., Hasrane, I., Design, technology, and management of greenhouse: a review. J. Clean. Prod., 373, 2022, 133753, 10.1016/j.jclepro.2022.133753.
Pornea, A.M., Kim, H., Synthesis of hybrid dual-MOF encapsulated phase-changing material for improved broadband light absorption and photothermal conversion enabling efficient solar energy storage. Sol. Energy Mater. Sol. Cell., 244, 2022, 111817, 10.1016/j.solmat.2022.111817.
Sun, W., Wei, X., Zhou, B., Lu, C., Guo, W., Greenhouse heating by energy transfer between greenhouses: System design and implementation. Appl. Energy, 325, 2022, 119815, 10.1016/j.apenergy.2022.119815.
Bao, X., Yang, H., Xu, X., Xu, T., Cui, H., Tang, W., Sang, G., Fung, W.H., Development of a stable inorganic phase change material for thermal energy storage in buildings. Sol. Energy Mater. Sol. Cell., 208, 2020, 110420, 10.1016/j.solmat.2020.110420.
Wijesuriya, S., Booten, C., Bianchi, MarcusV.A., Kishore, R.A., Building energy efficiency and load flexibility optimization using phase change materials under futuristic grid scenario. J. Clean. Prod., 339, 2022, 130561, 10.1016/j.jclepro.2022.130561.
Ismail, M.M., Dincer, I., Bicer, Y., Saghir, M.Z., Effect of using phase change materials on thermal performance of passive solar greenhouses in cold climates. International Journal of Thermofluids, 19, 2023, 100380, 10.1016/j.ijft.2023.100380.
Zhu, J., Zhang, X., Hua, W., Ji, J., Lv, X., Current status and development of research on phase change materials in agricultural greenhouses: a review. J. Energy Storage, 66, 2023, 107104, 10.1016/J.EST.2023.107104.
Sarbu, I., Dorca, A., Review on heat transfer analysis in thermal energy storage using latent heat storage systems and phase change materials. Int. J. Energy Res. 43 (2019), 29–64, 10.1002/er.4196.
Mahdi, J.M., Lohrasbi, S., Nsofor, E.C., Hybrid heat transfer enhancement for latent-heat thermal energy storage systems: a review. Int. J. Heat Mass Tran. 137 (2019), 630–649.
Zhang, X., Zhang, Y., Li, H., Chen, Z., Enhanced thermal conductivity and photothermal effect of microencapsulated n-octadecane phase change material with calcium carbonate-polydopamine hierarchical shell for solar energy storage. Sol. Energy Mater. Sol. Cell., 256, 2023, 112336, 10.1016/j.solmat.2023.112336.
Yang, R., Li, D., Arıcı, M., Wang, B., Wu, Y., Ma, Y., Yang, X., Photothermal performance of plastic greenhouse embedded with phase change materials in translucent envelopes: a dynamic experimental study. J. Energy Storage, 58, 2023, 106375, 10.1016/j.est.2022.106375.
Le, W.T., Kankkunen, A., Rojas, O.J., Yazdani, M.R., Leakage-free porous cellulose-based phase change cryogels for sound and thermal insulation. Sol. Energy Mater. Sol. Cell., 256, 2023, 112337, 10.1016/j.solmat.2023.112337.
Singh, P., Sharma, R.K., Khalid, M., Goyal, R., Sarı, A., V Tyagi, V., Evaluation of carbon based-supporting materials for developing form-stable organic phase change materials for thermal energy storage: a review. Sol. Energy Mater. Sol. Cell., 246, 2022, 111896.
Nam, J., Yun, B.Y., Choi, J.Y., Kim, S., Potential of wood as thermal energy storage materials: different characteristics depending on the hierarchical structure and components. Int. J. Energy Res. 46 (2022), 14926–14945, 10.1002/er.8195.
Sun, Y., Zhang, N., Pan, X., Zhong, W., Qiu, B., Cai, Y., Yuan, Y., Thermal properties of biomass-based form-stable phase change material for latent heat thermal energy storage. Int. J. Energy Res. 45 (2021), 20372–20383, 10.1002/er.7122.
Luo, Y., Zhang, F., Li, C., Cai, J., Biomass-based shape-stable phase change materials supported by garlic peel-derived porous carbon for thermal energy storage. J. Energy Storage, 46, 2022, 103929.
Wang, Z., Zhang, X., Xu, Y., Chen, G., Lin, F., Ding, H., Preparation and thermal properties of shape-stabilized composite phase change materials based on paraffin wax and carbon foam. Polymer (Guildf)., 237, 2021, 124361.
Jacob, J., Pandey, A.K., Rahim, N.A., Selvaraj, J., Paul, J., Samykano, M., Saidur, R., Quantifying thermophysical properties, characterization, and thermal cycle testing of nano-enhanced organic eutectic phase change materials for thermal energy storage applications. Sol. Energy Mater. Sol. Cell., 248, 2022, 112008, 10.1016/j.solmat.2022.112008.
Yang, Z., Deng, Y., Li, J., Preparation of porous carbonized woods impregnated with lauric acid as shape-stable composite phase change materials. Appl. Therm. Eng. 150 (2019), 967–976.
Lv, L., Huang, S., Zhou, C., Ma, W., Biochar activated by potassium carbonate to load organic phase change material: better performance and environmental friendliness. Ind. Crops Prod., 204, 2023, 117184, 10.1016/j.indcrop.2023.117184.
Ma, L., Wang, Q., Li, L., Delignified wood/capric acid-palmitic acid mixture stable-form phase change material for thermal storage. Sol. Energy Mater. Sol. Cell. 194 (2019), 215–221.
Zhao, Y., Sun, B., Du, P., Min, X., Huang, Z., Liu, Y., Wu, X., Fang, M., Hierarchically channel-guided porous wood-derived shape-stabilized thermal regulated materials with enhanced thermal conductivity for thermal energy storage. Mater. Res. Express, 6, 2019, 115515.
Chao, W., Yang, H., Cao, G., Sun, X., Wang, X., Wang, C., Carbonized wood flour matrix with functional phase change material composite for magnetocaloric-assisted photothermal conversion and storage. Energy, 202, 2020, 117636.
Li, Y., Samad, Y.A., Polychronopoulou, K., Alhassan, S.M., Liao, K., From biomass to high performance solar–thermal and electric–thermal energy conversion and storage materials. J. Mater. Chem. A Mater. 2 (2014), 7759–7765.
Liu, H., Qian, Z., Wang, Q., Wu, D., Wang, X., Development of renewable biomass-derived carbonaceous aerogel/mannitol phase-change composites for high thermal-energy-release efficiency and shape stabilization. ACS Appl. Energy Mater. 4 (2021), 1714–1730.
Tony, M.A., From biomass residue to solar thermal energy: the potential of bagasse as a heat storage material. EuroMediterr J Environ Integr, 5, 2020, 17.
Xiao, S., Hu, X., Jiang, L., Ma, Y., Che, Y., Zu, S., Jiang, X., Nano-Ag modified bio-based loofah foam/polyethylene glycol composite phase change materials with higher photo-thermal conversion efficiency and thermal conductivity. J. Energy Storage, 54, 2022, 105238, 10.1016/j.est.2022.105238.
Wei, Y., Li, J., Sun, F., Wu, J., Zhao, L., Leakage-proof phase change composites supported by biomass carbon aerogels from succulents. Green Chem. 20 (2018), 1858–1865.
Pan, X., Zhang, N., Yuan, Y., Shao, X., Zhong, W., Yang, L., Balsa-based porous carbon composite phase change material with photo-thermal conversion performance for thermal energy storage. Sol. Energy 230 (2021), 269–277.
Xu, J., Yang, T., Xu, X., Guo, X., Cao, J., Processing solid wood into a composite phase change material for thermal energy storage by introducing silica-stabilized polyethylene glycol. Compos Part A Appl Sci Manuf, 139, 2020, 106098.
Li, Y., Li, X., Liu, D., Cheng, X., He, X., Wu, Y., Li, X., Huang, Q., Fabrication and properties of polyethylene glycol-modified wood composite for energy storage and conversion. Bioresources 11 (2016), 7790–7802.
Ye, X., Yang, L., Tian, Z., Zhou, P., Wang, S., Sun, H., Zhu, Z., Li, J., Liang, W., Li, A., Polypyrrole-coated conjugated microporous polymers/expanded graphene carbon aerogels based phase change materials composites for efficient energy conversion and storage. Sol. Energy Mater. Sol. Cell., 245, 2022, 111873, 10.1016/j.solmat.2022.111873.
Chen, B., Han, M., Zhang, B., Ouyang, G., Shafei, B., Wang, X., Hu, S., Efficient solar-to-thermal energy conversion and storage with high-thermal-conductivity and form-stabilized phase change composite based on wood-derived scaffolds. Energies, 12, 2019, 1283.
Chen, W., Liang, X., Wang, S., Gao, X., Zhang, Z., Fang, Y., Macro-encapsulated 3D phase change material: Na2S2O3·5H2O-NaOAc·3H2O/carbonized Melamine sponge composite as core and SiC modified polyurethane thin-layer as shell. Compos. Sci. Technol., 214, 2021, 108981, 10.1016/j.compscitech.2021.108981.
Cai, Y., Zhang, N., Cao, X., Yuan, Y., Zhang, Z., Yu, N., Ultra-light and flexible graphene aerogel-based form-stable phase change materials for energy conversion and energy storage. Sol. Energy Mater. Sol. Cell., 252, 2023, 112176, 10.1016/j.solmat.2022.112176.
Zhang, Q., Zhao, Y., Feng, J., Systematic investigation on shape stability of high-efficiency SEBS/paraffin form-stable phase change materials. Sol. Energy Mater. Sol. Cell. 118 (2013), 54–60, 10.1016/j.solmat.2013.07.035.
Wu, T., Hu, Y., Rong, H., Wang, C., SEBS-based composite phase change material with thermal shape memory for thermal management applications. Energy, 221, 2021, 119900, 10.1016/j.energy.2021.119900.
Krzesińska, M., Anisotropy of skeleton structure of highly porous carbonized bamboo and yucca related to the pyrolysis temperature of the precursors. J. Anal. Appl. Pyrolysis 123 (2017), 73–82.
Sheng, N., Zhu, R., Dong, K., Nomura, T., Zhu, C., Aoki, Y., Habazaki, H., Akiyama, T., Vertically aligned carbon fibers as supporting scaffolds for phase change composites with anisotropic thermal conductivity and good shape stability. J. Mater. Chem. A Mater. 7 (2019), 4934–4940.
Zhou, M., Wang, J., Zhao, Y., Wang, G., Gu, W., Ji, G., Hierarchically porous wood-derived carbon scaffold embedded phase change materials for integrated thermal energy management, electromagnetic interference shielding and multifunctional application. Carbon N Y 183 (2021), 515–524.
Wu, T., Hu, Y., Rong, H., Wang, C., SEBS-based composite phase change material with thermal shape memory for thermal management applications. Energy, 221, 2021, 119900.
Maleki, M., Ahmadi, P.T., Mohammadi, H., Karimian, H., Ahmadi, R., Emrooz, H.B.M., Photo-thermal conversion structure by infiltration of paraffin in three dimensionally interconnected porous polystyrene-carbon nanotubes (PS-CNT) polyHIPE foam. Sol. Energy Mater. Sol. Cell. 191 (2019), 266–274.
Umair, M.M., Zhang, Y., Tehrim, A., Zhang, S., Tang, B., Form-stable phase-change composites supported by a biomass-derived carbon scaffold with multiple energy conversion abilities. Ind. Eng. Chem. Res. 59 (2020), 1393–1401, 10.1021/acs.iecr.9b06288.
Chen, P., Gao, X., Wang, Y., Xu, T., Fang, Y., Zhang, Z., Metal foam embedded in SEBS/paraffin/HDPE form-stable PCMs for thermal energy storage. Sol. Energy Mater. Sol. Cell. 149 (2016), 60–65, 10.1016/j.solmat.2015.12.041.
V Belessiotis, G., Papadokostaki, K.G., Favvas, E.P., Efthimiadou, E.K., Karellas, S., Preparation and investigation of distinct and shape stable paraffin/SiO2 composite PCM nanospheres. Energy Convers. Manag. 168 (2018), 382–394, 10.1016/j.enconman.2018.04.059.
Rathore, P.K.S., kumar Shukla, S., Improvement in thermal properties of PCM/Expanded vermiculite/expanded graphite shape stabilized composite PCM for building energy applications. Renew. Energy 176 (2021), 295–304, 10.1016/j.renene.2021.05.068.
Zhang, Q., Zhao, Y., Feng, J., Systematic investigation on shape stability of high-efficiency SEBS/paraffin form-stable phase change materials. Sol. Energy Mater. Sol. Cell. 118 (2013), 54–60, 10.1016/j.solmat.2013.07.035.
Raveendran, K., Ganesh, A., Khilar, K.C., Pyrolysis characteristics of biomass and biomass components. Fuel 75 (1996), 987–998, 10.1016/0016-2361(96)00030-0.
Rao, T.R., Sharma, A., Pyrolysis rates of biomass materials. Energy 23 (1998), 973–978, 10.1016/S0360-5442(98)00037-1.
