cooling rate; dendritic growth; olivine; phosphorus zoning; Sept Iles layered intrusion; Cooling rates; Dendritic growth; Dendritics; Earth's crust; Layered intrusions; Magma chamber; Model-based OPC; Phosphorus zoning; Sept ile layered intrusion; Undercoolings; Geophysics; Geochemistry and Petrology; Earth and Planetary Sciences (miscellaneous); Space and Planetary Science
Abstract :
[en] Layered intrusions are fossilized mafic magma chambers in the Earth's crust. The pathways that led to crystallization and solidification of layered intrusions have been hotly debated as the growth model of primocrysts (the earliest-formed crystals) in mafic magma chambers remains enigmatic. In this study, we carried out high-resolution elemental mapping of mm-scale olivine primocrysts from the Sept Iles layered intrusion (Canada), the third largest one in the world, with a focus on phosphorus (P) zoning of olivine. Our results reveal that complex P zoning of olivine with intense dissolution textures is ubiquitous in the ∼4.7 km-thick Layered Series of the intrusion. The P-rich zones of olivine are featured with dendritic, hopper and sector-zoned patterns, which are attributed to significant magma undercooling. Thermal modeling based on a 1-D conductive cooling model suggests that initially hot parental magma intruding into cold country rocks would result in high degrees of undercooling (-ΔT >60 °C) in the margins (i.e., floor, roof and sidewalls) of magma chamber, facilitating rapid growth of dendritic olivine, which may be then spread within the magma chamber by dynamic convection and crucial to construct initial crystal framework of a solidifying magma chamber. Additionally, diffusion modeling based on the P gradients in olivine suggests a minimum cooling rate of 2.7 to 3.3×10−3 °C/year in the center of the intrusion, similar to the averaged cooling rate of other layered intrusions (e.g., Bushveld, Stillwater and Skaergaard) reported in previous studies. This indicates that rapid cooling (ca. 10−2 to 10−3 °C/year) at high temperature (>800 °C) may be predominant regardless of the size of magma chambers. Our study demonstrates that P zoning of olivine is powerful in decoding crystallization and thermal histories of mafic-ultramafic intrusions.
Disciplines :
Earth sciences & physical geography
Author, co-author :
Xing, Chang-Ming; Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, China ; CAS Center for Excellence in Deep Earth Science, Guangzhou, China ; Guangdong Provincial Key Laboratory of Mineral Physics and Materials, Guangzhou, China
Wang, Christina Yan; Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, China ; CAS Center for Excellence in Deep Earth Science, Guangzhou, China ; Guangdong Provincial Key Laboratory of Mineral Physics and Materials, Guangzhou, China
Charlier, Bernard ; Université de Liège - ULiège > Département de géologie > Pétrologie, géochimie endogènes et pétrophysique
Namur, Olivier ; Department of Earth and Environmental Sciences, KU Leuven, Heverlee, Belgium
Language :
English
Title :
Ubiquitous dendritic olivine constructs initial crystal framework of mafic magma chamber
This study was financially supported by the National Key R&D Program of China (2018YFA0702600), NSFC grants (42072068, 41921003 and 41325006), the Youth Innovation Promotion Association CAS (2018388), and Science and Technology Planning of Guangdong Province, China (2020B1212060055). BC is a Research Associate of the Belgian Fund for Scientific Research-FNRS. Many thanks to Jibamitra Ganguly, who kindly guided the calculation of closure temperature. William Nelson was thanked for his suggestion for the diffusivity of P in olivine. Valentina Batanova kindly shared the MongOL Sh11-2 olivine standard. Wei Tan and Jiang-Ze Wang were thanked for providing assistance during EBSD analysis and measurement of modal proportion of minerals. Eiichi Takahashi was thanked for helping FTIR analysis. We are grateful to Christian Tegner and one anonymous reviewer, and editor, Chiara Maria Petrone, who kindly provided constructive comments that were helpful to improve the manuscript.This study was financially supported by the National Key R&D Program of China ( 2018YFA0702600 ), NSFC grants ( 42072068 , 41921003 and 41325006 ), the Youth Innovation Promotion Association CAS ( 2018388 ), and Science and Technology Planning of Guangdong Province , China ( 2020B1212060055 ). BC is a Research Associate of the Belgian Fund for Scientific Research-FNRS. Many thanks to Jibamitra Ganguly, who kindly guided the calculation of closure temperature. William Nelson was thanked for his suggestion for the diffusivity of P in olivine. Valentina Batanova kindly shared the MongOL Sh11-2 olivine standard. Wei Tan and Jiang-Ze Wang were thanked for providing assistance during EBSD analysis and measurement of modal proportion of minerals. Eiichi Takahashi was thanked for helping FTIR analysis. We are grateful to Christian Tegner and one anonymous reviewer, and editor, Chiara Maria Petrone, who kindly provided constructive comments that were helpful to improve the manuscript.
Agrell, S.O., Charnley, N.R., Chinner, G.A., Phosphoran olivine from Pine Canyon, Piute Co., Utah. Mineral. Mag., 62, 1998.
Bachmann, F., Hielscher, R., Schaeben, H., Texture analysis with MTEX – free and open source software toolbox. Solid State Phenom. 160 (2010), 63–68.
Bai, Y., Su, B.-X., Xiao, Y., Chen, C., Cui, M.-M., He, X.-Q., Qin, L.-P., Charlier, B., Diffusion-driven chromium isotope fractionation in ultramafic cumulate minerals: elemental and isotopic evidence from the Stillwater Complex. Geochim. Cosmochim. Acta 263 (2019), 167–181.
Batanova, V.G., Thompson, J.M., Danyushevsky, L.V., Portnyagin, M.V., Garbe-Schönberg, D., Hauri, E., Kimura, J.-I., Chang, Q., Senda, R., Goemann, K., Chauvel, C., Campillo, S., Ionov, D.A., Sobolev, A.V., New olivine reference material for in situ microanalysis. Geostand. Geoanal. Res. 43 (2019), 453–473.
Boesenberg, J.S., Hewins, R.H., An experimental investigation into the metastable formation of phosphoran olivine and pyroxene. Geochim. Cosmochim. Acta 74 (2010), 1923–1941.
Bradshaw, R.W., Kent, A.J.R., Tepley, F.J. III, Chemical fingerprints and residence times of olivine in the 1959 Kilauea Iki eruption, Hawaii: insights into picrite formation. Am. Mineral. 103 (2018), 1812–1826.
Brandeis, G., Jaupart, C., On the interaction between convection and crystallization in cooling magma chambers. Earth Planet. Sci. Lett. 77 (1986), 345–361.
Cashman, K.V., Sparks, R.S.J., Blundy, J.D., Vertically extensive and unstable magmatic systems: a unified view of igneous processes. Science, 355, 2017, eaag3055.
Cawthorn, R.G., Webb, S.J., Cooling of the Bushveld Complex, South Africa: implications for paleomagnetic reversals. Geology 41 (2013), 687–690.
Charlier, B., Namur, O., Toplis, M.J., Schiano, P., Cluzel, N., Higgins, M.D., Auwera, J.V., Large-scale silicate liquid immiscibility during differentiation of tholeiitic basalt to granite and the origin of the Daly gap. Geology 39 (2011), 907–910.
Costa, F., Chakraborty, S., The effect of water on Si and O diffusion rates in olivine and implications for transport properties and processes in the upper mantle. Phys. Earth Planet. Inter. 166 (2008), 11–29.
Crank, J., The Mathematics of Diffusion. 2ed ed., 1975, Oxford Science Publications, Oxford.
de Maisonneuve, C.B., Costa, F., Huber, C., Vonlanthen, P., Bachmann, O., Dungan, M.A., How do olivines record magmatic events? Insights from major and trace element zoning. Contrib. Mineral. Petrol., 171, 2016, 56.
Di Maio, R., Piegari, E., Mancini, C., Scandone, R., Numerical study of conductive heat losses from a magmatic source at Phlegraean Fields. J. Volcanol. Geotherm. Res. 290 (2015), 75–81.
Dohmen, R., Chakraborty, S., Becker, H.-W., Si and O diffusion in olivine and implications for characterizing plastic flow in the mantle. Geophys. Res. Lett. 29 (2002), 26–21–26-24.
Donaldson, C.H., An experimental investigation of olivine morphology. Contrib. Mineral. Petrol. 57 (1976), 187–213.
Faak, K., Gillis, K.M., Slow cooling of the lowermost oceanic crust at the fast-spreading East Pacific Rise. Geology 44 (2016), 115–118.
Faure, F., Schiano, P., Experimental investigation of equilibration conditions during forsterite growth and melt inclusion formation. Earth Planet. Sci. Lett. 236 (2005), 882–898.
Faure, F., Trolliard, G., Nicollet, C., Montel, J.-M., A developmental model of olivine morphology as a function of the cooling rate and the degree of undercooling. Contrib. Mineral. Petrol. 145 (2003), 251–263.
Ganguly, J., Tirone, M., Diffusion closure temperature and age of a mineral with arbitrary extent of diffusion: theoretical formulation and applications. Earth Planet. Sci. Lett. 170 (1999), 131–140.
Girona, T., Costa, F., DIPRA: a user-friendly program to model multi-element diffusion in olivine with applications to timescales of magmatic processes. Geochem. Geophys. Geosyst. 14 (2013), 422–431.
Higgins, M.D., A new interpretation of the structure of the Sept Iles Intrusive suite, Canada. Lithos 83 (2005), 199–213.
Higgins, M.D., van Breemen, O., The age of the Sept Iles layered mafic intrusion, Canada: implications for the late Neoproterozoic/Cambrian history of Southeastern Canada. J. Geol. 106 (1998), 421–432.
Holness, M.B., Tegner, C., Nielsen, T.F., Stripp, G., Morse, S.A., A textural record of solidification and cooling in the Skaergaard intrusion, East Greenland. J. Petrol. 48 (2007), 2359–2377.
Irvine, T.N., Andersen, J.C.Ø., Brooks, C.K., Included blocks (and blocks within blocks) in the Skaergaard intrusion: geologic relations and the origins of rhythmic modally graded layers. GSA Bull. 110 (1998), 1398–1447.
Jambon, A., Lussiez, P., Clocchiatti, R., Weisz, J., Hernandez, J., Olivine growth rates in a tholeiitic basalt: an experimental study of melt inclusions in plagioclase. Chem. Geol. 96 (1992), 277–287.
Keevil, H.A., Namur, O., Holness, M.B., Microstructures and late-stage magmatic processes in layered mafic intrusions: symplectites from the Sept Iles intrusion, Quebec, Canada. J. Petrol., 61, 2020, egaa071.
Latypov, R., Chistyakova, S., Barnes, S.J., Godel, B., Delaney, G.W., Cleary, P.W., Radermacher, V.J., Campbell, I., Jakata, K., Chromitite layers indicate the existence of large, long-lived, and entirely molten magma chambers. Sci. Rep., 12, 2022, 4092.
Latypov, R.M., Chistyakova, S.Y., Namur, O., Barnes, S., Dynamics of evolving magma chambers: textural and chemical evolution of cumulates at the arrival of new liquidus phases. Earth-Sci. Rev., 210, 2020, 103388.
Loncarevic, B.D., Feininger, T., Lefebvre, D., The Sept-îles layered mafic intrusion: geophysical expression. Can. J. Earth Sci. 27 (1990), 501–512.
Mao, Y.-J., Schoneveld, L., Barnes, S.J., Williams, M.J., Su, B.-X., Ruprecht, P., Evans, N.J., Qin, K.-Z., Coupled Li-P zoning and trace elements of olivine from magmatic Ni-Cu deposits: implications for postcumulus re-equilibration in olivine. J. Petrol., 63, 2022, egac018.
McBirney, A.R., The Skaergaard intrusion. Cawthorn, R.G., (eds.) Developments in Petrology, 1996, Elsevier, 147–180.
Milman-Barris, M.S., Beckett, J.R., Baker, M.B., Hofmann, A.E., Morgan, Z., Crowley, M.R., Vielzeuf, D., Stolper, E., Zoning of phosphorus in igneous olivine. Contrib. Mineral. Petrol. 155 (2008), 739–765.
Morse, S.A., Thermal structure of crystallizing magma with two-phase convection. Geol. Mag. 123 (1986), 205–214.
Mourey, A.J., Shea, T., Forming olivine phenocrysts in basalt: a 3D characterization of growth rates in laboratory experiments. Front. Earth Sci., 7, 2019.
Namur, O., Charlier, B., Holness, M.B., Dual origin of Fe-Ti-P gabbros by immiscibility and fractional crystallization of evolved tholeiitic basalts in the Sept Iles layered intrusion. Lithos 154 (2012), 100–114.
Namur, O., Charlier, B., Pirard, C., Hermann, J., Liégeois, J.-P., Auwera, J.V., Anorthosite formation by plagioclase flotation in ferrobasalt and implications for the lunar crust. Geochim. Cosmochim. Acta 75 (2011), 4998–5018.
Namur, O., Charlier, B., Toplis, M.J., Higgins, M.D., Liégeois, J.-P., Vander Auwera, J., Crystallization sequence and magma chamber processes in the ferrobasaltic Sept Iles layered intrusion, Canada. J. Petrol. 51 (2010), 1203–1236.
Namur, O., Humphreys, M.C.S., Holness, M.B., Crystallization of interstitial liquid and latent heat buffering in solidifying gabbros: Skaergaard intrusion, Greenland. J. Petrol. 55 (2014), 1389–1427.
Nelson, W.S., Hammer, J.E., Shea, T., Hellebrand, E., Jeffrey Taylor, G., Chemical heterogeneities reveal early rapid cooling of Apollo Troctolite 76535. Nat. Commun., 12, 2021, 7054.
Nelson, W., Hammer, J., Shea, T., Chakraborty, S., Diffusivity of phosphorous in olivine revisited: a joint experimental and modeling approach. Goldschmidt Conference Abstracts, 2020.
Norton, D., Taylor, H.P. Jr., Quantitative simulation of the hydrothermal systems of crystallizing magmas on the basis of transport theory and oxygen isotope data: an analysis of the Skaergaard intrusion. J. Petrol. 20 (1979), 421–486.
Oldenburg, C.M., Spera, F.J., Yuen, D.A., Sewell, G., Dynamic mixing in magma bodies: theory, simulations, and implications. J. Geophys. Res., Solid Earth 94 (1989), 9215–9236.
Shea, T., Costa, F., Krimer, D., Hammer, J.E., Accuracy of timescales retrieved from diffusion modeling in olivine: a 3D perspective. Am. Mineral. 100 (2015), 2026–2042.
Shea, T., Hammer, J.E., Kinetics of cooling- and decompression-induced crystallization in hydrous mafic-intermediate magmas. J. Volcanol. Geotherm. Res. 260 (2013), 127–145.
Shea, T., Hammer, J.E., Hellebrand, E., Mourey, A.J., Costa, F., First, E.C., Lynn, K.J., Melnik, O., Phosphorus and aluminum zoning in olivine: contrasting behavior of two nominally incompatible trace elements. Contrib. Mineral. Petrol., 174, 2019, 85.
Sparks, R.S.J., Cashman, K.V., Dynamic magma systems: implications for forecasting volcanic activity. Elements 13 (2017), 35–40.
Streck, M.J., Mineral textures and zoning as evidence for open system processes. Rev. Mineral. Geochem. 69 (2008), 595–622.
Sun, C., Liang, Y., A REE-in-plagioclase–clinopyroxene thermometer for crustal rocks. Contrib. Mineral. Petrol., 172, 2017, 24.
Tang, M., Rudnick, R.L., McDonough, W.F., Bose, M., Goreva, Y., Multi-mode Li diffusion in natural zircons: evidence for diffusion in the presence of step-function concentration boundaries. Earth Planet. Sci. Lett. 474 (2017), 110–119.
Tegner, C., Wilson, J.R., Textures in a poikilitic olivine gabbro cumulate: evidence for supercooling. Mineral. Petrol. 54 (1995), 161–173.
Tegner, C., Wilson, J.R., Brooks, C.K., Intraplutonic quench zones in the Kap Edvard Holm layered gabbro complex, East Greenland. J. Petrol. 34 (1993), 681–710.
Thy, P., Lesher, C.E., Tegner, C., The Skaergaard liquid line of descent revisited. Contrib. Mineral. Petrol. 157 (2009), 735–747.
Thy, P., Lesher, C.E., Tegner, C., Further work on experimental plagioclase equilibria and the Skaergaard liquidus temperature. Am. Mineral. 98 (2013), 1360–1367.
Wager, L., Brown, G., Layered Igneous Rocks. 1968, Oliver and Boyd, Edinburgh.
Watson, E.B., Cherniak, D., Holycross, M., Diffusion of phosphorus in olivine and molten basalt. Am. Mineral. 100 (2015), 2053–2065.
Welsch, B., Faure, F., Famin, V., Baronnet, A., Bachèlery, P., Dendritic crystallization: a single process for all the textures of olivine in basalts?. J. Petrol. 54 (2013), 539–574.
Welsch, B., Hammer, J., Hellebrand, E., Phosphorus zoning reveals dendritic architecture of olivine. Geology 42 (2014), 867–870.
Whittington, A.G., Sehlke, A., Spontaneous reheating of crystallizing lava. Geology 49 (2021), 1457–1461.
Wotzlaw, J.-F., Bindeman, I.N., Schaltegger, U., Brooks, C.K., Naslund, H.R., High-resolution insights into episodes of crystallization, hydrothermal alteration and remelting in the Skaergaard intrusive complex. Earth Planet. Sci. Lett. 355–356 (2012), 199–212.
Xing, C.-M., Wang, C.Y., Tan, W., Disequilibrium growth of olivine in mafic magmas revealed by phosphorus zoning patterns of olivine from mafic–ultramafic intrusions. Earth Planet. Sci. Lett. 479 (2017), 108–119.
Yao, Z., Mungall, J.E., Jenkins, M.C., The Rustenburg Layered Suite formed as a stack of mush with transient magma chambers. Nat. Commun., 12, 2021, 505.
Selkin, P.A., Gee, J.S., Meurer, W.P., Hemming, S.R., Paleointensity record from the 2.7 Ga Stillwater Complex, Montana. Geochem. Geophys. Geosyst., 9, 2008, Q12023.
Setera, J.B., VanTongeren, J.A., Turrin, B.D., Swisher, C.C. III, Rapid cooling of the Rustenburg Layered Suite of the Bushveld Complex (South Africa): insights from biotite 40Ar/39Ar geochronology. Geology 48 (2020), 834–838.
Wall, C.J., Scoates, J.S., Weis, D., Friedman, R.M., Amini, M., Meurer, W.P., The Stillwater Complex: integrating zircon geochronological and geochemical constraints on the age, emplacement history and crystallization of a large, open-system layered intrusion. J. Petrol. 59 (2018), 153–190.
Zeh, A., Ovtcharova, M., Wilson, A.H., Schaltegger, U., The Bushveld Complex was emplaced and cooled in less than one million years – results of zirconology, and geotectonic implications. Earth Planet. Sci. Lett. 418 (2015), 103–114.