hydrogen cyanide; biomass burning; remote sensing; atmospheric model simulations
Abstract :
[en] We use the GEOS-Chem global 3-D chemistry transport model to investigate the relative importance of chemical and physical processes that determine observed variability of hydrogen cyanide (HCN) in the troposphere and lower stratosphere. Consequently, we reconcile ground-based FTIR column measurements of HCN, which show annual and semi-annual variations, with recent space-borne measurements of HCN mixing ratio in the tropical lower stratosphere, which show a large two-year variation. We find that the observed column variability over the ground-based stations is determined by a superposition of HCN from several regional burning sources, with GEOS-Chem reproducing these column data with a positive bias of 5%. GEOS-Chem reproduces the observed HCN mixing ratio from the Microwave Limb Sounder and the Atmospheric Chemistry Experiment satellite instruments with a mean negative bias of 20%, and the observed HCN variability with a mean negative bias of 7%. We show that tropical biomass burning emissions explain most of the observed HCN variations in the upper troposphere and lower stratosphere (UTLS), with the remainder due to atmospheric transport and HCN chemistry. In the mid and upper stratosphere, atmospheric dynamics progressively exerts more influence on HCN variations. The extent of temporal overlap between African and other continental burning seasons is key in establishing the apparent bienniel cycle in the UTLS. Similar analysis of other, shorter-lived trace gases have not observed the transition between annual and bienniel cycles in the UTLS probably because the signal of inter-annual variations from surface emission has been diluted before arriving at the lower stratosphere (LS), due to shorter atmospheric lifetimes.
Disciplines :
Earth sciences & physical geography
Author, co-author :
Li, Q.
Palmer, P. I.
Pumphrey, H. C.
Bernath, P.
Mahieu, Emmanuel ; Université de Liège - ULiège > Département d'astrophys., géophysique et océanographie (AGO) > Groupe infra-rouge de phys. atmosph. et solaire (GIRPAS)
Language :
English
Title :
What drives the observed variability of HCN in the troposphere and lower stratosphere?
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Bibliography
Baldwin, M. P., Gray, L. J., and Dunkerton, T. J.: The quasi-biennial oscillation, Rev. Geophys., 39, 179-229, 2001.
Bange, H. W. and Williams, J.: Acetonitrile in atmospheric and biogeochemical cycles, Atmos. Environ., 34, 4959-4990, 2000.
Bernath, P. F., McElroy, C. T., Abrams, M. C., et al.: Atmospheric Chemistry Experiment (ACE): Mission overview, Geophys. Res. Lett., 32, L15S01, doi:10.1029/2005GL022386, 2005. (Pubitemid 41398766)
Bertschi, I., Yokelson, R. J., Ward, D. E., Babbitt, R. E., Su-sott, R. A., Goode, J. G., and Hao, W. M.: Trace gas and particle emissions from fires in large diameter and be-lowground biomass fuels, J. Geophys. Res., 108(D13), 8472, doi:10.1029/2002JD002100, 2003.
Bey, I., Jacob, D. J., Yantosca, R. M., Logan, J. A., Field, B. D., Fiore, A. M., Li, Q., Liu, H. Y., Mickley, L. J., and Schultz, M. G.: Global modeling of tropospheric chemistry with assim-ilated meteorology: Model description and evaluation, J. Geo-phys. Res. 106(D19) 23073-23095 2001.
Boone, C. D., Nassar, R., Walker, K. A., Rochon, Y., McLeod, S. D., Rinsland, C. P., and Bernath, P. F.: Retrievals for the atmospheric chemistry experiment Fourier-transform spectrometer, Appl. Optics, 44, 7218-7231, 2005.
Brasseur, G., Zellner, De Rudder, R. A., and Arjis, E.: Is hydrogen cyanide a progenitor of acetonitrile in the atmosphere?, Geophys. Res. Lett., 12, 117-120, 1985.
Cicerone, R. J. and Zellner, R.: The Atmospheric Chemistry of Hydrogen Cyanide (HCN), J. Geophys. Res., 88(C15), 10689-10696, 1983.
Duncan, B. N., Strahan, S. E., Yoshida, Y., Steenrod, S. D., and Livesey, N.: Model study of the cross-tropopause transport of biomass burning pollution, Atmos. Chem. Phys., 7, 3713-3736, 2007, http://www.atmos-chem-phys.net/7/3713/ 2007/. (Pubitemid 47117785)
Fiore, A., Jacob, D. J., Liu, H., Yantosca, R. M., Fairlie, T. D., and Li, Q. B.: Variability in surface ozone background over the United States: Implications for air quality policy, J. Geophys. Res., 108(4787), doi:10.1029/2003JD003855, 2003.
Holton, J. R., Haynes, P. H., McIntyre, M. E., Douglass, A. R., Rood, R. B., and Pfister, L.: Stratosphere-Troposphere Exchange, Rev. Geophys., 33(4), 403-439, 1995.
Holzinger, R., Warneke, C., Hansel, A., Jordan, A., and Lindinger, W.: Biomass burning as a source of formaldehyde, acetaldehyde, methanol, acetone, acetonitrile, and hydrogen cyanide, Geophys. Res. Lett., 26(8), 1161-1164, 1999.
Holzinger, R., Jordan, A., Hansel, A., and Lindinger, W.: Automobile emissions of acetonitrile: Assessments of its contribution to the global sources, Atmos. Environ., 38, 187-193, 2001.
Jacob, D. J., Crawford, J., Kleb, M. M., Connors, V. S., Bendura, R. J., Raper, J. L., Sachse, G. W., Gille, J., Emmons, L., and Heald, J. C.: Transport and Chemical Evolution over the Pacific (TRACE-P) mission: Design, execution, and first results, J. Geo-phys., Res., 108(D20), 9000, doi:10.1029/2002JD003276, 2003. (Pubitemid 350187705)
Kleinboehl, A., Toon, G. C., Sen, B., et al.: On the stratospheric chemistry of hydrogen cyanide, Geophys. Res. Lett., 33, L11806, doi:10.1029/2006GL026015, 2006. (Pubitemid 44123141)
Li, Q., Jacob, D. J., Bey, I., Yantosca, R. M., Zhao, Y., Kondo, Y., and Notholt, J.: Atmospheric hydrogen cyanide (HCN): Biomass burning source, ocean sink?, Geophys. Res. Lett., 27(3), 357-360, 2000.
Li, Q., Jacob, D. J., Yantosca, R. M., Heald. C. L., Singh, H. B., Koike, M., Zhao, Y., Sachse, G. W., and Streets, D. G.: A global three-dimensional model analysis of the atmospheric budgets of HCN and CH3CN: Constraints from aircraft and ground measurements, J. Geophys. Res., 108(D21), 8827, doi:10.1029/2002JD003975, 2003.
Liu, C. and Zipser, E. J.: Global distribution of convection penetrating the tropical tropopause, J. Geophys. Res., 110, D23104, doi:10.1029/ 2005JD006063, 2005. (Pubitemid 43141246)
Lobert, J. M., Scharffe, D. H., Hao, W. M., and Crutzen, P. J.: Importance of biomass burning in the atmospheric budgets of nitrogen-containing gases, Nature, 346, 552-554, 1990.
Logan, J. A., Jones, D. B. A., Megretskaia, I. A., et al.: Quasibiennial oscillation in tropical ozone as revealed by ozonesonde and satellite data, J. Geophy. Res., 108(D8), 4244, doi:1029/2002JD002170, 2003.
Lupu, A., Kaminski, J. W., Neary, L., McConnell, J. C., Toyota, K., Rinsland, C. P., Bernath, P. F., Walker, K. A., Boone, C. D., Nagahama, Y., and Suzuki, K.: Hydrogen cyanide in the upper troposphere: GEM-AQ simulation and comparison with ACE-FTS observations, Atmos. Chem. Phys., 9, 4301-4313, 2009, http://www.atmos-chem-phys.net/9/4301/2009/.
Mahieu, E., Rinsland, C. P., Zander, R., Demoulin, P., Delbouille, L., and Roland, G.: Vertical Column Abundances of HCN Deduced from Ground-Based Infrared Solar Spectra: Long-Term Trend and Variability, J. Atmos. Chem., 20, 299-310, 1995.
Mahieu, E., Zander, R., Delbouille, L., Demoulin, P., Roland, G., and Servais, C.: Observed trends in total vertical column abundances of atmospheric gases from IR solar spectra recorded at the Jungfraujoch, J. Atmos. Chem., 28, 227-243, 1997.
Martin, R. V., Jacob, D. J., Logan, J. A., et al.: Interpretation of TOMS observations of tropical tropospheric ozone with a global model and in situ observations, J. Geosphys. Res., 107(D18), 4351, doi:10.1029/2001JD001480, 2002.
Mote, P. W., Rosenlof, K. H., McIntyre, M. E., et al.: An atmospheric tape recorder: The imprint of tropical tropopause temperatures on stratospheric water vapor, J. Geophys. Res, 101(D2), 3989-4006, 1996.
Park, R. J., Jacob, D. J., Field, B. D., Yantosca, R. M., and Chin, M.: Natural and transboundary pollution influences on sulface-nitrate-ammonium aerosols in the United States: Implications for policy, J. Geophys. Res., 109, D15204, doi:10.1029/2003JD004473, 2005.
Pickett, H. M., Read, W. G., Lee, K. K., and Yung, Y. L.: Observation of night OH in the mesosphere, Geophys. Res. Lett., 33, L19808, doi:10.1029/2006GL026910, 2006. (Pubitemid 46535095)
Pickett, H. M., Drouin, B. J., Canty, T., et al.: Validation of Aura Microwave Limb Sounder OH and HO2 measurements, J. Geo-phys. Res., 113, D16S30, doi:10.1029/2007JD008775, 2008.
Plumb, R. A. and Bell, R. C.: A model of the quasi-biennial oscillation on an equatorial beta-plane, Q. J. Roy. Meteorol. Soc., 108, 335-352, 1982.
Pumphrey, H. C., Jimenez, C. J., and Waters, J. W.: Measurement of HCN in the middle atmosphere by EOS MLS, Geophys. Res. Lett., 33(8), L08804, doi:10.1029/2005GL025656, 2006. (Pubitemid 43950165)
Pumphrey, H. C., Boone, C., Walker, K. A., Bernath, P., and Liv-ersey, N. J.: Tropical tape recorder observed in HCN, Geophys. Res. Lett., 35, L05801, doi:10.1029/2007/GL032137, 2008.
Randel, W. and Wu, F.: Isolation of the ozone QBO in SAGE II data by singular-value decomposition, J. Atmos. Sci., 53, 2546-2559, 1996.
Randel, W. J., Wu, F., Russell III, J. M., Roche, A., and Waters, J. W.: Seasonal Cycle and QBO Variations in Stratospheric CH4 and H2O Observed in UARS HALOE Data, J. Atmos. Sci., 55, 163-185, 1998.
Randel, W. J. and Wu, F.: A stratospheric ozone profile data set for 1979-2005: Variability, trends, and comparison with column ozone data, J. Geosphy. Res., 112, D06313, doi:10.1029/2006JD007339, 2007. (Pubitemid 46824918)
Rinsland, C. P., Goldman, A., Murcray, F. J., et al.: Infrared solar spectroscopic measurements of free tropospheric CO, C2H6, and HCN above Mauna Loa, Hawaii: Seasonal variations and evidence for enhanced emissions from the Southeast Asian tropical fires 1997-1998, J. Geophys. Res., 104(D15), 18667-18680, 1999.
Rinsland, C. P., Mahieu, E., Zander, R., Demoulin, P., Forrer, J., and Buchmann, B.: Free tropospheric CO, C2H6, and HCN above central Europe: Recent measurements from the Jungfraujoch station including the detection of elevated columns during 1998, J. Geophys. Res., 105(D19), 24235-24249, 2000.
Rinsland, C. R., Goldman, A., Zander, R., and Mahieu, E.: Enhanced tropospheric HCN columns above Kitt Peak during the 1982-1983 and 1997-1998 El Nino warm phases, J. Quant. Spectrosc. Ra., 69, 3-8, 2001.
Rinsland, C. P., Goldman, A., Hannigan, J. W., Wood, S. W., Chiou, L. S., and Mahieu, E.: Long-term trends of tropospheric carbon monoxide and hydrogen cyanide from analysis of high resolution infrared solar spectra, J. Quant. Spectrosc. Ra., 104, 40-51, 2007.
Schneider, J., Burger, V., and Arnold, F.: Methyl cyanide and hydrogen cyanide measurements in the lower stratosphere: Implications for methyl cyanide sources and sinks, J. Geophys. Res., 102(D21), 25501-25506, 1997.
Schoeberl, M. R., Roche, A. E., Russell III, J. M., Ortland, D., Hays, P. B., and Waters, J. W.: An estimation of the dynamical isolation of the tropical lower stratosphere using trace gas observations of the quasi-biennial oscillation, Geophys. Res. Lett., 24, 53-56, 1997.
Schoeberl, M. R., Duncan, B. N., Douglass, A. R., Waters, J., Liversey, N., Read, W., and Filipiak, M.: The carbon monoxide tape recorder, Geophys. Res. Lett., 33, L12811, doi:10.1029/2006GL026178, 2006. (Pubitemid 44687737)
Schoeberl, M. R., Douglass, A. R., Newman, P. A., et al.: QBO and annual cycle variations in tropical lower stratosphere trace gases from HALOE and Aura MLS observations, J. Geophys. Res., 113, D05301, doi:10.1029/2007JD008678, 2008.
Singh, H. B., Salas, L., Herlth, D., et al.: In situ measurements of HCN and CH3CN over the Pacific Ocean: Sources, sinks and budgets, J. Geophys. Res., 108, 8795, doi:10.1029/2002JD003006, 2003. (Pubitemid 350187717)
Streets, D. G., Bond, T. C., Carmichael, G. R., et al.: An inventory of gaseous and primary aerosol emissions in Asia in the year 2000, J. Geophys. Res., 108(D21), 8809, doi:10.1029/2002JD003093, 2003.
van der Werf, G. R., Randerson, J. T., Giglio, L., Collatz, G. J., Kasibhatla, P. S., and Arellano Jr., A. F.: Interannual variability in global biomass burning emissions from 1997 to 2004, Atmos. Chem. Phys., 6, 3423-3441, 2006, http://www.atmos-chem-phys.net/6/3423/2006/.
Wand, M. P. and Jones, M. C.: Kernel Smoothing, Chapman and Hall, London, UK, 1995.
Waters, J. W.: The Earth Observing System Microwave Limb Sounder (EOS MLS) on the Aura satellite, IEEE T. Geosci. Remote, 44(5), 1106-1121, 2006.
Zhao, Y., Kondo, Y., Murcray, F. J., et al.: Seasonal variations of HCN over northern Japan measured by ground-based infrared solar spectroscopy, J. Geophys. Res., 27, 2085-2088, 2000.
Zhao, Y., Strong, K., Kondo, Y., et al.: Spectroscopic measurements of tropospheric CO, C2H6, C2H2, and HCN in northern Japan, J. Geophys. Res., 107(D8), 4343, doi:10.1029/2001JD000748, 2002.
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