Biomass; Chalcone; Dimethylmalonate; Ionic liquids; Michael reaction; Microwaves; Catalysis; Physical and Theoretical Chemistry
Abstract :
[en] We developed a synthesis of chiral ionic liquids from proline and one of its derivatives. Nine chiral ionic liquids were synthesized with yields from 78% to 95%. These synthesized ionic liquids played two roles in Michael reactions, as solvents, and as basic catalysts, where the ionic phase could also be reused at least five times without loss of activity. The yields up to 99% were improved by increasing the amount of dimethylmalonate from 1.2 equivalents to 3 or 4 equivalents. Furthermore, the reaction time could be reduced from 24 h to 45 min through microwaves activation.
Disciplines :
Chemistry
Author, co-author :
Bacha, Katia ; Université de Liège - ULiège > TERRA Research Centre ; Institut de Chimie Moléculaire de Reims, UMR CNRS 7312, Université de Reims Champagne-Ardenne, Reims, France
Aguibi, Kawther; Institut de Chimie Moléculaire de Reims, UMR CNRS 7312, Université de Reims Champagne-Ardenne, Reims, France
Mbakidi, Jean-Pierre; Institut de Chimie Moléculaire de Reims, UMR CNRS 7312, Université de Reims Champagne-Ardenne, Reims, France
Bouquillon, Sandrine; Institut de Chimie Moléculaire de Reims, UMR CNRS 7312, Université de Reims Champagne-Ardenne, Reims, France
Language :
English
Title :
Beneficial contribution of biosourced ionic liquids and microwaves in the Michael reaction
Funding: This research was funded by Région Champagne Ardenne Excellence Framework [Amisolver program]. The APC was funded by the ICMR.This research was funded by R?gion Champagne Ardenne Excellence Framework [Amisolver program]. The APC was funded by the ICMR. This work was supported by the Amisolver program (Excellence Framework). We are grateful to the Public Authorities of Champagne-Ardenne and FEDER for material funds and post-doctoral fellowships to J.-P.M and to S. Hayouni and M. Mention for preliminary studies.
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