[en] Two new families of glycerol-based dendrimers
(glyceroladendrimers (GADs) and glyceroclickdendrimers (GCDs))
have been synthesized. Three generations have been isolated for each
family with good yields and were fully analyzed. The encapsulation of
essential oils (citronella and cinnamon) in GADs, GCDs, and also in
previously described glycerodendrimers GD-PAMAMs and GD-PPIs
has been studied by dynamic-headspace gas chromatography coupled
to mass spectrometry. The retention rates obtained were from −35.8
to 26.65% for citronella essential oil and from 2.14 to 38.84% for the
cinnamon essential oil. In addition, the best results were obtained with
GD-PAMAMs and GD-PPIs of higher generation. The interaction
study between essential oils or more precisely their major components
have been performed through NMR spectroscopy (1
H NMR and
DOSY NMR). No direct interactions between dendrimers and
essential oils have been observed, but a surprising behavior of compression of the dendrimer in stable emulsions was observed.
Indeed, the hydrodynamic radius of GD-PPI-3 has been reduced in the presence of cinnamon essential oil.
Disciplines :
Chemistry Agriculture & agronomy
Author, co-author :
Maes, Chloé ; Université de Liège - ULiège > Département GxABT > Chimie des agro-biosystèmes ; UMR CNRS 7312, Université Reims-Champagne-Ardenne, Institut de Chimie Moléculaire de Reims, UFR Sciences, BP 1039 boîte 44, 51687 Reims Cedex 2, France
Menot, Bérengère; UMR CNRS 7312, Université Reims-Champagne-Ardenne, Institut de Chimie Moléculaire de Reims, UFR Sciences, BP 1039 boîte 44, 51687 Reims Cedex 2, France
Hayouni, Safa; UMR CNRS 7312, Université Reims-Champagne-Ardenne, Institut de Chimie Moléculaire de Reims, UFR Sciences, BP 1039 boîte 44, 51687 Reims Cedex 2, France
Martinez, Agathe; UMR CNRS 7312, Université Reims-Champagne-Ardenne, Institut de Chimie Moléculaire de Reims, UFR Sciences, BP 1039 boîte 44, 51687 Reims Cedex 2, France
Bouquillon, Sandrine ; UMR CNRS 7312, Université Reims-Champagne-Ardenne, Institut de Chimie Moléculaire de Reims, UFR Sciences, BP 1039 boîte 44, 51687 Reims Cedex 2, France
Language :
English
Title :
Preparation of New Glycerol-Based Dendrimers and Studies on Their Behavior toward Essential Oil Encapsulation
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