[en] This review is dedicated to the state‐of‐the art routes used for the synthesis of CO2 ‐based
(a)cyclic carbonates and polycarbonates from alcohol substrates, with an emphasis on their respective main advantages and limitations. The first section reviews the synthesis of organic carbonates such as dialkyl carbonates or cyclic carbonates from the carbonation of alcohols. Many different synthetic strategies have been reported (dehydrative condensation, the alkylation route, the “leaving group” strategy, the carbodiimide route, the protected alcohols route, etc.) with various substrates (mono‐alcohols, diols, allyl alcohols, halohydrins, propargylic alcohols, etc.). The second section reviews the formation of polycarbonates via the direct copolymerization of CO2
with diols, as well as the ring‐opening polymerization route. Finally, polycondensation processes involving CO2-‐based dimethyl and diphenyl carbonates with aliphatic and aromatic diols are described.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM), Belgium Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Belgium
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Brege, Antoine ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Grignard, Bruno ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Méreau, Raphaël; University of Bordeaux, CNRS, Institute of Molecular Sciences, Talence, France
Detrembleur, Christophe ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Jérôme, Christine ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Tassaing, Thierry; University of Bordeaux, CNRS, Institute of Molecular Sciences, Talence, France
Language :
English
Title :
En route to CO2-based (a)cyclic carbonates and polycarbonates from alcohols substrates by direct and indirect approaches
Publication date :
20 January 2022
Journal title :
Catalysts
eISSN :
2073-4344
Publisher :
MDPI AG, Basel, Switzerland
Volume :
12
Issue :
2
Pages :
124
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE] FWO - Fonds Wetenschappelijk Onderzoek Vlaanderen [BE] EOS - The Excellence Of Science Program [BE] Région Nouvelle-Aquitaine [FR]
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