Orientation and Order of Self-Assembled p-Benzenedimethanethiol Films on Pt(111) Obtained by Direct Adsorption and via Alkanethiol Displacement

Silien, Christophe; Dreesen, Laurent; Cecchet, Francesca; Thiry, Paul. A.; Peremans, André

doi:10.1021/jp067153e

Article (Scientific journals)

Orientation and Order of Self-Assembled p-Benzenedimethanethiol Films on Pt(111) Obtained by Direct Adsorption and via Alkanethiol Displacement

Silien, Christophe; Dreesen, Laurent; Cecchet, Francesca et al.

2007 • In Journal of Physical Chemistry. C, Nanomaterials and interfaces, 111, p. 6357-6364

Peer reviewed

Permalink
https://hdl.handle.net/2268/26607

DOI
10.1021/jp067153e

Files (1)Send to Details Statistics Bibliography Similar publications

Files

Full Text

J Phys Chem C_2007_N111_p6357-Silien.pdf

Publisher postprint (271.16 kB)

Request a copy

All documents in ORBi are protected by a user license.

Send to

RIS BibTex APA Chicago Permalink X Linkedin

Details

Abstract :

[en] Self-assembly of p-benzenedimethanethiol (p-BDMT) on Pt(111) has been investigated by high-resolution electron energy loss spectroscopy and sum-frequency generation spectroscopy. The molecules adsorb on Pt-(111) like on gold, attached through one single thiol, leaving the second thiol moiety unreacted and exposed to the outer surface. Yet, the order of the p-BDMT self-assembled film is poor in comparison to alkanethiol SAMs. Displacement in solution of a preadsorbed pentanethiol (PTT) SAM by p-BDMT molecules proved to be a successful approach to achieve films of higher quality, where the size of the dithiol molecular domains tends toward the size measured for PTT. Nearly complete exchange is accomplished after 42 h. However, no significant exchange is observed when dodecanethiol replaces PTT. Displacing the alkanethiols by benzenethiol leads to the same conclusions, suggesting that the exchange processes are lessened as compared to gold.

Disciplines :

Physics

Author, co-author :

Silien, Christophe

Dreesen, Laurent ; Université de Liège - ULiège > Département de physique > Biophotonique

Cecchet, Francesca

Thiry, Paul. A.

Peremans, André

Language :

English

Title :

Orientation and Order of Self-Assembled p-Benzenedimethanethiol Films on Pt(111) Obtained by Direct Adsorption and via Alkanethiol Displacement

Publication date :

2007

Journal title :

Journal of Physical Chemistry. C, Nanomaterials and interfaces

ISSN :

1932-7447

eISSN :

1932-7455

Volume :

111

Pages :

6357-6364

Peer reviewed :

Peer reviewed

Available on ORBi :

since 26 October 2009

Statistics

Number of views

80 (1 by ULiège)

Number of downloads

0 (0 by ULiège)

More statistics

Scopus citations^®

Scopus citations^®
without self-citations

OpenCitations

Bibliography

Tour, J. M.; Jones, L., II; Pearson, D. L.; Lamba, J. J. S.; Burgin, T. P.; Withesides, O. M.; Allara, D. L.; Parikh, A. N.; Atre, S. V. J. Am. Chem. Soc. 1995, 117, 9529-9534.
Murty, K. V. G. K.; Venkataramanan, M.; Pradeep, T. Langmuir 1998, 14, 5446-5456.
Kohli, P.; Taylor, K. K.; Harris, J. J: Blanchard, G. J. J. Am. Chem. Soc. 1998, 120, 11962-11968.
Rieley, H.; Kendall, G. K.; Zemicael, F. W.; Smith, T. L.; Yang, S. Langmuir 1998, 14, 5147-5133.
Joo, S. W.; Han, S. W.; Kim, K. J. Phys. Chem. B 1999, 103, 10831-10837.
de Boer, B.; Meng, H.; Perepichka, D. F.; Zheng, J.; Frank, M. M.; Chabal, Y. J.; Bao, Z. Langmuir 2003, 19, 4272-4284.
Pugmire, D. L.; Tarlov, M. J.; van Zee, R. D. Langmuir 2003, 19, 3720-3726.
Tai, Y.; Shaporenko, A.; Rong, H.-T.; Buck, M.; Eck, W.; Grunze, M.; Zharnikov, M. J. Phys. Chem. B 2004, 108, 16806-16810.
Kwon, C. K.; Kim, K.; Kim, M. S. J. Mol. Struct. 1989, 197, 171-180.
Lee, T. G.; Kim, K.; Kim, M. S. J. Phys. Chem. 1991, 95, 9950-9955.
Cho, S. H.; Han, H. S.; Jang, D.-J.; Kim, K.; Kim, M. S. J. Phys. Chem. 1995, 99, 10594-10599.
Venkataramanan, M.; Ma, S.; Pradeep, T. J. Colloid Interface Sci. 1999, 216, 134-142.
Leung, T. Y. B.; Gernstenberg, M. C.; Lavrich, D. J.; Scoles, G.; Schreiber, F.; Poirier, G. E. Langmuir 2000, 16, 549-561.
Rifai, S.; Lopinski, G. P.; Ward, T.: Wayner, D. D. M.; Morin, M. Langmuir 2003, 19, 8916-8921.
Weckenmann, S. U.; Mittler, S.; Naumann, K.; Fischer, R. A. Langmuir 2002, 18, 5479-5486.
Henderson, J. I.; Feng, S.; Ferrence, G. M.; Beins, T.; Kubiak, C. P. Inorg. Chim. Acta 1996, 242, 115-124.
Dorogi, M.; Gomez, J. M.; Osifchin, R. J.; Andres, R. P.; Reifenberger, R. P. Phys. Rev. B 1995, 52, 9071-9077.
Dadosh, T.; Gordin, Y.; Krahne, R.; Khivrich, L; Mahalu, D.; Frydman, V.; Sperling, J.; Yacoby, A.; Bar-Joseph, I. Nature 2005, 436, 677-680.
Jiang, W.; Zhitenev, N.; Bao, Z.; Meng, H.; Abusch-Magder, D.; Tennant, D.; Garfunkel, E. Langmuir 2005, 21, 8751-8757.
Yang, Y.-C.; Yang, S.-L.; Yau, Y. S.-L.; Lee, Y.-L. J. Am. Chem. Soc. 2006, 128, 3677-3682.
de Boer, M. M. B.; Frank, Y. J. M. M.; Chabal, W. Y. J.; Jiang, E. W.; Garfunkel, Z. E.; Bao, Z. Langmuir 2004, 20, 1539-1542.
Li, Z.; Chang, S. C.; Williams, R. S. Langmuir 2003, 19, 6744-6749.
Ulman, A. Chem. Rev. 1996, 96, 1533-1554.
Schlenoff, J. B.; Li, M.; Ly, H. J. Am. Chem. Soc. 1995, 117, 12528-12536.
Yang, Y.-C.; Lee, Y.-L.; Yang, L.-Y. O,; Yau, S.-L. Langmuir 2006, 22, 5189-5195.
Kim, B.; Ahn, S. J.; Park, J. G.; Lee, S. H.; Park, Y. W. Appl. Phys. Lett. 2004, 85, 4756-4758.
Kim, B.; Ahn, S. J.; Park, J. O.; Lee, S. H.; Park, Y. W.; Campbell, E. E. B. Thin Solid Films 2006, 499, 196-200.
Cygan, M. T.; Dunbar, T. D.; Arnold, J. J.; Bumm, L. A.; Shedlock, N. F.; Burgin, T. P.; Jones, L.; Allara, D. L.; Tour, J. M.; Weiss, P. S. J. Am. Chem. Soc. 1998, 120, 2721-2732.
Lin, P.-H.; Guyot-Sionnest, P. Langmuir 1999, 15, 6825-6828.
Baralia, G. B.; Duwez, A.-S.; Nysten, B.; Jonas, A. M. Langmuir 2005, 21, 6825-6829.
Chidsey, C. E. D.; Bertozzi, C. R.; Putvinski, T. M.; Mujsce, A. M. J. Am. Chem. Soc. 1990, 112, 4301.
Collard, D. M.; Fox, M. A. Langmuir 1991, 7, 1192.
Aizenberg, J.; Black, A. J.; Withesides, G. M. Nature 1998, 394, 868-871.
Kakiuchi, T.; Sato, K.; Iida, M.; Hobara, D.; Imabayashi, S.-I.; Niki, K. Langmuir 2000, 16, 7238-7244.
Ibach H.; Mills D. L. Electron Energy Loss Spectroscopy and surface vibrations; Academic Press: New York, 1982
Shen, Y. R. The Principles of Nonlinear Optics; Wiley: New York, 1984.
Mani, A. A.; Dreesen, L.; Humbert, C.; Hollander, P.; Caudano, Y.; Thiry, P. A.; Peremans, A. Appl. Surf. Sci. 2002, 502-503, 261-267.
Mani, A. A.; Dreesen, L.; Hollander, Ph.; Humbert, C.; Caudano, Y.; Thiry, P. A.; Peremans, A. Appl. Phys. Lett. 2001, 79, 1945-1947.
Rifai, S.; Morin, M. J. Electroanal. Chem. 2003, 550-551, 277-289.
Han, S. W.; Lee, S. J.; Kim, K. Langmuir 2001, 17, 6981-6987.
Kato, H. S.; Noh, J.; Hara, M.; Kawai, M. J. Phys. Chem. B 2002, 106, 9655-9658.
Kluth, G. J.; Carraro, C.; Maboudian, R. Phys. Rev. B 1999, 59, R10449-R10452.
Maboudian, R. Surf. Sci. Rep. 1998, 30, 207-269.
Rei Vilar, M.; Bouali, Y.; Kitakatsu, N.; Lang, Ph.; Mitchalitsch, R.; Gamier, F.; Dubot, P. Thin Solid Films 1998, 327-329, 236-240.
Lin, T. H.; Huang, T. P.; Liu, Y. L.; Yeh, C. C.; Lai, Y. H.; Hung, W. H. J. Phys. Chem. B 2005, 109, 14079-14084.
Duwez, A.-S.; Yu, L. M.; Riga, J.; Pireaux, J.-J.; Delhalle, J. Thin Solid Films 1998, 327-329, 156-160.
Hines, M. A.; Todd, J. A.; Guyot-Sionnest, P. Langmuir 1995, 11, 493-497.
Dreesen, L.; Humbert, C.; Celebi, M.; Lemaire, J. J.; Mani, A. A.; Thiry, P. A.; Peremans, A. Appl. Phys. B 2002, 74, 621-625.
Although we could not proceed with a precise calibration of the SFG intensities, we repeatedly observed that the nonresonant signal of p-BDMT is of the same magnitude as the peak intensity of PTT.
That assertion has been verified by us for SAM made of all three BDMT isomers and for BT, 1,3-benzenedithiol benzeneselenol, and methanebenzenethiol.
Nishi, N.; Hobara, D.; Yamamoto, M.; Kakiuchi, T. Langmuir 2003, 19, 6187-6192.
Stoycheva, S.; Himmelhaus, M.; Fick, J.; Kornviakov, A.; Grunze, M.; Ulman, A. Langmuir 2006, 22, 4170-4178.
Kim, Y.-K.; Koo, J. P.; Ha, J. S. Appl. Surf. Sci. 2005, 249, 7-11.
Bruckner, M.; Heinz, B.; Morgner, H. Surf. Sci. 1994, 319, 370-380.
Roke, S.; Schins, J.; Muller, M.; Bonn, M. Phys. Rev. Lett. 2003, 90, 128101-1288104.
Ma, G.; Allen, H. C. Langmuir 2006, 22, 5341-5349.
Liu, J.; Conboy, J. C. Langmuir 2005, 21, 9091-9097.
Mugele, F.; Baldelli, S.; Salmeron, M.; Somorjai, G. A. J. Phys. Chem. B 2000, 104, 3140-3144.
Walker, R. A.; Gruetzmacher, J. A.; Richmond, G. L. J. Am. Chem. Soc. 1998, 120, 6991-7003.