Mapping soil Pb stocks and availability in mainland France combining regression trees with robust geostatistics

Availability; Diffuse contamination mapping; Regression tree; Robust geostatistics; Soil Pb; Ethylenediaminetetraacetic acid; Explanatory variables; Fixed effects; Geo-statistics; Geostatistical; Key factors; Linear mixed models; Parent materials; Peak concentrations; Population densities; Regression tree models; Regression trees; Soil monitoring; Spatial correlations; Winsorizing; Lithology; Population statistics; Regression analysis; Soils; Textures; Forestry; EDTA; Biological Populations; Soil; Statistics; Texture; France

Abstract :

[en] Maps of lead (Pb) stocks in soils and estimates of its availability are needed to assess risks of contamination. Stocks in soils of total and ethylenediamine tetraacetic acid (EDTA) extractable Pb, as well as Pb availability, assessed by EDTA/total Pb ratio, were measured and calculated to a depth of 30. cm with the French soil monitoring network at sites defined by a regular 16 × 16. km grid. Setting aside punctual anomalies by winsorizing, these properties were mapped using linear mixed models (LMM). LMMs combined conditional partitioning trees upon 5 predictors (pH, texture, parent material, land use, population density) with robust geostatistics to avoid distortion due to outlying values. Rather than selecting the fixed effects according to expert-knowledge, regression trees were used to account for explanatory variables in a single classification. This original method stressed both the necessity for a geostatistical component to complement regression tree models when spatial correlation is evident, and the usefulness of these trees to interpret maps. Pb stocks varied widely with peak concentrations and availability in densely populated areas. Lithology, texture and forestation also affected total Pb stocks. With regards to availability, forestation and pH appeared as key factors. © 2011 Elsevier B.V.

Disciplines :

Environmental sciences & ecology

Author, co-author :

Lacarce, E.; INRA, US 1106 Infosol, INRA Orléans, CS 40001 Ardon, F45075 Orleans Cedex 2, France

Saby, N. P. A.; INRA, US 1106 Infosol, INRA Orléans, CS 40001 Ardon, F45075 Orleans Cedex 2, France

Martin, M. P.; INRA, US 1106 Infosol, INRA Orléans, CS 40001 Ardon, F45075 Orleans Cedex 2, France

Marchant, B. P.; Rothamstead Research, Harpenden, Hertfordshire AL5 2JQ, United Kingdom

Boulonne, L.; INRA, US 1106 Infosol, INRA Orléans, CS 40001 Ardon, F45075 Orleans Cedex 2, France

Meersmans, Jeroen ; Université de Liège - ULiège > Département GxABT > Analyse des risques environnementaux

Jolivet, C.; INRA, US 1106 Infosol, INRA Orléans, CS 40001 Ardon, F45075 Orleans Cedex 2, France

Bispo, A.; ADEME, Centre d'Angers, Direction Déchets et Sols, 20 avenue du Grésillé, BP 90406, F49004 Angers Cedex 01, France

Arrouays, D.; INRA, US 1106 Infosol, INRA Orléans, CS 40001 Ardon, F45075 Orleans Cedex 2, France

Language :

English

Title :

Mapping soil Pb stocks and availability in mainland France combining regression trees with robust geostatistics

Publication date :

2012

Journal title :

Geoderma

ISSN :

0016-7061

eISSN :

1872-6259

Publisher :

Elsevier, Netherlands

Volume :

170

Pages :

359-368

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

BBSRC - Biotechnology and Biological Sciences Research Council

Funding number :

BBS/E/C/00004943

Available on ORBi :

since 08 November 2021

Statistics

Number of views

68 (1 by ULiège)

Number of downloads

1 (1 by ULiège)

More statistics

Scopus citations^®

Scopus citations^®
without self-citations

OpenCitations

OpenAlex citations

Bibliography

AFNOR Qualité des sols - Méthodes physiques - Mesure de la masse volumique apparente d'un échantillon de sol non remanié - Méthode du cylindre., NF X31-501 1992, AFNOR.
AFNOR Qualité du sol - détermination du pH, ISO 10390:1994 1994, AFNOR.
AFNOR Mise en solution pour la détermination des teneurs élémentaires totales - Partie 1: mise en solution par l'acide fluorhydrique et l'acide perchlorique, NF ISO 14869-1 2001, AFNOR.
AFNOR Qualité de l'eau - Application de la spectrométrie de masse avec plasma à couplage inductif (ICP-MS) - Partie 2: Dosage de 62 éléments, ISO 17294-2:2003 2003, AFNOR.
AFNOR Qualité du sol - Détermination de la distribution granulométrique des particules du sol - Méthode à la pipette, NF X31-107 2003, AFNOR.
AFNOR Soil Quality - Pretreatment of Samples for Physico-Chemical Analysis, NF ISO 11464 2006.
Agreste L'utilisation du territoire en 2008 - Teruti-Lucas. n° 208 2009.
Arrouays D., Mench M., Amans V., Gomez A. Short-range variability of fallout Pb in a contaminated soil. Canadian Journal of Soil Science 1996, 76(1):73-81.
Arrouays D., et al. A new initiative in France: a multi-institutional soil quality monitoring network. Comptes rendus de l'Academie d'Agriculture de France 2002, 88(5):93-103.
Baize D. Teneurs totales en éléments traces métalliques dans les sols (France). Un point sur. INRA, Paris 1997, 409pp.
Baize D., Chrétien J. Les couvertures pédologiques de la plate-forme sinémurienne en Bourgogne. Particularités morphologiques et pédo-géochimiques. Etude et Gestion des Sols 1994, 2:7-27.
Baize D., Saby N., Deslais W. Content of Eight Trace Metals (Cd, Cr, Cu, Hg, Ni, Pb, Se, Zn) in French Arable Topsoils. Convention 0375 C0035, ADEME, Angers, France 2007.
Bivand R.S., Pebesma E.J., Gómez-Rubio V. Applied Spatial Data Analysis with R. UseR! Series 2008, Springer, 378pp.
Breiman L., Friedman J.H., Olshen R.A., Stone C.J. Classification and Regression Trees 1984, Wadsworth, Belmont, California.
Citeau L., Lamy I., van Oort F., Elsass F. Colloidal facilitated transfer of metals in soils under different land use. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2003, 217(1-3):11.
CITEPA Emission dans l'air en France. Métropole. Substances relatives à la contamination par les métaux lourds, Centre Interprofessionnel Technique d'Etudes de la Pollution Atmosphérique, Paris, France 2010.
Cornu S., et al. Trace element accumulation in Mn-Fe-oxide nodules of a planosolic horizon. Geoderma 2005, 125(1-2):11-24.
Cressie N. Fitting variogram models by weighted least squares. Journal of the International Association for Mathematical Geology 1985, 17:563-586.
Demetriades A., Li X.D., Ramsey M.H., Thornton I. Chemical speciation and bioaccessibility of lead in surface soil and house dust, Lavrion urban area, Attiki, Hellas. Environmental Geochemistry and Health 2010, 32(6):529-552.
Denaix L., Semlali R.M., Douay F. Dissolved and colloidal transport of Cd, Pb, and Zn in a silt loam soil affected by atmospheric industrial deposition. Environmental Pollution 2001, 114(1):29-38.
Douay F., et al. Contamination of woody habitat soils around a former lead smelter in the North of France. Science of the Total Environment 2009, 407(21):5564-5577.
Dowd P.A. The variogram and kriging: robust and resistant estimators. Geostatistics for Natural Resources Characterrization 1984, 91-106. D. Reidel, Dordrecht. G. Verly, A.G. David, A.G. Journal, A. Marechal (Eds.).
Egli M., Fitze P., Oswald M. Changes in heavy metal contents in an acidic forest soil affected by depletion of soil organic matter within the time span 1969-93. Environmental Pollution 1999, 105(3):367-379.
Falq G., et al. Blood lead levels in the adult population living in France the French Nutrition and Health Survey (ENNS 2006-2007). Environment International 2011, 37(3):565.
Gandois L., Probst A., Dumat C. Modelling trace metal extractability and solubility in French forest soils by using soil properties. European Journal of Soil Science 2010, 61(2):271-286.
Glorennec P., et al. Probabilistic modeling of young children's overall lead exposure in France: integrated approach for various exposure media. Environment International 2007, 33(7):937.
Hawkins D.M., Cressie N. Robust kriging - a proposal. Journal of the International Association for Mathematical Geology 1984, 16(1):3-18.
Hothorn T., Hornik K., Zeileis A. Unbiased recursive partitioning: a conditional inference framework. Journal of Computational and Graphical Statistics 2006, 15(3):651-674.
INSEE Evolutions démographiques 1990-1999: populations définitives-logements provisoires, département, communes, zones d'emploi, unités urbaines 1999 [Ressource électronique]. - 2e éd 2000, Paris, France. INSEE (Ed.).
King D., et al. The EU soil geographical database. European Land Information Systems for Agro-Environmental Monitoring, EUR 16232 EN 1995, Office for Official Publications of the European Communities, Luxembourg. D. King, R.J.A. Jones, A.J. Thomasson (Eds.).
Lacarce E., et al. Data management for monitoring forest soils in Europe for the Biosoil project. Soil Use and Management 2009, 25(1):57-65.
Laidlaw M.A.S., Taylor M.P. Potential for childhood lead poisoning in the inner cities of Australia due to exposure to lead in soil dust. Environmental Pollution 2011, 159(1):1-9.
Lark R.M. Modelling complex soil properties as contaminated regionalized variables. Geoderma 2002, 106(3-4):173-190.
Lemercier B., et al. Broad-scale soil monitoring through a nationwide soil-testing database. Digital Soil Mapping with Limited Data 2008, 273-281. Springer, Netherlands. A.E. Hartemink, A. McBratney, M. Mendonça-Santos (Eds.).
Marchant B.P., et al. Robust analysis of soil properties at the national scale: cadmium content of French soils. European Journal of Soil Science 2010, 61(1):144-152.
Marchant B., Tye A., Rawlins B. The assessment of point-source and diffuse soil metal pollution using robust geostatistical methods: a case study in Swansea (Wales, UK). European Journal of Soil Science 2011, (62):346-358.
Markus J., McBratney A.B. A review of the contamination of soil with lead: II. Spatial distribution and risk assessment of soil lead. Environment International 2001, 27(5):399.
Martin M.P., et al. Optimizing pedotransfer functions for estimating soil bulk density using boosted regression trees. Soil Science Society of America Journal 2009, 73(2):485-493.
Matérn B. Spatial variation. Meddelanden fran Statens Skogsforskningsinstitut 1960, 49:1-144.
Menzies N.W., Donn M.J., Kopittke P.M. Evaluation of extractants for estimation of the phytoavailable trace metals in soils. Environmental Pollution 2007, 145(1):121-130.
Mielke H.W., Laidlaw M.A.S., Gonzales C.R. Estimation of leaded (Pb) gasoline's continuing material and health impacts on 90 US urbanized areas. Environment International 2011, 37(1):248-257.
Morvan X., et al. Soil monitoring in Europe: A review of existing systems and requirements for harmonisation. Science of the Total Environment 2008, 391(1):1.
Nicolini P. Gîtologie des concentrations minérales stratiformes 1970, Gauthier-Villars Editeurs, Paris, 792pp.
Palumbo B., Bellanca A., Neri R., Roe M.J. Trace metal partitioning in Fe-Mn nodules from Sicilian soils, Italy. Chemical Geology 2001, 173:257-269.
Peryea F.J. Historical use of lead arsenate insecticides, resulting soil contamination and implications for soil remediation. 16th World Congress of Soil Science, Montpellier, France 1998, 20-26.
Quevauviller P., et al. Certified reference material for the quality control of EDTA- and DTPA-extractable trace metal contents in calcareous soil (CRM 600). Fresenius' Journal of Analytical Chemistry 1998, 360(5):505-511.
Quinton J.N., Catt J.A. Enrichment of heavy metals in sediment resulting from soil erosion on agricultural fields. Environmental Science & Technology 2007, 41(10):3495-3500.
R: A Language and Environment for Statistical Computing 2009, R Foundation for Statistical Computing, Vienna, Austria. R. Development Core Team (Ed.).
Ribeiro P.J., Diggle P.J. geoR: a package for geostatistical analysis. R-NEWS 2001, 1(2):15-18.
Rieuwerts J.S., Ashmore M.R., Farago M.E., Thornton I. The influence of soil characteristics on the extractability of Cd, Pb and Zn in upland and moorland soils. Science of the Total Environment 2006, 366(2-3):864-875.
Rodrigues S.M., et al. Evaluation of an approach for the characterization of reactive and available pools of 20 potentially toxic elements in soils: part II - solid-solution partition relationships and ion activity in soil solutions. Chemosphere 2010, 81(11):1560-1570.
Saby N.P.A., et al. Changes in soil organic carbon in a mountainous French region, 1990-2004. Soil Use and Management 2008, 24(3):254-262.
Saby N.P.A., Marchant B.P., Lark R.M., Jolivet C.C., Arrouays D. Robust geostatistical prediction of trace elements across France. Geoderma 2011, 162(3-4):303-311.
Sauvé S., Hendershot W., Allen H.E. Solid-solution partitioning of metals in contaminated soils: dependence on pH, total metal burden, and organic matter. Environmental Science & Technology 2000, 34(7):1125-1131.
Semlali R.M., et al. Modeling lead input and output in soils using lead isotopic geochemistry. Environmental Science & Technology 2004, 38(5):1513-1521.
Smith S.R. A critical review of the bioavailability and impacts of heavy metals in municipal solid waste composts compared to sewage sludge. Environment International 2009, 35(1):142.
SOGREAH Bilan des flux de contaminants entrant sur les sols agricoles de France métropolitaine. Agence de l'Environnement et de la Maitrise de l'Energie 2007, 329pp.
UE-SOeS CORINE Land Cover. Service de l'observation et des statistiques (SOeS) du Ministère chargé de l'environnement 2000.
UMR LERFoB and IFN Carte des pH de surface des sols forestiers - Données et guide d'utilisation selon le document accord AgroParisTech (UMR LERFoB) IFN n° 2007-CPA-2-072 2008.
Unamuno V.I.R., Meers E., Du Laing G., Tack F.M.G. Effect of physicochemical soil characteristics on copper and lead solubility in polluted and unpolluted soils. Soil Science 2009, 174(11):601-610.
Vega F.A., Andrade M.L., Covelo E.F. Influence of soil properties on the sorption and retention of cadmium, copper and lead, separately and together, by 20 soil horizons: comparison of linear regression and tree regression analyses. Journal of Hazardous Materials 2010, 174(1/3):522-533.
Webster R., Oliver M.A. Geostatistics for Environmental Scientists 2007, Wiley, Chichester.