A1. Black phosphorus; A1. Chemical vapor transport; B1. Copper; A2. Optimizations; A.2 BP conversion ratio
Abstract :
[en] Understanding the growth mechanism of large crystals and high-quality of black phosphorus (BP) is a fundamental challenge to further study its physical properties. The BP was prepared from amorphous red phosphorus (RP), by short-way chemical vapor transport (CVT) reaction using the addition of small quantities of copper, tin, and tin(IV) iodide as reaction promoters. The method used in this present work is currently developed by our research laboratory for preparation of BP. In fact, a series of experiments was designed to understand and optimize the preparation conditions (the catalyst's choice (Cu), temperature, time, dimensions of quartz tube ...) of this surprisingly easy and effective method and to ensure a high BP conversion ratio (wt%) from RP with high purity, high crystallinity, and large size of orthorhombic BP (flakes size ∼1 cm), It’s the main goal of this work. The products recovered in the hot and cold zones of the tube are analyzed by X-ray diffraction (XRD) to give an idea of the role of mineralizers (Cu,Sn, and SnI4) allowing the synthesis of BP. Decomposition of reaction system (RP/Cu/Sn) with the tin(IV) iodide should lead to the formation of the condensed phases represented by Cu4SnP10,Sn4P3, CuSn,Cu2P7, SnI4 and P2O5could be detected at a hot zone of the tube. The characterizations of the prepared BP were carried out also using Raman spectroscopy, scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX) and Raman spectroscopy.
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Bibliography
Bridgman, P.W., Two new modifications of phosphorus. J. Am. Chem. Soc. 36:7 (1914), 1344–1363, 10.1021/ja02184a002.
Karttunen, A.J., Linnolahti, M., Pakkanen, T.A., Structural Principles of Polyhedral Allotropes of Phosphorus. ChemPhysChem 9:17 (2008), 2550–2558, 10.1002/cphc.v9:1710.1002/cphc.200800646.
Keyes, R.W., The electrical properties of black phosphorus, Physical. Review. 92:3 (1953), 580–584, 10.1103/PhysRev.92.580.
Z. Zhu, D. Tománek, Semiconducting Layered Blue Phosphorus: A Computational Study, (2014). https://doi.org/10.1103/PhysRevLett.112.176802.
A. Brown, S.R.-A. Crystallographica, U. 1965, Refinement of the crystal structure of black phosphorus, Scripts.Iucr.Org. 19 (1965) 684–685. https://doi.org/10.1107/S0365110X65004140 (accessed May 30, 2020).
Liu, H., Du, Y., Deng, Y., Ye, P.D., Semiconducting black phosphorus: Synthesis, transport properties and electronic applications. Chem. Soc. Rev. 44:9 (2015), 2732–2743, 10.1039/C4CS00257A.
Ribeiro-Soares, J., Almeida, R.M., Cançado, L.G., Dresselhaus, M.S., Jorio, A., Group theory for structural analysis and lattice vibrations in phosphorene systems. Phys. Rev. B Condensed Matter Mater. Phys., 91(20), 2015, 10.1103/PhysRevB.91.205421.
Akahama, Y., Utsumi, W., Endo, S., Kikegawa, T., Iwasaki, H., Shimomura, O., Yagi, T., Akimoto, S., Melting curve of black phosphorous. Phys. Lett. A 122:2 (1987), 129–131, 10.1016/0375-9601(87)90790-0.
Çaklr, D., Sevik, C., Peeters, F.M., Significant effect of stacking on the electronic and optical properties of few-layer black phosphorus. Phys. Rev. B Condensed Matter Mater. Phys. 92 (2015), 1–8, 10.1103/PhysRevB.92.165406.
Shu, H., Li, Y., Niu, X., Wang, J., The stacking dependent electronic structure and optical properties of bilayer black phosphorus. PCCP 18:8 (2016), 6085–6091, 10.1039/C5CP07995K.
Castellanos-Gomez, A., Vicarelli, L., Prada, E., Island, J.O., Narasimha-Acharya, K.L., Blanter, S.I., Groenendijk, D.J., Buscema, M., Steele, G.A., Alvarez, J.V., Zandbergen, H.W., Palacios, J.J., van der Zant, H.S.J., Van Der Zant, Isolation and characterization of few-layer black phosphorus. 2D Materials., 1(2), 2014, 025001, 10.1088/2053-1583/1/2/025001.
Sansone, G., Maschio, L., Usvyat, D., Schütz, M., Karttunen, A., Toward an Accurate Estimate of the Exfoliation Energy of Black Phosphorus: A Periodic Quantum Chemical Approach. J. Phys. Chem. Lett. 7:1 (2016), 131–136, 10.1021/acs.jpclett.5b02174.
R. Mansfield, W. Williams, The electrical properties of bismuth telluride, Proceedings of the Physical Society. 72 (1958) 733–741. https://doi.org/10.1088/0370-1328/72/5/307.
Tran, V., Soklaski, R., Liang, Y., Yang, L., Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus. Phys. Rev. B Condensed Matter Mater. Phys. 89 (2014), 1–6, 10.1103/PhysRevB.89.235319.
Aldave, S.H., Yogeesh, M.N., Zhu, W., Kim, J., Sonde, S.S., Nayak, A.P., Akinwande, D., Characterization and sonochemical synthesis of black phosphorus from red phosphorus. 2D Materials., 3(1), 2016, 014007, 10.1088/2053-1583/3/1/014007.
Jariwala, D., Sangwan, V.K., Lauhon, L.J., Marks, T.J., Hersam, M.C., Emerging device applications for semiconducting two-dimensional transition metal dichalcogenides. ACS Nano 8:2 (2014), 1102–1120, 10.1021/nn500064s.
Tiouitchi, G., Ali, M.A., Benyoussef, A., Hamedoun, M., Lachgar, A., Benaissa, M., Kara, A., Ennaoui, A., Mahmoud, A., Boschini, F., Oughaddou, H., El Kenz, A., Mounkachi, O., An easy route to synthesize high-quality black phosphorus from amorphous red phosphorus. Mater. Lett. 236 (2019), 56–59, 10.1016/j.matlet.2018.10.019.
G. Tiouitchi, M. Raji, O. Mounkachi, M.A. Ali, A. Mahmoud, F. Boschini, H. Essabir, R. Bouhfid, A. el kacem Qaiss, Black phosphorus-based polyvinylidene fluoride nanocomposites: Synthesis, processing and characterization, Composites Part B: Engineering. 175 (2019) 107165. https://doi.org/10.1016/j.compositesb.2019.107165.
Lange, S., Schmidt, P., Nilges, T., Au3SnP7@Black Phosphorus: An easy access to black phosphorus. Inorg. Chem. 46 (2007), 4028–4035, 10.1021/ic062192q.
Lu, W., Nan, H., Hong, J., Chen, Y., Zhu, C., Liang, Z., Ma, X., Ni, Z., Jin, C., Zhang, Z., Plasma-assisted fabrication of monolayer phosphorene and its Raman characterization. Nano Res. 7:6 (2014), 853–859, 10.1007/s12274-014-0446-7.
Maruyama, Y., Suzuki, S., Kobayashi, K., Tanuma, S., Synthesis and some properties of black phosphorus single crystals. Physica B+C. 105:1-3 (1981), 99–102, 10.1016/0378-4363(81)90223-0.
Ling, X., Wang, H., Huang, S., Xia, F., Dresselhaus, M.S., The renaissance of black phosphorus. PNAS 112:15 (2015), 4523–4530, 10.1073/pnas.1416581112.
Schöneich, M., Schmidt, M.P., Schmidt, P., Chemical vapour transport of bismuth and antimony chalcogenides M 2Q3 (M = Sb, Bi, Q = Se, Te). Z. Anorg. Allg. Chem. 636:9-10 (2010), 1810–1816, 10.1002/zaac.201000149.
Thiel, H., Zur Kristallstruktur des schwarzen Phosphors. Ann. Phys. 452:2-3 (1956), 122–125, 10.1002/(ISSN)1521-3889.
Vanderborgh, C.A., Schiferl, D., Raman studies of black phosphorus from 0.25 to 7.7 GPa at 15 K. Phys. Rev. B. 40:14 (1989), 9595–9599, 10.1103/PhysRevB.40.9595.
Gupta, S.N., Singh, A., Pal, K., Chakraborti, B., Muthu, D.V.S., Waghmare, U.V., Sood, A.K., Raman anomalies as signatures of pressure induced electronic topological and structural transitions in black phosphorus: Experiments and theory. Phys. Rev. B. 96 (2017), 1–10, 10.1103/PhysRevB.96.094104.
Akhtar, M., Anderson, G., Zhao, R., Alruqi, A., Mroczkowska, J.E., Sumanasekera, G., Jasinski, J.B., Recent advances in synthesis, properties, and applications of phosphorene. npj 2D Mater. Appl. 1 (2017), 1–12, 10.1038/s41699-017-0007-5.
Feng, Y., Zhou, J., Du, Y., Miao, F., Duan, C.-G., Wang, B., Wan, X., Raman spectra of few-layer phosphorene studied from first-principles calculations. J. Phys.: Condens. Matter, 27(18), 2015, 185302, 10.1088/0953-8984/27/18/185302.
Ling, Z.-P., Ang, K.-W., Thermal effects on the Raman phonon of few-layer phosphorene. APL Mater., 3(12), 2015, 126104, 10.1063/1.4937468.
Sugai, S., Ueda, T., Murase, K., Pressure dependence of the lattice vibration in the orthorhombic and rhombohedral structures of black phosphorus. J. Phys. Soc. Jpn. 50:10 (1981), 3356–3361, 10.1143/JPSJ.50.3356.
Li, S., Liu, X., Fan, X., Ni, Y., Miracle, J., Theodoropoulou, N., Sun, J., Chen, S., Lv, B., Yu, Q., New strategy for black phosphorus crystal growth through ternary clathrate. Cryst. Growth Des. 17:12 (2017), 6579–6585, 10.1021/acs.cgd.7b01239.
Nilges, T., Kersting, M., Pfeifer, T., A fast low-pressure transport route to large black phosphorus single crystals. J. Solid State Chem. 181:8 (2008), 1707–1711, 10.1016/j.jssc.2008.03.008.
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