[en] The cobalt-mediated radical polymerization (CMRP) of new ionic liquid monomers (ILMs), vinyl imidazolium functionalized with redox-active free radical 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO)VIm and its CMR copolymerization with vinyl imidazolium units functionalized with triethylene oxide (TEG)VIm produced a well-defined PILs (co)polymers. The controlled nature of (co)polymerization can be seen from the linear first-order kinetic plot, linear evolutions of the molar mass with total monomer conversion and the low polydispersity of the resulting (co)polymers. By combining the redox activity of (TEMPO)PVIm and remarkable ionic conductivity of (TEG)PVIm, outstanding rate capability performance was achieved with a remarkable capacity of 69 mAh g−1 at 60C. The obtained organic electrode can serve as sustainable electrodes in lithium ion batteries.
Research Center/Unit :
Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Belgium Center for Education and Research on Macromolecules (CERM), Belgium
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Aqil, Mohamed ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium > University Mohammed Premier, LCAE-URAC 18, Oujda, Morocco > Mohammed VI Polytechnic University, Materials Science and Nano-engineering, Hay Moulay Rachid, Ben Guerir, Morocco
Aqil, Abdelhafid ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Ouhib, Farid; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
El Idrissi, Abdelrahman; Univeristy Mohammed Premier, LCAE-URAC 18, Oujda, Morocco
Dahbi, Mouad; Mohammed VI Polytechnic University, Materials Science and Nano-engineering, Hay Moulay Rachid, Ben Guerir, Morocco
Detrembleur, Christophe ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Jérôme, Christine ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Language :
English
Title :
Nitroxide TEMPO-containing PILs: kinetics study and electrochemical characterizations
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