Room-Temperature Inter-Dot Coherent Dynamics in Multilayer Quantum Dot Materials

[en] The full blossoming of quantum technologies requires the availability of easy-to-prepare materials where quantum coherences can be effectively initiated, controlled, and exploited, preferably at ambient conditions. Solid-state multilayers of colloidally grown quantum dots (QDs) are highly promising for this task because of the possibility of assembling networks of electronically coupled QDs through the modulation of sizes, inter-dot linkers, and distances. To usefully probe coherence in these materials, the dynamical characterization of their collective quantum mechanically coupled states is needed. Here, we explore by two-dimensional electronic spectroscopy the coherent dynamics of solid-state multilayers of electronically coupled colloidally grown CdSe QDs and complement it by detailed computations. The time evolution of a coherent superposition of states delocalized over more than one QD was captured at ambient conditions. We thus provide important evidence for inter-dot coherences in such solid-state materials, opening up new avenues for the effective application of these materials in quantum technologies.

Research Center/Unit :

MolSys - Molecular Systems - ULiège

Disciplines :

Physical, chemical, mathematical & earth Sciences: Multidisciplinary, general & others

Author, co-author :

Collini, Elisabetta

Gattuso, Hugo ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de chimie physique théorique

Kolodny, Yuval

Bolzonello, Luca

Volpato, Andrea

Fridman, Hanna T.

Yochelis, Shira

Mor, Morin

Dehnel, Johanna

Lifshitz, Efrat

More authors (3 more)

Language :

English

Title :

Room-Temperature Inter-Dot Coherent Dynamics in Multilayer Quantum Dot Materials

Publication date :

2020

Journal title :

Journal of Physical Chemistry. C, Nanomaterials and interfaces

ISSN :

1932-7447

eISSN :

1932-7455

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

https://doi.org/10.1021/acs.jpcc.0c05572

European Projects :

H2020 - 766563 - COPAC - Coherent Optical Parallel Computing

Name of the research project :

MONACOMP

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
EC - European Commission
European Union

Available on ORBi :

since 26 January 2021

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