Enzymatically-synthesized xylo-oligosaccharides laurate esters as surfactants of interest

Laurate ester; Lipase; Surfactant; Transesterification; Xylo-oligosaccharides; Oligosaccharides; Surface active agents; Degree of polymerization; Experimental parameters; Lipase-catalyzed synthesis; Reaction conditions; Reducing ends; Regio-selective; Surface-active property; Xylo- oligosaccharides; Esters

Abstract :

[en] Lipase-catalyzed synthesis of xylo-oligosaccharides esters from pure xylobiose, xylotriose and xylotetraose in the presence of vinyl laurate was investigated. The influence of different experimental parameters such as the loading of lipase, the reaction duration or the use of a co-solvent was studied and the reaction conditions were optimized with xylobiose. Under the best conditions, a regioselective esterification occurred to yield a monoester with the acyl chain at the OH-4 of the xylose unit at the non-reducing end. Surface-active properties of these pure xylo-oligosaccharides fatty esters have been evaluated. They display interesting surfactant activities that differ according to the degree of polymerization (DP) of the glycone moiety. © 2020

Disciplines :

Biochemistry, biophysics & molecular biology

Author, co-author :

Gerard, D.; Université de Reims Champagne Ardenne

Méline, T.; Université de Reims Champagne Ardenne, INRAE, FARE, UMR A 614, Chaire AFERE, Reims, 51686, France

Muzard, M.; Institut de Chimie Moléculaire de Reims, Université de Reims Champagne-Ardenne, CNRS UMR 7312, Reims Cedex51687, France

Plantier-Royon, R.

Deleu, Magali ^✱; Université de Liège - ULiège > Département GxABT > Chimie des agro-biosystèmes

Rémond, C. ^✱; Université de Reims Champagne Ardenne, INRAE, FARE, UMR A 614, Chaire AFERE, Reims, 51686, France

^✱ These authors have contributed equally to this work.

Language :

English

Title :

Enzymatically-synthesized xylo-oligosaccharides laurate esters as surfactants of interest

Publication date :

2020

Journal title :

Carbohydrate Research

ISSN :

0008-6215

eISSN :

1873-426X

Publisher :

Elsevier Ltd

Volume :

495

Pages :

108090

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

Interreg
FEDER - Fonds Européen de Développement Régional [BE]

Available on ORBi :

since 08 January 2021

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