[en] Aqueous all-polymer batteries (AqPBs) are foreseen as promising solutions for safe, sustainable, and high-performance energy storage applications. Nevertheless, their development is still challenging as it demands precise optimization of both electrodes and the electrolyte composition to be able to sustain a stable redox activity, while delivering an optimal voltage output. Herein, we report AqPBs based on a poly(imide) (PI) anode and poly(catechol) (PC) cathode that exhibit tunable cell voltage depending on the salt used in the aqueous electrolyte, i.e., 0.58, 0.74, 0.89, and 0.95 V, respectively, when Li+, Zn2+, Al3+, and Li+/H+ were utilized as charge carriers. The PI–PC full-cell delivers the best rate performance (a sub-second charge/discharge) and cycling stability (80% capacity retention over 1000 cycles at 5 A g−1) in Li+. Furthermore, a maximum energy/power density of 80.6 W h kganode+cathode−1/348 kW kganode+cathode−1 is achieved in Li+/H+, superior to most of the previously reported AqPBs.
Research Center/Unit :
CESAM - Complex and Entangled Systems from Atoms to Materials - ULiège Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Patil, Nagaraj; IMDEA Energy Institute, Electrochemical Processes Unit, Madrid, Spain
Mavrandonakis, Andreas; IMDEA Energy Institute, Electrochemical Processes Unit, Madrid, Spain
Jérôme, Christine ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Detrembleur, Christophe ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Casado, Nerea; University of the Basque Country, POLYMAT, Donostia/SanSebastian, Spain
Mecerreyes, David; University of the Basque Country, POLYMAT, Donostia/SanSebastian, > IKERBASQUE Basque Foundation for Science, Bilbao, Spain
Palma, Jesus; IMDEA Energy Institute, Electrochemical Processes Unit, Madrid, Spain
Marcilla, Rebeca Marcilla; IMDEA Energy Institute, Electrochemical Processes Unit, Madrid, Spain
Language :
English
Title :
High-performance all-organic aqueous batteries based on a poly(imide) anode and poly(catechol) cathode
Publication date :
07 January 2021
Journal title :
Journal of Materials Chemistry A
ISSN :
2050-7488
eISSN :
2050-7496
Publisher :
Royal Society of Chemistry, United Kingdom
Volume :
9
Issue :
1
Pages :
505-514
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique ERC - European Research Council Spanish Ministry of Science MINECO - Gobierno de Espana. Ministerio de Economia y Competitividad Spanish Comunidad de Madrid
