Preparation of poly-D,L-lactide based nanocomposites with polymer-grafted silica by melt blending: Study of molecular, morphological, and mechanical properties
aliphatic polyesters; poly-D,L-lactide; nanocomposites; melt blending; grafting from; grafting to
Abstract :
[en] Polylactide was first designed for the pharmaceutical and medical fields. Unfortunately,
polylactide, especially poly-D,L-lactide (PDLLA), presents too low mechanical properties for a
wide range of applications. The addition of silica nanoparticles should reinforce the mechanical
strength of PDLLA. In order to improve silica/polymer interactions, this study focused on the
preparation of polymer chain grafted silica using two grafting methods. The first strategy relied
upon the ring opening polymerization of D,L-lactide on initiating silica surface (i.e. “grafting
from”). The second approach considered a sol-gel synthesis process in presence of Si-OR
terminated polylactide chains to promote grafting of these chains on new silica particles (i.e.
“grafting to” method). Only “grafting from” silica successfully led to a nanoscale dispersion into
the polyester matrix for silica content up to 5 wt%. A 3 wt% content of this silica allowed improving
Young modulus of 106.0 % and ultimate tensile stress (UTS) of 63.7 % compared to the PDLLA
control.
Disciplines :
Chemistry Materials science & engineering Chemical engineering
Author, co-author :
Regibeau, Nicolas ; Université de Liège - ULiège > Département des sciences biomédicales et précliniques > Biochimie et physiologie générales, et biochimie humaine
Tilkin, Rémi ; Université de Liège - ULiège > Department of Chemical Engineering > Nanomaterials, Catalysis, Electrochemistry
Grandfils, Christian ; Université de Liège - ULiège > Département des sciences biomédicales et précliniques > Biochimie et physiologie générales, et biochimie humaine
Heinrichs, Benoît ; Université de Liège - ULiège > Department of Chemical Engineering > Génie chimique - Nanomatériaux et interfaces
Language :
English
Title :
Preparation of poly-D,L-lactide based nanocomposites with polymer-grafted silica by melt blending: Study of molecular, morphological, and mechanical properties
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