Quenching rattling modes in skutterudites with pressure

[en] A high-pressure study of the lattice dynamics in the filled skutterudite Eu0.84Fe4Sb12 was carried out by means of x-ray powder diffraction and nuclear inelastic scattering. The anharmonicity of particular phonon modes was characterized by mode and element specific Grüneisen parameters. The large anharmonicity of the rattling optical mode that is hybridized with the acoustical phonons at ambient pressure is reduced at high pressure as the phonon modes decouple. This result suggests that anharmonic coupling between acoustic and optical phonon modes plays a central role in the reduced thermal conductivity. © 2015 American Physical Society.

Disciplines :

Chemistry

Author, co-author :

Sergueev, I.; Deutsches Elektronen-Synchrotron, Hamburg, Germany

Glazyrin, K.; Deutsches Elektronen-Synchrotron, Hamburg, Germany

Kantor, I.; European Synchrotron Radiation Facility (ESRF), P.O. Box 220, Grenoble, France

McGuire, M. A.; Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, United States

Chumakov, A. I.; European Synchrotron Radiation Facility (ESRF), P.O. Box 220, Grenoble, France

Klobes, B.; Jülich Center for Neutron Science JCNS, Peter Grünberg Institut PGI, Forschungszentrum Jülich GmbH, Jülich, Germany

Sales, B. C.; Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN, United States

Hermann, Raphaël ; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)

Language :

English

Title :

Quenching rattling modes in skutterudites with pressure

Publication date :

2015

Journal title :

Physical Review. B, Condensed Matter and Materials Physics

ISSN :

1098-0121

eISSN :

1550-235X

Publisher :

American Physical Society

Volume :

Issue :

Peer reviewed :

Peer Reviewed verified by ORBi

Name of the research project :

DFG priority program SPP1386 “Nanostructured Thermoelectrics”; Helmholtz Association Grant No. VH NG-407

Funders :

DOE - United States. Department of Energy
DFG - Deutsche Forschungsgemeinschaft

Available on ORBi :

since 14 November 2020

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Bibliography

G. J. Snyder and E. S. Toberer, Nat. Mater. 7, 105 (2008). 1476-1122 10.1038/nmat2090
E. S. Toberer, L. L. Baranowski, and C. Dames, Annu. Rev. Mater. Res. 42, 179 (2012). ARMRCU 1531-7331 10.1146/annurev-matsci-070511-155040
C. J. Vineis, A. Shakouri, A. Majumdar, and M. G. Kanatzidis, Adv. Mater. 22, 3970 (2010). ADVMEW 0935-9648 10.1002/adma.201000839
G. A. Slack and V. G. Tsoukala, J. Appl. Phys. 76, 1665 (1994). JAPIAU 0021-8979 10.1063/1.357750
G. Slack, in CRC Handbook of Thermoelectrics, edited by D. Rowe (CRC Press, Boca Raton, FL, 1995).
B. C. Sales, D. Mandrus, and R. K. Williams, Science 272, 1325 (1996). SCIEAS 0036-8075 10.1126/science.272.5266.1325
B. C. Sales, D. Mandrus, B. C. Chakoumakos, V. Keppens, and J. R. Thompson, Phys. Rev. B 56, 15081 (1997). PRBMDO 0163-1829 10.1103/PhysRevB.56.15081
J. L. Cohn, G. S. Nolas, V. Fessatidis, T. H. Metcalf, and G. A. Slack, Phys. Rev. Lett. 82, 779 (1999). PRLTAO 0031-9007 10.1103/PhysRevLett.82.779
M. M. Koza, M. R. Johnson, R. Viennois, H. Mutka, L. Girard, and D. Ravot, Nat. Mater. 7, 805 (2008). 1476-1122 10.1038/nmat2260
H.-C. Wille, R. P. Hermann, I. Sergueev, O. Leupold, P. van der Linden, B. C. Sales, F. Grandjean, G. J. Long, R. Rüffer, and Yu. V. Shvyd'ko, Phys. Rev. B 76, 140301 (R) (2007). PRBMDO 1098-0121 10.1103/PhysRevB.76.140301
G. J. Long, R. P. Hermann, F. Grandjean, E. E. Alp, W. Sturhahn, C. E. Johnson, D. E. Brown, O. Leupold, and R. Rüffer, Phys. Rev. B 71, 140302 (2005). PRBMDO 1098-0121 10.1103/PhysRevB.71.140302
J. L. Feldman, D. J. Singh, I. I. Mazin, D. Mandrus, and B. C. Sales, Phys. Rev. B 61, R9209 (2000). PRBMDO 0163-1829 10.1103/PhysRevB.61.R9209
J. L. Feldman, P. Dai, T. Enck, B. C. Sales, D. Mandrus, and D. J. Singh, Phys. Rev. B 73, 014306 (2006). PRBMDO 1098-0121 10.1103/PhysRevB.73.014306
A. Yamakage and Y. Kuramoto, J. Phys. Soc. Jpn. 78, 064602 (2009). JUPSAU 0031-9015 10.1143/JPSJ.78.064602
K. Iwasa, M. Kohgi, H. Sugawara, and H. Sato, Physica B (Amsterdam) 378-380, 194 (2006). PHYBE3 0921-4526 10.1016/j.physb.2006.01.073
C. H. Lee, I. Hase, H. Sugawara, H. Yoshizawa, and H. Sato, J. Phys. Soc. Jpn. 75, 123602 (2006). JUPSAU 0031-9015 10.1143/JPSJ.75.123602
W. Li and N. Mingo, Phys. Rev. B 89, 184304 (2014). PRBMDO 1098-0121 10.1103/PhysRevB.89.184304
M. M. Koza, A. Leithe-Jasper, H. Rosner, W. Schnelle, H. Mutka, M. R. Johnson, M. Krisch, L. Capogna, and Y. Grin, Phys. Rev. B 84, 014306 (2011). PRBMDO 1098-0121 10.1103/PhysRevB.84.014306
M. Christensen, A. B. Abrahamsen, N. B. Christensen, F. Juranyi, N. H. Andersen, K. Lefmann, J. Andreasson, C. R. H. Bahl, and B. B. Iversen, Nat. Mater. 7, 811 (2008). 1476-1122 10.1038/nmat2273
N. Bernstein, J. L. Feldman, and D. J. Singh, Phys. Rev. B 81, 134301 (2010). PRBMDO 1098-0121 10.1103/PhysRevB.81.134301
J. S. Tse, S. Desgreniers, Z.-q. Li, M. R. Ferguson, and Y. Kawazoe, Phys. Rev. Lett. 89, 195507 (2002). PRLTAO 0031-9007 10.1103/PhysRevLett.89.195507
T. Kume, H. Fukuoka, T. Koda, S. Sasaki, H. Shimizu, and S. Yamanaka, Phys. Rev. Lett. 90, 155503 (2003). PRLTAO 0031-9007 10.1103/PhysRevLett.90.155503
T. Kume, S. Ohno, S. Sasaki, H. Shimizu, Y. Ohishi, N. L. Okamoto, K. Kishida, K. Tanaka, and H. Inui, J. Appl. Phys. 107, 013517 (2010). JAPIAU 0021-8979 10.1063/1.3276153
A. Chumakov and R. Rüffer, Hyperfine Interact. 113, 59 (1998). 0304-3834 10.1023/A:1012659229533
R. Rüffer and A. I. Chumakov, Hyperfine Interact. 97-98, 589 (1996). 0304-3834 10.1007/BF02150199
H.-P. Liermann, W. Morgenroth, A. Ehnes, A. Berghäuser, B. Winkler, H. Franz, and E. Weckert, J. Phys.: Conf. Ser. 215, 012029 (2010). 1742-6596 10.1088/1742-6596/215/1/012029
V. Kohn and A. Chumakov, Hyperfine Interact. 125, 205 (2000). 0304-3834 10.1023/A:1012689705503
A. Chumakov and W. Sturhahn, Hyperfine Interact. 123-124, 781 (1999). 0304-3834 10.1023/A:1017052730094
A. Möchel, I. Sergueev, H.-C. Wille, J. Voigt, M. Prager, M. B. Stone, B. C. Sales, Z. Guguchia, A. Shengelaya, V. Keppens, Phys. Rev. B 84, 184306 (2011). PRBMDO 1098-0121 10.1103/PhysRevB.84.184306
S. Tsutsui, J. Umemura, H. Kobayashi, T. Tazaki, S. Nasu, Y. Kobayashi, Y. Yoda, H. Onodera, H. Sugawara, T. Matsuda, Hyperfine Interact. 168, 1073 (2006). HYINDN 0304-3843 10.1007/s10751-006-9404-4
F. Birch, Phys. Rev. 71, 809 (1947). PHRVAO 0031-899X 10.1103/PhysRev.71.809
O. Leupold, A. Chumakov, E. Alp, W. Sturhahn, and A. Baron, Hyperfine Interact. 123-124, 611 (1999). 0304-3834 10.1023/A:1017000713255
F. Grandjean and G. Long, in Mössbauer Spectroscopy Applied to Inorganic Chemistry, edited by G. Long and F. Grandjean, Springer Series in Modern Inorganic Chemistry Vol. 3 (Springer, New York, 1989), pp. 513-597.
I. Sergueev, R. P. Hermann, D. Bessas, U. Pelzer, M. Angst, W. Schweika, M. A. McGuire, A. S. Sefat, B. C. Sales, D. Mandrus, Phys. Rev. B 87, 064302 (2013). PRBMDO 1098-0121 10.1103/PhysRevB.87.064302
See Supplemental Material at http://link.aps.org/supplemental/10.1103/PhysRevB.91.224304 for the shifts of the peak positions at high pressure and for the mode specific Grüneisen parameters.
J. L. Feldman, D. J. Singh, and N. Bernstein, Phys. Rev. B 89, 224304 (2014). PRBMDO 1098-0121 10.1103/PhysRevB.89.224304
F. Birch, J. Geophys. Res.: Solid Earth 83, 1257 (1978). JGREA2 0148-0227 10.1029/JB083iB03p01257
B. J. Maier, A.-M. Welsch, B. Mihailova, R. J. Angel, J. Zhao, C. Paulmann, J. M. Engel, W. G. Marshall, M. Gospodinov, D. Petrova, Phys. Rev. B 83, 134106 (2011). PRBMDO 1098-0121 10.1103/PhysRevB.83.134106
W. Liu, Q. Jie, Q. Li, Z. Chen, and B. Li, Physica B (Amsterdam) 406, 52 (2011). PHYBE3 0921-4526 10.1016/j.physb.2010.10.011
M. Jacobsen, W. Liu, and B. Li, J. Phys. Chem. Solids 75, 1017 (2014). JPCSAW 0022-3697 10.1016/j.jpcs.2014.04.012

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