Electronic excitation and optical cross sections of methylamine and ethylamine in the UV-VUV spectral region

Absorption spectroscopy; Electron energy loss spectroscopy; Electron transitions; Molecular vibrations; Oscillators (electronic); Photons; Synchrotron radiation; Electronic excitations; Amines

Abstract :

[en] The high resolution ultraviolet (UV)-vacuum ultraviolet (VUV) photon absorption spectra of methylamine and ethylamine was discussed using synchrotron radiation. It was found that in methylamine, the energies of the absorption bands were centered at 5.7, 7.2 and 8.7 eV. The optical oscillator strengths of both molecules for the 5-14 eV energy range were also reported.

Disciplines :

Chemistry

Author, co-author :

Hubin-Franskin, Marie-Jeanne ; Université de Liège > Département de chimie (sciences) > Laboratoire de spectrométrie de masse (L.S.M.)

Delwiche, Jacques ; Université de Liège > Relations académiques et scientifiques (Sciences)

Giuliani, A.; Laboratoire de Spectroscopie d'Électrons Diffusés, Université de Liège, Institut de Chimie-Bât. B6c, B-4000 Liège, Belgium

Ska, M.-P.; Laboratoire de Spectroscopie d'Électrons Diffusés, Université de Liège, Institut de Chimie-Bât. B6c, B-4000 Liège, Belgium

Motte-Tollet, Françoise ; Université de Liège - ULiège > Direction administrative de la faculté des sciences

Walker, I. C.; Department of Chemistry, Heriot-Watt University, Riccarton, Edinburgh, United Kingdom

Mason, N. J.; Department of Physics and Astronomy, University College London, Gower Street, London WCIE 6BT, United Kingdom

Gingell, J. M.; Department of Physics and Astronomy, University College London, Gower Street, London WCIE 6BT, United Kingdom

Jones, N. C.; Department of Physics and Astronomy, University College London, Gower Street, London WCIE 6BT, United Kingdom

Language :

English

Title :

Electronic excitation and optical cross sections of methylamine and ethylamine in the UV-VUV spectral region

Publication date :

2002

Journal title :

Journal of Chemical Physics

ISSN :

0021-9606

eISSN :

1089-7690

Publisher :

American Institute of Physics, New York, United States - New York

Volume :

116

Issue :

Pages :

9261-9268

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 19 October 2020

Statistics

Number of views

73 (12 by ULiège)

Number of downloads

27 (4 by ULiège)

More statistics

Scopus citations^®

Scopus citations^®
without self-citations

OpenCitations

OpenAlex citations

See more details

publications

supporting

mentioning

contrasting

Smart Citations

Citing PublicationsSupportingMentioningContrasting

View Citations

See how this article has been cited at scite.ai

scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.

Bibliography

Schade G.W., Crutzen P.J. J. Atmos. Chem. 1995, 22:319.
Collin J.E., Hubin-Franskin M.-J., Hyatt D. Bull. Soc. R. Sci. Liège 1966, 11-12:744.
Bull. Soc. R. Sci. Liège 1967, 5-6:318.
Hubin-Franskin M.-J., Collin J.E. Bull. Soc. R. Sci. Liège 1971, 9-10:502.
Hwang S.Y., Kong A.C.F., Schmidt L.D. J. Phys. Chem. 1989, 93:8327.
Jhanwar B.L., Meath W.J., Mac Donald J.C.F. Radiat. Res. 1986, 106:288.
Emeléus J., Jolley L.J. J. Chem. Soc. 1935:1612.
Henry V., Lasareff W. J. Chem. Phys. 1935, 32:353.
Tannenbaum E., Coffin E.M., Harrison A.J. J. Chem. Phys. 1953, 21:311.
Taylor D.P., Bernstein E.R. J. Chem. Phys. 1995, 103:10453.
Hubin-Franskin M.-J., Delwiche J., Tollet F., Furlan M., Collin J.E. J. Phys. B 1988, 21:189.
Wight G.R., Brion C.E. J. Electron Spectrosc. Relat. Phenom. 1974, 4:25.
Sodhi R.N.S., Brion C.E. J. Electron Spectrosc. Relat. Phenom. 1985, 36:187.
Burton G.R., Chan W.F., Cooper G., Brion C.E., Kumar A., Meath W.J. Can. J. Chem. 1994, 72:529.
Mason N.J., Gingell J.M., Davies J.A., Zhao H., Walker I.C., Siggel M.R.F. J. Phys. B 1996, 29:3075.
Chan W.F., Cooper G., Brion C.E. Phys. Rev. A 1991, 44:186.
Motte-Tollet F., Heinesch J., Gingell J.M., Mason N.J. J. Chem. Phys. 1997, 106:5990.
Johnstone W.M., Newell W.R. J. Phys. B 1991, 24:473.
Celotta R.J., Huebner R.H. Electron Spectroscopy "Theory, Techniques and Applications" , edited by C. R. Brundle and A. D. Baker (Academic, New York); 1979, 3:41.
Tsuboi M., Hirakawa A.Y., Kawashima H.J. J. Mol. Spectrosc. 1969, 29:216.
Waschewsky G.C.G., Kitchen D.C., Browning P.W., Butler L.J. J. Phys. Chem. 1995, 99:2635.
Kassab E., Gleghorn J.T., Evleth E.M. J. Am. Chem. Soc. 1983, 105:1746.
Kassab E., Evleth E.M. The Role of Rydberg States in Spectroscopy and Photochemistry , edited by C. Sandorfi (Kluwer Academic, New York); 1999, 231.
Gray A.P., Lord R.C. J. Chem. Phys. 1957, 26:690.
Wolf H., Ludwig H. Ber. Bunsenges. Phys. Chem. 1967, 71:1107.
Zeroka D., Jensen J.O., Samuels A.C. J. Mol. Struct.: THEOCHEM 1999, 465:119.
Takashashi M., Watanabe I., Ikeda S. J. Electron Spectrosc. Relat. Phenom. 1985, 37:275.
Kimura K., Katsumata S., Achiba Y., Yamazaki T., Iwata S. Hand-book of HeI Photoelectron Spectra of Fundamental Organic Molecules, Japan Scientific Soc., Tokyo, Halsted, New York; 1980.

Similar publications

Sorry the service is unavailable at the moment. Please try again later.

Name	Provider / Domaine	Expiration	Description
JSESSIONID	Oracle Corporation www.uliege.be	Session	General purpose platform session cookie, used by sites written in JSP. Usually used to maintain an anonymous user session by the server.
CookieScriptConsent	CookieScript .uliege.be	1 year	This cookie is used by Cookie-Script.com service to remember visitor cookie consent preferences. It is necessary for Cookie-Script.com cookie banner to work properly.

Name	Provider / Domaine	Expiration	Description
_pk_id	InnoCraft Ltd .uliege.be	1 year	Used to store a few details about the user such as the unique visitor ID
_pk_ses	InnoCraft Ltd .uliege.be	30 minutes	Short lived cookies used to temporarily store data for the visit
_pk_ref	InnoCraft Ltd .uliege.be	6 months	Used to store the attribution information, the referrer initially used to visit the website