[en] The present study elucidates the role of surface oxygen functional groups on the electrochemical behavior of porous carbons when used as anodes for Li-ion batteries. To achieve this objective, a carbon xerogel (CX) obtained by pyrolysis of a resorcinol-formaldehyde gel was modified by different post-synthesis treatments in order to modulate its surface chemistry while maintaining its external surface constant. Various surface modifications were obtained by oxidation in air, in- situ polymerization of dopamine and, finally, by grafting of a polyethylene oxide layer on the polydopamine coating. While oxidation in air did not affect the pore texture of the CX, modifications by coating techniques substantially decreased the micropore fraction. Detailed electrochemical characterizations of the materials processed as electrodes were performed by capacitance measurements and galvanostatic cycling. Surface chemistry results, by X-ray photoelectron spectroscopy, show that the accessibility and the capacity increase when carbonyl (R-C=O) groups are formed on the CX, but not with oxides and hydroxyls. The amount of surface carbonyls, and in particular aldehyde (O=CH) groups, is found as the key parameter since it is directly correlated with the modified CX electrochemical behavior. Overall, the explored surface coatings tend to reduce the micropore volume and add mainly hydroxyl functional groups but hardly change the Li+ insertion/de-insertion capacities, while oxidation in air adds carbonyl groups, increasing the Li+ ions storage capacity thanks to an improved accessibility to the carbon network, which is not caused by any textural change
Research center :
Center for Education and Research on Macromolecules (CERM) CESAM - Complex and Entangled Systems from Atoms to Materials - ULiège Chemical engineering - Nanomaterials Catalysis Electrochemistry
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Piedboeuf, Marie-Laure ; University of Liège (ULiège), Department of Chemical Engineering – Nanomaterials, Catalysis, Electrochemistry
Job, Nathalie ; University of Liège (ULiège), Department of Chemical Engineering – Nanomaterials, Catalysis, Electrochemistry
Aqil, Abdelhafid ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Busby, Yan; University of Namur, (UNamur) Institute of Structured Matter, Belgium > French-German Research Institute of Saint-Louis, Nanomatériaux pour les Systèmes Sous Sollicitations Extrêmes, France
Fierro, Vanessa; University of Lorraine, Institut Jean Lamour, France
Celzard, Alain; University of Lorraine, Institut Jean Lamour, France
Detrembleur, Christophe ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Léonard, Alexandre ; University of Liège (ULiège), Department of Chemical Engineering – Nanomaterials, Catalysis, Electrochemistry
Language :
English
Title :
Understanding the influence of surface oxygen groups on the electrochemical behavior of porous carbons as anodes for lithium-ion batteries
Publication date :
21 July 2020
Journal title :
ACS Applied Materials and Interfaces
ISSN :
1944-8244
eISSN :
1944-8252
Publisher :
American Chemical Society, United States - District of Columbia
Volume :
12
Pages :
36054-36065
Peer reviewed :
Peer Reviewed verified by ORBi
Name of the research project :
BATWAL project; Programme des fonds Spéciaux pour la Recherche, Promotee
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE] FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture [BE] Région wallonne [BE] RFCS - European Commission. Research Fund for Coal and Steel [BE] ULiège - Université de Liège [BE]
Tarascon, J.-M.; Armand, M. Issues and Challenges Facing Rechargeable Lithium Batteries. Nature 2001, 414, 359-367, 10.1038/35104644
Aurbach, D.; Zaban, A.; Ein-Eli, Y.; Weissman, I.; Chusid, O.; Markovsky, B.; Levi, M.; Levi, E.; Schechter, A.; Granot, E. Recent Studies on the Correlation Between Surface Chemistry, Morphology, Three-Dimensional Structures and Performance of Li and Li-C Intercalation Anodes in Several Important Electrolyte Systems. J. Power Sources 1997, 68, 91-98, 10.1016/S0378-7753(97)02575-5
Collins, J.; Gourdin, G.; Foster, M.; Qu, D. Carbon Surface Functionalities and SEI Formation During Li Intercalation. Carbon 2015, 92, 193-244, 10.1016/j.carbon.2015.04.007
Fujimoto, H.; Tokumitsu, K.; Mabuchi, A.; Chinnasamy, N.; Kasuh, T. The Anode Performance of the Hard Carbon for the Lithium Ion Battery Derived from the Oxygen-Containing Aromatic Precursors. J. Power Sources 2010, 195, 7452-7456, 10.1016/j.jpowsour.2010.05.041
Ni, J.; Huang, Y.; Gao, L. A High-Performance Hard Carbon for Li-Ion Batteries and Supercapacitors Application. J. Power Sources 2013, 223, 306-311, 10.1016/j.jpowsour.2012.09.047
Aurbach, D.; Markovsky, B.; Weissman, I.; Levi, E.; Ein-Eli, Y. On the Correlation Between Surface Chemistry and Performance of Graphite Negative Electrodes for Li Ion Batteries. Electrochim. Acta 1999, 45, 67-86, 10.1016/S0013-4686(99)00194-2
Tran, C.; Kafle, J.; Yang, X.-Q.; Qu, D. Increased Discharge Capacity of a Li-Air Activated Carbon Cathode Produced by Preventing Carbon Surface Passivation. Carbon 2011, 49, 1266-1271, 10.1016/j.carbon.2010.11.045
Anjos, D. M.; McDonough, J. K.; Perre, E.; Brown, G. M.; Overbury, S. H.; Gogotsi, Y.; Presser, V. Pseudocapacitance and Performance Stability of Quinone-Coated Carbon Onions. Nano Energy 2013, 2, 702-712, 10.1016/j.nanoen.2013.08.003
Ventosa, E.; Xia, W.; Klink, S.; La Mantia, F.; Muhler, M.; Schuhmann, W. Influence of Surface Functional Groups on Lithium Ion Intercalation of Carbon Cloth. Electrochim. Acta 2012, 65, 22-29, 10.1016/j.electacta.2011.12.128
Klink, S.; Ventosa, E.; Xia, W.; La Mantia, F.; Muhler, M.; Schuhmann, W. Tailoring of CNT Surface Oxygen Groups by Gas-Phase Oxidation and its Implications for Lithium Ion Batteries. Electrochem. Commun. 2012, 15, 10-13, 10.1016/j.elecom.2011.11.012
Mangun, C. L.; Benak, K. R.; Daley, M. A.; Economy, J. Oxidation of Activated Carbon Fibers: Effect on Pore Size, Surface Chemistry, and Adsorption Properties. Chem. Mater. 1999, 11, 3476-3483, 10.1021/cm990123m
Lopez-Ramon, M. V.; Stoeckli, F.; Moreno-Castilla, C.; Carrasco-Marin, F. On the Characterization of Acidic and Basic Surface Sites on Carbons by Various Techniques. Carbon 1999, 37, 1215-1221, 10.1016/S0008-6223(98)00317-0
Jaramillo, J.; álvarez, P. M.; Gómez-Serrano, V. Oxidation of Activated Carbon by Dry and Wet Methods. Fuel Process. Technol. 2010, 91, 1768-1775, 10.1016/j.fuproc.2010.07.018
da Silva Pires, M.; Haye, E.; Zubiaur, A.; Job, N.; Pireaux, J. J.; Houssiau, L.; Busby, Y. Defective Pt-Ni/Graphene Nanomaterials by Simultaneous or Sequential Treatments of Organometallic Precursors by Low-Pressure Oxygen Plasma. Plasma Process. Polym. 2019, 16, 1800203, 10.1002/ppap.201800203
Haye, E.; Busby, Y.; da Silva Pires, M.; Bocchese, F.; Job, N.; Houssiau, L.; Pireaux, J.-J. Low-Pressure Plasma Synthesis of Ni/C Nanocatalysts from Solid Precursors: Influence of the Plasma Chemistry on the Morphology and Chemical State. ACS Appl. Nano Mater. 2018, 1, 265-273, 10.1021/acsanm.7b00125
Mager, N.; Meyer, N.; Léonard, A. F.; Job, N.; Devillers, M.; Hermans, S. Functionalization of Carbon Xerogels for the Preparation of Palladium Supported Catalysts Applied in Sugar Transformations. Appl. Catal. B Environ. 2014, 148-149, 424-435, 10.1016/j.apcatb.2013.11.028
Boehm, H. P. Surface Oxides on Carbon and Their Analysis: A Critical Assessment. Carbon 2002, 40, 145-149, 10.1016/S0008-6223(01)00165-8
Fraga, M. A.; Jordão, E.; Mendes, M. J.; Freitas, M. M. A.; Faria, J. L.; Figueiredo, J. L. Properties of Carbon-Supported Platinum Catalysts: Role of Carbon Surface Sites. J. Catal. 2002, 209, 355-364, 10.1006/jcat.2002.3637
Gheorghiu, C. C.; Pérez-Cadenas, M.; Carmen Román-Martínez, M.; Salinas-Martínez de Lecea, C.; Job, N. Immobilization of Homogeneous Catalysts in Nanostructured Carbon Xerogels. Stud. Surf. Sci. Catal. 2010, 175, 647-651, 10.1016/S0167-2991(10)75128-4
Samant, P. V.; Gonçalves, F.; Freitas, M. M. A.; Pereira, M. F. R.; Figueiredo, J. L. Surface Activation of a Polymer Based Carbon. Carbon 2004, 42, 1321-1325, 10.1016/j.carbon.2004.01.034
Lee, H.; Dellatore, S. M.; Miller, W. M.; Messersmith, P. B. Mussel-Inspired Surface Chemistry for Multifunctional Coatings. Science 2007, 318, 426-430, 10.1126/science.1147241
Zhao, F.-Y.; Ji, Y.-L.; Weng, X.-D.; Mi, Y.-F.; Ye, C.-C.; An, Q.-F.; Gao, C.-J. High-Flux Positively Charged Nanocomposite Nanofiltration Membranes Filled with Poly(dopamine) Modified Multiwall Carbon Nanotubes. ACS Appl. Mater. Interfaces 2016, 8, 6693-6700, 10.1021/acsami.6b00394
Park, S.-H.; Kim, H. J.; Lee, J.; Jeong, Y. K.; Choi, J. W.; Lee, H. Mussel-Inspired Polydopamine Coating for Enhanced Thermal Stability and Rate Performance of Graphite Anodes in Li-Ion Batteries. ACS Appl. Mater. Interfaces 2016, 8, 13973-13981, 10.1021/acsami.6b04109
Aqil, A.; Serwas, H.; Delplancke, J. L.; Jérôme, R.; Jérôme, C.; Canet, L. Preparation of Stable Suspensions of Gold Nanoparticles in Water by Sonoelectrochemistry. Ultrason. Sonochem. 2008, 15, 1055-1061, 10.1016/j.ultsonch.2008.04.004
Assegie, A. A.; Cheng, J.-H.; Kuo, L.-M.; Su, W.-N.; Hwang, B.-J. Polyethylene Oxide Film Coating Enhances Lithium Cycling Efficiency of an Anode-Free Lithium-Metal Battery. Nanoscale 2018, 10, 6125-6138, 10.1039/c7nr09058g
Piedboeuf, M.-L. C.; Léonard, A. F.; Deschamps, F. L.; Job, N. Carbon Xerogels as Model Materials: Toward a Relationship Between Pore Texture and Electrochemical Behavior as Anodes for Lithium-Ion Batteries. J. Mater. Sci. 2016, 51, 4358-4370, 10.1007/s10853-016-9748-3
Léonard, A. F.; Job, N. Safe and Green Li-Ion Batteries Based on LiFePO4and Li4Ti5O12Sprayed as Aqueous Slurries with Xanthan Gum as Common Binder. Mater. Today Energy 2019, 12, 168-178, 10.1016/j.mtener.2019.01.008
Rey-Raap, N.; Piedboeuf, M.-L. C.; Arenillas, A.; Menéndez, J. A.; Léonard, A. F.; Job, N. Aqueous and Organic Inks of Carbon Xerogels as Models for Studying the Role of Porosity in Lithium-Ion Battery Electrodes. Mater. Des. 2016, 109, 282-288, 10.1016/j.matdes.2016.07.007
Job, N.; Pirard, R.; Marien, J.; Pirard, J.-P. Porous Carbon Xerogels with Texture Tailored by pH Control during Sol-Gel Process. Carbon 2004, 42, 619-628, 10.1016/j.carbon.2003.12.072
Piedboeuf, M.-L. C.; Léonard, A. F.; Traina, K.; Job, N. Influence of the Textural Parameters of Resorcinol-Formaldehyde Dry Polymers and Carbon Xerogels on Particle Sizes upon Mechanical Milling. Colloid. Surface. Physicochem. Eng. Aspect. 2015, 471, 124-132, 10.1016/j.colsurfa.2015.02.014
Yu, B.; Wang, X.; Qian, X.; Xing, W.; Yang, H.; Ma, L.; Lin, Y.; Jiang, S.; Song, L.; Hu, Y.; Lo, S. Functionalized Graphene Oxide/Phosphoramide Oligomer Hybrids Flame Retardant Prepared via in situ Polymerization for Improving the Fire Safety of Polypropylene. RSC Adv. 2014, 4, 31782-31794, 10.1039/c3ra45945d
Liu, T.; Kim, K. C.; Lee, B.; Chen, Z.; Noda, S.; Jang, S. S.; Lee, S. W. Self-Polymerized Dopamine as an Organic Cathode for Li-and Na-Ion Batteries. Energy Environ. Sci. 2017, 10, 205-215, 10.1039/c6ee02641a
Ruiz-Taylor, L. A.; Martin, T. L.; Zaugg, F. G.; Witte, K.; Indermuhle, P.; Nock, S.; Wagner, P. Monolayers of Derivatized Poly(L-lysine)-grafted Poly(ethylene glycol) on Metal Oxides as a Class of Biomolecular Interfaces. Proc. Natl. Acad. Sci. U.S.A. 2001, 98, 852-857, 10.1073/pnas.98.3.852
Piedboeuf, M.-L. C.; Léonard, A. F.; Reichenauer, G.; Balzer, C.; Job, N. How Do the Micropores of Carbon Xerogels Influence their Electrochemical Behavior as Anodes for Lithium-Ion Batteries?. Microporous Mesoporous Mater. 2019, 275, 278-287, 10.1016/j.micromeso.2018.08.029
Rouquerol, J.; Llewellyn, P.; Rouquerol, F. Is the BET Equation Applicable to Microporous Adsorbents?. Stud. Surf. Sci. Catal. 2007, 160, 49-56, 10.1016/S0167-2991(07)80008-5
Dubinin, M. M. Adsorption in Micropores. J. Colloid Interface Sci. 1967, 23, 487-499, 10.1016/0021-9797(67)90195-6
Jagiello, J.; Ania, C.; Parra, J. B.; Cook, C. Dual Gas Analysis of Microporous Carbons using 2D-NLDFT Heterogeneous Pore Surface Model and Combined Adsorption Data of N2and CO2. Carbon 2015, 91, 330-337, 10.1016/j.carbon.2015.05.004
Jagiello, J.; Kenvin, J.; Celzard, A.; Fierro, V. Enhanced Resolution of Ultra Micropore Size Determination of Biochars and Activated Carbons by Dual Gas Analysis using N2and CO2with 2D-NLDFT Adsorption Models. Carbon 2019, 144, 206-215, 10.1016/j.carbon.2018.12.028
Washburn, E. W. Note on a Method of Determining the Distribution of Pore Sizes in a Porous Material. Proc. Natl. Acad. Sci. U.S.A. 1921, 7, 115-116, 10.1073/pnas.7.4.115
Thommes, M.; Kaneko, K.; Neimark, A. V.; Olivier, J. P.; Rodriguez-Reinoso, F.; Rouquerol, J.; Sing, K. S. W. Physisorption of Gases, with Special Reference to the Evaluation of Surface Area and Pore Size Distribution (IUPAC Technical Report). Pure Appl. Chem. 2015, 87, 1051-1069, 10.1515/pac-2014-1117
Chen, L.; Deng, J.; Hong, S.; Lian, H. Rapid, Tunable Synthesis of Porous Carbon Xerogels with Expanded Graphite and their Application as Anodes for Li-Ion Batteries. J. Colloid Interface Sci. 2020, 565, 368-377, 10.1016/j.jcis.2020.01.048
Fu, R.; Chang, Z.; Shen, C.; Guo, H.; Huang, H.; Xia, Y.; Liu, Z. Surface Oxo-Functionalized Hard Carbon Spheres Enabled Superior High-Rate Capability and Long-Cycle Stability for Li-Ion Storage. Electrochim. Acta 2018, 260, 430-438, 10.1016/j.electacta.2017.12.043
Lee, S. W.; Yabuuchi, N.; Gallant, B. M.; Chen, S.; Kim, B.-S.; Hammond, P. T.; Shao-Horn, Y. High-Power Lithium Batteries from Functionalized Carbon-Nanotube Electrodes. Nat. Nanotechnol. 2010, 5, 531-537, 10.1038/NNANO.2010.116
Kuo, S.-L.; Liu, W.-R.; Kuo, C.-P.; Wu, N.-L.; Wu, H.-C. Lithium Storage in Reduced Graphene Oxides. J. Power Sources 2013, 244, 552-556, 10.1016/j.jpowsour.2013.01.186