Synthesis and characterization of magnetic perovskites La1-xSrxMnO3: Green catalyst for oxidation of olefins in aqueous medium

Hasnaoui, Ali; Fkhar, Lahcen; Nayad, Abdallah; Mahmoud, Abdelfattah; Boschini, Frédéric; Mounkachi, Omar; Hamedoun, Mohamed; Benyoussef, Abdelilah; firdoussi], Larbi El; Ali], Mustapha Ait

doi:10.1016/j.inoche.2020.107892

Article (Scientific journals)

Synthesis and characterization of magnetic perovskites La1-xSrxMnO3: Green catalyst for oxidation of olefins in aqueous medium

Hasnaoui, Ali; Fkhar, Lahcen; Nayad, Abdallah et al.

2020 • In Inorganic Chemistry Communications, p. 107892

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/246606

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10.1016/j.inoche.2020.107892

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Keywords :

Catalysis; Sol-gel; Oxidation; Water solvent; Olefins

Abstract :

[en] The main goal of this work is the preparation of magnetic perovskites La1-xSrxMnO3 (x= 0, 0.2 and 0.4) with a modified sol-gel process and the assessment of their catalytic activity in the oxidation of styrene in neat water (aqueous medium). The structural properties of LaMnO3, La0.8Sr0.2MnO3 and La0.6Sr0.4MnO3 were characterized using the X-ray Diffraction and infrared techniques. Microstructural features of the catalyst were confirmed by the Scanning Electron Microscopy. The sample La0.6Sr0.4MnO3 has proven a good catalytic activity in the oxidation of styrene after different optimization steps. The catalyst has shown a good recyclability after four cycles. The optimized parameters of the reaction procedure were applied successfully in the oxidation of other simple olefins.

Disciplines :

Materials science & engineering

Author, co-author :

Hasnaoui, Ali

Fkhar, Lahcen

Nayad, Abdallah

Mahmoud, Abdelfattah ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT

Boschini, Frédéric ; Université de Liège - ULiège > Plateforme APTIS

Mounkachi, Omar

Hamedoun, Mohamed

Benyoussef, Abdelilah

firdoussi], Larbi El

Ali], Mustapha Ait

Language :

English

Title :

Synthesis and characterization of magnetic perovskites La1-xSrxMnO3: Green catalyst for oxidation of olefins in aqueous medium

Publication date :

19 March 2020

Journal title :

Inorganic Chemistry Communications

ISSN :

1387-7003

Publisher :

Elsevier, Netherlands

Pages :

107892

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science/article/pii/S1387700320302203

Available on ORBi :

since 13 April 2020

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