Double ionization; Dissociation; NH3; Kinetic energy distribution; Appearance energies; Electron impact
Abstract :
[en] The double ionization and dissociation of NH3 into the doubly ionized fragment N2+ is investigated by electron impact. Two double ionization energies of NH3 are directly measured at 34.8+/-0.2 eV and 39.4+/-0.5 eV. A third critical energy observed at 66 eV is assigned to a (NH3)2+ state whose ionization energy is at 61 eV. Two appearance energies are observed for the N2+ ion at 65.9+/-1.7 eV and 74.3+/-2.6 eV. The translational energy distribution of N2+ is shown to be essentially thermal. The former onset is ascribed to the dissociation of the 61 eV state of (NH3)2+, the latter originates from the doubly ionized (NH3)2+ state at 70 eV.
Research Center/Unit :
Laboratoire de Dynamique Moléculaire
Disciplines :
Chemistry
Author, co-author :
Locht, Robert ; Université de Liège - ULiège > Département de Chimie (Faculté des sciences) > Laboratoire de Dynamique Moléculaire (Sciences)
Momigny, J.
Language :
English
Title :
The double Ionization of Ammonia. Its Dissociation into the Doubly Ionized Fragment N2+.
Alternative titles :
[fr] L'ionisation double de l'Ammoniac. Sa dissociation donnant le fragment doublement ionisé N2+.
Publication date :
1987
Journal title :
Chemical Physics Letters
ISSN :
0009-2614
Publisher :
Elsevier Science, Amsterdam, Netherlands
Volume :
138
Issue :
5
Pages :
391-396
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
FRFC, ARC
Commentary :
- Printed version of reprint available on request
- Version imprimée du tiré-à-part disponible sur demande
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Bibliography
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