Effect of Different Parameters on Composition of Volatile Components of Leaf, Stem and Seed from Algerian Bupleurum fruticosum L. Extracted by Hydrodistillation and Headspace Solid-Phase Microextraction
Bupleurum fruticosumL; volatile composition; hydrodistillation; solid phase microextraction; gas chromatography; mass spectrometry
Abstract :
[en] The present study describes the effect of physical parameters of plant and fiber coating on the qualitative and quantitative volatile profile of Bupleurum fruticosum L., (leave, stem and seed) from Yama Gouraya Algerian Park using the headspace solid-phase microextraction (HS-SPME) coupled with gas chromatography-mass spectrometry (GC/MS). The HS-SPME-GC/MS analysis showed a significant variation of the volatile composition according some parameters as the type of fiber coating polydimethyl siloxane (PDMS) and polydimethyl siloxane/divinylbenzene (PDMS-DVB), particle size (dp), and the mass (m) used. Results demonstrated that HS-SPME recoveries are strongly conditioned by the polarity and volatility of analytes were investigated, and by the composition and physical state of the vegetable matrix, characteristics which, in their turn, condition the headspace composition. According to the particle size and mass used, there were significant differences in chemical classes composition of monoterpenes (leaves: 28.35-62.01 %, stems: 23.8-57.49 % and seeds: 60.92-85.76 %) and sesquiterpene hydrocarbons (leaves: 19.39-36.91 %, stems: 36.71-59.90 % and seeds: 7.9-21.96 %) as well as oxygenated compounds (leaves: 6.17-50.3 %, stems: 4.22-9.12 % and seeds 4.17-9.43 %). Whereas hydrodistillation (heating based) essential oil showed a different qualitative and quantitative aromatic profile compared to the green technique HS-SPME (adsorption and affinity based), in chemical groups as monoterpene (leaves: 59.8, stems: 69.37 and seeds: 88.14 %) and sesquiterpenes (leaves: 13.93, stems: 17.17 and seeds: 4.23 %) hydrocarbons as well as in oxygenated compounds (leaves: 24.32, stems: 21.19 and seeds: 5.37 %).
Research Center/Unit :
MSLab CART - Centre Interfacultaire d'Analyse des Résidus en Traces - ULiège MolSys - Molecular Systems - ULiège
Disciplines :
Chemistry
Author, co-author :
Mékaoui, Radja; University of Sciences and Technologies Houari Boumediène, Faculty of Chemistry, Laboratory of Organic and Functional Analysis, U.S.T.H.B, B.P. 32 El Alia, Bâb Ezzouar, Algiers, Algeria
Benkaci-Ali, Farid; University of Sciences and Technologies Houari Boumediène, Faculty of Chemistry, Laboratory of Organic and Functional Analysis, U.S.T.H.B, B.P. 32 El Alia, Bâb Ezzouar, Algiers, Algeria
Scholl, Georges ; Université de Liège - ULiège > Département de chimie (sciences) > Center for Analytical Research and Technology (CART)
Eppe, Gauthier ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie analytique inorganique
Language :
English
Title :
Effect of Different Parameters on Composition of Volatile Components of Leaf, Stem and Seed from Algerian Bupleurum fruticosum L. Extracted by Hydrodistillation and Headspace Solid-Phase Microextraction
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