[en] Interconnected macroporous imidazolium-based mono- liths are produced via the modified Radziszewski multicomponent reaction (MCR) applied to triamines under high internal phase emulsion (HIPE) conditions. This straightforward one-pot synthesis combines the efficiency and versatility ofMCRs with the ease of implementation of the emulsion templating polymerization process. The characterization of the chemical structure and morphology of the resulting materials confirms the formation of the expected macroporous poly(ionic liquid)s (PILs) networks. The promising catalytic activity and recyclability of these porous PIL monoliths are illustrated for the transesterification reaction and the decarboxylation of caffeic acid. In these cases, almost complete conversion is reached while benefiting from the advantages associated with a heterogeneous catalyst.
Research Center/Unit :
Center for Education and Research on Macromolecules Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Stiernet, Pierre ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Aqil, Abdelhafid ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Zhu, Xiaomin; RWTH Aachen University, Institut für technische und makromolekulare Chemie, Germany
Debuigne, Antoine ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM) Research Unit, Center for Education and Research on Macromolecules (CERM), Belgium
Language :
English
Title :
Multicomponent Radziszewski emulsion polymerization towards macroporous poly(ionic liquid)s catalysts
Publication date :
21 January 2020
Journal title :
ACS Macro Letters
eISSN :
2161-1653
Publisher :
American Chemical Society, United States - District of Columbia
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